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As for what time of day to drink your protein shake, this partially depends on when you workout. The most effective times for drinking your protein shake is first thing in the morning after you wake up, and then again immediately following your workout.
When you have your pre-workout drink, these nutrients carry over to well after your workout is over. For example, one research study found that having a whey protein drink before a workout resulted in blood amino acid levels being increased for up to 2 hours following the workout.