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Yes, in specific rare cases, vitamin B can cause acne for its supplement users. Though there are many different varieties of vitamin B that may cause this acne to occur, it is still a possibility. Users who have been documented using vitamins B6 and B12 have been noted to have acne breakouts after using the supplement.
1 When vitamin B12 is taken at normal doses, side-effects are rare. 2  High doses may cause acne. 3  Allergies to vitamin B12 supplements have been reported and can cause swelling, itchy skin and shock.4  Interactions. 5  Drugs for acid reflux, diabetes and other conditions may make it harder for your body to absorb vitamin B12. When vitamin B12 is taken at normal doses, side-effects are rare. 2  High doses may cause acne. 3  Allergies to vitamin B12 supplements have been reported and can cause swelling, itchy skin and shock.