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As for what time of day to drink your protein shake, this partially depends on when you workout. The most effective times for drinking your protein shake is first thing in the morning after you wake up, and then again immediately following your workout.
The best way to do this is to drink a protein shake directly after exercising, preferably within 30 minutes of the conclusion of your workout. This helps your body to recover while also providing the protein needed to fuel your body. Another reason that people use protein shakes is to help with weight loss.