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DOS uses CLI (command line interface), whereas Windows used GUI (graphical user interface).. DOS does not support networking, Windows does.. DOS is a single user OS, Windows is Multiuser.. DOS is a single tasking OS, Windows is Multitasking.. Dos is a single threading OS, Windows is a Multithreading..
In contrast, Windows is based on NT and is by far the most popular operating system among general PC users. Second, as pointed out by others, Microsoft, simply doesn't need to! NT is quite robust and stable and also modern Windows can provide some amount of POSIX compatibility as well. Third, they are better off with what they have : The whole Windows ecosystem is closely linked to Windows NT.