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The XML Paper Specification (XPS) format is basically an electronic representation of digital documents based on XML. It is a paginated fixed-layout format that retains the look and feel of your electronic documents. As a form of electronic paper, the XPS format provides a way in which you can easily create, share, print and save digital documents. Although XPS Documents can be easily created once you have the right software installed, just like the PDF, the XPS format is a difficult-to-handle format.
How to Print to the XPS Document Writer. To do so, click on the File menu of a document or a file you want to print to .xps format and then click Print. A Print dialog box will be visible on your computer screen. From it choose Microsoft XPS Document Writer. Here, I tried this with my Word 2013 file.