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The Bonjour service is a program from Apple. It is a program that discovers computers and programs/devices on computers that are inside a computing network. It is supposed to make communication between apple devices more efficient. That being said, if you have any apple devices connected to the network, it wont hurt to keep it on the PC.
And since Bonjour service allows for automatic detection of printers and file-sharing servers, users of various Apple products can take advantage of faster and easier sharing of files. Those using iTunes can easily share music files with friends and family.