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Ice water with lemon is virtually calorie-free. Water, of course, contains no calories, and the juice of one lemon wedge provides only 1 calorie. Even if you mixed your water with 1/4 cup of lemon juice, you'd still only get 13 calories.
At that time, I was told that drinking lemon water first thing in the morning was especially good for cleansing the liver. In my nutrition studies, I learned that lemons are a good source of citric acid, potassium, calcium, phosphorous and magnesium.