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What is the largest city in North Korea? The largest city in North Korea is Pyongyang, the country's capital city. At the time of the 2008 census it had 3,255,288 residents, making it the only city in North Korea with a population of more than one million people.
Skyline of Central Daejeon. Daejeon is the 5th largest city in South Korea, with a population of approximately 1.5 million. It is located in the centre of Korea and is at the crossroads of national rail and road transport routes, the Gyeongbu railway, Honam railway, Gyeongbu Expressway, and Honam Expressway.