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Yes, in specific rare cases, vitamin B can cause acne for its supplement users. Though there are many different varieties of vitamin B that may cause this acne to occur, it is still a possibility. Users who have been documented using vitamins B6 and B12 have been noted to have acne breakouts after using the supplement.
Vitamin C and Acne Scars. Citrus fruits such as oranges are full of vitamin C. Photo Credit Denira777/iStock/Getty Images. Vitamin C plays an important role in skin repair, including the healing of acne scars. It is a water-soluble vitamin, meaning it is not stored in your body, so you must ingest it daily.If you are acne-prone, talk with your dermatologist about vitamin C. She may advise you to take a supplement or use a vitamin C cream.itamin C plays an important role in skin repair, including the healing of acne scars. It is a water-soluble vitamin, meaning it is not stored in your body, so you must ingest it daily. If you are acne-prone, talk with your dermatologist about vitamin C. She may advise you to take a supplement or use a vitamin C cream.