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The Bonjour service is a program from Apple. It is a program that discovers computers and programs/devices on computers that are inside a computing network. It is supposed to make communication between apple devices more efficient. That being said, if you have any apple devices connected to the network, it wont hurt to keep it on the PC.
Remote Desktop. If I could install only one app on my Windows 8 tablet, the Remote Desktop app would be it. This is the app that gives you a full Windows desktop even on the Windows RT version of a tablet, but with a simple, touch-friendly user interface.