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As for what time of day to drink your protein shake, this partially depends on when you workout. The most effective times for drinking your protein shake is first thing in the morning after you wake up, and then again immediately following your workout.
The best time to have a protein shake depends on the type of protein you are drinking. However in general, you should try to drink it 30 minutes before and after exercise and 2 hours before going to bed for best results.