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To activate your product over the telephone, use one of the following numbers: 1  Windows activation: (888) 571-2048. 2  Microsoft Office activation (United States only): (888) 652-2342. 3  TTY number: (800) 718-1599.  If you are an international customer, find the telephone number from the following list: Country/region. Volume License Keys only toll call.
The above are methods to activate an office 2010 product on your home computer.If you are using a volume edition of Microsoft Office 2010 (usually at work places), then you will have to activate office 2010 using volume licenses. Related Videos.iled Under: Office 2010, Office Tips. Office 2010 need to be activated before you could continue to use its full features, after an initial grace period. This is similar to windows activation to activate a copy of windows 7 or vista on your computer. Find below the details on the various activation methods.