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Wash the brush with ordinary water. Add a coat of gloss or semi-gloss latex paint to the primed plywood furniture using a mini roller. Apply to a small area and then smooth the paint using the cleaned brush. Continue until the plywood furniture is completely coated.
Most plywood can be satisfactorily painted. As with any other wood surface, though, poor results are achieved with poor preparation and poor materials. Raw (and clean/dry!) wood should first be primed with a good exterior primer (I prefer alkyd), then painted within a few days with a good satin or semi-gloss exterior paint (latex or acrylic).