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PA (Polyamide) is a semi-crystalline polymer. There are two types: those made of one basic material (e.g. PA 6) and those made of two basic materials (e.g. PA 66). They can occur both naturally (e.g. wool and silk) and synthetically (e.g. nylon).
Kevlar is a polyamide, a type of synthetic polymer, in which the amide groups are separated by para phenylene groups, meaning that the amide groups are attached to each other on opposite sides of the phenyl group (i.e. carbons 1 and 4).