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As for what time of day to drink your protein shake, this partially depends on when you workout. The most effective times for drinking your protein shake is first thing in the morning after you wake up, and then again immediately following your workout.
Protein shakes contain complex carbohydrates, which are an important source of energy for the body. Drinking a protein shake before your workout can help ensure that you have enough energy to put your all into your workout and get the most out of it. Take a protein shake before your workout on the days when you need a bit of an extra push to get you going.