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As for what time of day to drink your protein shake, this partially depends on when you workout. The most effective times for drinking your protein shake is first thing in the morning after you wake up, and then again immediately following your workout.
If you have a protein shake 30 minutes before you workout, this should fuel your blood sugar throughout your whole workout. The main reason to ingest a during-workout drink is to refuel your glycogen levels, but this really isn't necessary if you eat only shortly before the workout.