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Preheat oven to 440 degrees F (227 degrees C). Whisk onion, ketchup, vinegar, honey, brown sugar, Worcestershire sauce, mustard, and cayenne pepper together in a bowl until barbeque sauce is smooth. Place pork chops on a baking sheet and season with salt and pepper. Top each pork chop with 2 tablespoons barbeque sauce. Bake in the preheated oven until pork chops are cooked through, about 30 minutes. An instant-read thermometer inserted into the center should read at least 145 degrees F (63 degrees C).
Cook the pork chops for 3-4 minutes on the first side. The oil will be piping hot by this point, so place the chops in the pan carefully to limit splattering. Let them sizzle until you notice the underside beginning to brown.