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As for what time of day to drink your protein shake, this partially depends on when you workout. The most effective times for drinking your protein shake is first thing in the morning after you wake up, and then again immediately following your workout.
The best form of protein after a workout is a protein drink. You don't want to stuff yourself with a burger or a ham sandwich; you want a light protein-rich meal that is easy to digest and won't leave you feeling sluggish. Try a yogurt smoothie or whey-based protein drink.