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Yes, in specific rare cases, vitamin B can cause acne for its supplement users. Though there are many different varieties of vitamin B that may cause this acne to occur, it is still a possibility. Users who have been documented using vitamins B6 and B12 have been noted to have acne breakouts after using the supplement.
Dietary supplements are available for people with vitamin B6 deficiency, which is rare in the United States. Other Vitamins. The American Skin Association lists other vitamins that may help improve skin. These vitamins include vitamin A, riboflavin, vitamin C and vitamin D.