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As for what time of day to drink your protein shake, this partially depends on when you workout. The most effective times for drinking your protein shake is first thing in the morning after you wake up, and then again immediately following your workout.
If you're interested in drinking your protein shake before bed, you will be better off opting for casein instead of whey. Unlike whey, casein protein converts into a gel like consistency when it reaches your stomach, which in turn reduces your digestion and absorption rate.