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Self-cleaning ovens work by raising the temp in the oven to a really high level and burning off everything inside, which in practice creates tons of smoke (no big deal if your oven is vented) and leaves carbon (and other things) behind. You will still need to clean it with oven cleaner.
A self-cleaning oven is one that uses extremely high temperatures to burn any spills or splatters inside the oven. Many of self-cleaning ovens heat up to around 850 degrees Fahrenheit in order to turn any foreign matter stuck on the walls, floor or door of the oven into ash. You can then wipe out the residue with a damp cloth.