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Cayenne pepper is named after its supposed place of origin, the city of Cayenne in French Guiana, and it is now cultivated in many tropical and subtropical areas throughout the world, including parts of India, Africa, and North and South America.he pepper is the fruit of a small plant named Capsicum annuum. It may be used fresh, but it is most commonly dried and ground into a powder for ease of storage and incorporation into food.
Cayenne pepper is pure ground dried chiles. 1  Chili powder is a blend of spices, of which cayenne happens to be but one. The other ingredients include cumin, garlic powder, oregano, and paprika. 2  Even so, I think it's illuminating to see what chili powder is, what ingredients it's made up of, and in what proportions.