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Self-cleaning ovens work by raising the temp in the oven to a really high level and burning off everything inside, which in practice creates tons of smoke (no big deal if your oven is vented) and leaves carbon (and other things) behind. You will still need to clean it with oven cleaner.
If you have a current model unit, go to the Rowenta website and see if you can view the PDF of the owners manual for details on using your new iron. Generally, the self-cleaning function is a special mode/setting to enable iron to generate a burst of steam that forces deposits in the system out the sole plate of your iron.