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As for what time of day to drink your protein shake, this partially depends on when you workout. The most effective times for drinking your protein shake is first thing in the morning after you wake up, and then again immediately following your workout.
This is especially important if you're drinking your whey protein shake after weight training. For 30 minutes following a workout, your body is at its peak for muscle building, and it's recommended that you consume a snack containing both protein and carbs within that time frame.