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The Bonjour service is a program from Apple. It is a program that discovers computers and programs/devices on computers that are inside a computing network. It is supposed to make communication between apple devices more efficient. That being said, if you have any apple devices connected to the network, it wont hurt to keep it on the PC.
Gizmo Project (http://www.gizmoproject.com) adds Bonjour Service to the Windows XP (or Windows 2000, or Windows NT) Services folder. This service starts automatically and runs a process named mDNSResponder.exe which cannot be ended by Windows Task Manager. To remove, it must first be disabled in Services.