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Best Answer: ethanol because of the OH polar head is more soluble in water because it forms hydrogen bonds with H20 than the CH3 in dimethyl ether.Also alcohol is more soluble then ethers because of that OH polar head.In addition, 1-5 carbons chain are generally soluble but more preference is given to the one with less carbon chain and OH polar head.Source(s): took organic chem 1 and 2.ating Newest Oldest. Best Answer: ethanol because of the OH polar head is more soluble in water because it forms hydrogen bonds with H20 than the CH3 in dimethyl ether. Also alcohol is more soluble then ethers because of that OH polar head.
Remind students that isopropyl alcohol has an oxygen atom bonded to a hydrogen atom so it does have some polarity but not as much as water. Since water is more polar than alcohol, it attracts the positive sodium and negative chloride ions better than alcohol. This is why water dissolves more salt than alcohol does. Another way of saying this is that the solubility of salt is greater in water than in alcohol.