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Though mostly water, the cytosol is full of proteins that control cell metabolism including signal transduction pathways, glycolysis, intracellular receptors, and transcription factors. Cytoplasm is a collective term for the cytosol plus the organelles suspended within the cytosol.
Without cytoplasm, the cell would be deflated and materials would not be able to pass easily from one organelle to another. Cytosol is the part of the cytoplasm that does not contain organelles. Instead, cytosol is confined by the boundaries of a matrix which fills the part of the cell that does not contain organelles.