So, let's look at an example of equilibrium in the cookie market and see what happens when things change. Let's say the equilibrium price for a chocolate chip cookie is $3. Here's an example of the supply and demand curves, with an equilibrium price of $3, which is at the intersection of the supply and demand curves.
A sigma bond is the end-to-end overlap of the bonding orbitals, usually hybrid orbitals. The sigma bond is a single bond. A pi bond is the side-to-side overlap of unhybridized p-orbitals. A pi bond, along with a sigma bond form a double bond. A triple bond is two pi bonds and a sigma bond. Take a look at this diagram showing a sigma bond and a pi bond, forming a single bond and a double bond. http://metafysica.nl/ethylene01.jpg.
Sigma and Pi Bonds. According to orbital theory, covalent bond is formed by the result of coupling of electrons with opposite spins belonging to orbitals of outermost orbits of the two atoms.