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As for what time of day to drink your protein shake, this partially depends on when you workout. The most effective times for drinking your protein shake is first thing in the morning after you wake up, and then again immediately following your workout.
It is also a good idea to drink a whey protein shake before you start your workout session, but that's not always necessary. You actually don't need to drink a protein shake if you've had a whole food meal with carbohydrate and lean protein at least a couple of hours before training. You can have a protein shake though if you ate your last meal more than 4 hours ago.