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Water is separated from the first overhead stream, and the resulting isobutylene-enriched stream is recycled back to the reaction step. The first bottoms stream is distilled to produce a bottoms product stream comprising diisobutylene and a second overhead stream comprising tertiary butyl alcohol and diisobutylene.he reaction product stream, comprising diisobutylene, isobutylene, TBA, and water, is purified by a process a shown in. . The reaction product stream is passed via line 11 to a first distillation tower 10. Tower 10 contains 35 ideal stages, 11 above feed and 24 below feed.
Butyl rubber is a synthetic rubber, a copolymer of isobutylene with isoprene. The abbreviation IIR stands for isobutylene isoprene rubber. Polyisobutylene, also known as PIB or polyisobutene, (C 4 H 8) n, is the homopolymer of isobutylene, or 2-methyl-1-propene, on which butyl rubber is based.Butyl rubber is produced by polymerization of about 98% of isobutylene with about 2% of isoprene.Structurally, polyisobutylene resembles polypropylene, having two methyl groups substituted on every other carbon atom.utyl rubber has excellent impermeability, and the long polyisobutylene segments of its polymer chains give it good flex properties. The formula for PIB is: â(âCH 2 âC(CH 3) 2 â) n â. The formula for IIR is: