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Any form of aluminum sulfate could be called alum, including toxic versions of the chemical. However, the type of alum you find used for pickling and in deodorant is potassium alum, KAl(SO 4) 2 Â·12H 2 O. Sodium aluminum sulfate is a type of alum that is used in commercial baking powder.
Sulfur and sulfate are non-toxic. However, carbon disulfide, hydrogen sulfide and sulfur dioxide are all toxic. Hydrogen sulfide is particularly dangerous and can cause death by respiratory paralysis. Sulfur dioxide is produced when coal and unpurified oil are burned. Sulfur dioxide in the atmosphere causes acid rain.