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Confidence votes 106. The role that enzymes plays in DNA replication is that the enzyme helicase breaks hydrogen bonds between the complementary bases, and the chains separate.
DNA polymerase is the chief enzyme of DNA replication. It helps to synthesize and catalyze the bonds between the nucleic acids in DNA (adenine, cytosine, guanine, thymine). DN â¦ A polymerase is an enzyme that are involved in DNA synthesis., II and III are known in of growing   * Yes. DNA polymerases, like most enzymes, are proteins, and the code for their primary structure (their amino acid sequences) is included in the genome.       Yes, DNA does code for DNA polymerase.