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You may deduct a maximum of up to 50% of your adjusted gross income (AGI) (Line 36 on IRS Form 1040) for the tax year the donation was given. However, if you give more than 50%, the excess may be carried forward for up to five years.
The IRS rules state the the Corporation is entitled to deduct upto a maximum of 10% of a Corporations net taxable income without consideration of NOL and Charitable contribution. In other words, calculate the taxable income w/o deduction of charitable contribution, and a maximum limit is 10% of this taxable income. Therefore, if there is no taxable income, the corporations would not be able to deduct charitable contributions for that calendar year. I guess the next question would be, what if your client, the C corporation made a contribution in excess of the 10% limit.