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A near-Earth object (NEO) is any small Solar System body whose orbit brings it into proximity with Earth. By definition, all NEOs have a closest approach to the Sun (perihelion) of less than 1.3 astronomical unit (AU).
To get the number in kilometers, multiply by the conversion above: 0.28 x 150 = 42 million kilometers. Another example: Jupiter is 5.2 AU from the Sun and Earth is 1 AU from the Sun. So the distance between Jupiter's orbit and Earth's orbit is 5.2 - 1 = 4.2 AU or 630 million kilometers.