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Self-cleaning ovens work by raising the temp in the oven to a really high level and burning off everything inside, which in practice creates tons of smoke (no big deal if your oven is vented) and leaves carbon (and other things) behind. You will still need to clean it with oven cleaner.
Place your cast iron upside down on the top rack, and set your oven to self-clean. This cycle on my oven goes for 4 hours. Once the self-clean cycle has finished, allow your pans to remain in the oven until cool. Tip: Do not line the bottom of your oven with foil, as it can melt during the self-clean cycle.