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Self-cleaning ovens work by raising the temp in the oven to a really high level and burning off everything inside, which in practice creates tons of smoke (no big deal if your oven is vented) and leaves carbon (and other things) behind. You will still need to clean it with oven cleaner.
Before the self-cleaning cycle is started, the oven racks must be removed and any liquid spills wiped from the bottom. Once the self-cleaning cycle is turned on, the oven locks and heats up to 880 degrees Fahrenheit for around three hours. When the self-cleaning cycle is over, the oven turns off, cools down and then unlocks the door. Ashes are left behind and should be swept out with a dust pan and broom.