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The Cayenne pepper. is a bit milder, rating at 30,000 to 50,000 Scoville units. They're named after the French Guiana city of Cayenne. I'm sure you're familiar with the Cayenne pepper; it's ground and sold as a pretty common spice.
Cayenne are peppers. They are really hot and cayenne powder is ground dried cayenne pepper. Chili Powder is a mix of chili pepper powder and other spices like cumin and garlic powder and sometimes other spices like cinnamon or nutmeg (no lie).But chili powder can be really hot depending on the ratio and kind of chiles to other ingredients in the mix.hili Powder is a mix of chili pepper powder and other spices like cumin and garlic powder and sometimes other spices like cinnamon or nutmeg (no lie).