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Self-cleaning ovens work by raising the temp in the oven to a really high level and burning off everything inside, which in practice creates tons of smoke (no big deal if your oven is vented) and leaves carbon (and other things) behind. You will still need to clean it with oven cleaner.
There are some drawbacks to using the self-cleaning cycle, the largest being that the oven must reach temperatures near 900 degrees Fahrenheit to carbonize the material stuck on the surfaces of the oven. To get to this temperature, the oven utilizes a locking mechanism, which prevents the oven door from being opened.