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Yes, in specific rare cases, vitamin B can cause acne for its supplement users. Though there are many different varieties of vitamin B that may cause this acne to occur, it is still a possibility. Users who have been documented using vitamins B6 and B12 have been noted to have acne breakouts after using the supplement.
A deficiency of vitamin B6 can result in acne. Vitamin C and bioflavonoids are another set of antioxidants that are required for at least 300 metabolic functions in the body, including tissue growth and repair. Vitamin C protects against infection and enhances immunity. Bioflavanoids have an antibacterial effect.