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Self-cleaning ovens work by raising the temp in the oven to a really high level and burning off everything inside, which in practice creates tons of smoke (no big deal if your oven is vented) and leaves carbon (and other things) behind. You will still need to clean it with oven cleaner.
Using the Self Cleaning System. A popular way to break-in the chemical odor of a new oven is to use the self-cleaning system several times until the smell is completely vanished. The smell may get quite strong while the self cleaning is working and good ventilation is essential in the house during this process.