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Best Answer: ethanol because of the OH polar head is more soluble in water because it forms hydrogen bonds with H20 than the CH3 in dimethyl ether.Also alcohol is more soluble then ethers because of that OH polar head.In addition, 1-5 carbons chain are generally soluble but more preference is given to the one with less carbon chain and OH polar head.Source(s): took organic chem 1 and 2.ating Newest Oldest. Best Answer: ethanol because of the OH polar head is more soluble in water because it forms hydrogen bonds with H20 than the CH3 in dimethyl ether. Also alcohol is more soluble then ethers because of that OH polar head.
Ethanol is soluble in water because the-OH group of ethanol (CH3CH2OH) can form hydrogen bonds with water.Hydrogen bonding occurs when a very electronegative molecule like O â¦ , N, F are bonded to molecules like hydrogen. For this example, I'll talk about groups that have-NH, -SH, -OH.herefore, they are too different from each other and are not miscible... Old (not so good) Answer Hexane is not soluble in water because Hexane is a Nonpolar solvent while water is Polar solvent. Like dissolves like.