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As for what time of day to drink your protein shake, this partially depends on when you workout. The most effective times for drinking your protein shake is first thing in the morning after you wake up, and then again immediately following your workout.
If you want to avoid weight gain, use caution when ingesting excessive amounts of whey protein before bed. One cup of a chocolate-flavored whey protein drink contains 120 calories, notes the U.S. Department of Agriculture.