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1. fourth in order. 2. containing four elements or groups. quaternary. 1 adj, pertaining to a chemical compound in which four atoms or groups of elements are bonded to one atom, such as a quaternary ammonium compound in which four organic radicals are substituted for the four hydrogen molecules on an ammonium ion.
Of fourth rank or order. the quaternary stress in a pronounced word. Of a mathematical expression containing e.g. x4. Relating to or in number base four.