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Yes, in specific rare cases, vitamin B can cause acne for its supplement users. Though there are many different varieties of vitamin B that may cause this acne to occur, it is still a possibility. Users who have been documented using vitamins B6 and B12 have been noted to have acne breakouts after using the supplement.
Yet, my skin problems really did seem to develop around the time I started taking these vitamins. I switched on my computer and began to Google around. Sure enough, I found numerous studies confirming that vitamin supplements, particularly B12 and B6 can induce and/or worsen acne in some people.