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The Cayenne pepper. is a bit milder, rating at 30,000 to 50,000 Scoville units. They're named after the French Guiana city of Cayenne. I'm sure you're familiar with the Cayenne pepper; it's ground and sold as a pretty common spice.
And substituting in cayenne for paprika â while easier â is a major heat uptick. Paprika is often listed as an ingredient for its earthy mild simmering heat â the cayenne is a significant upgrade. It may be best to cut the amount of chili powder that a recipe is requiring if you are opting for cayenne over paprika.