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Other Ways to Kill Sugar Ants. Try a natural home remedy to kill sugar ants if you don't want to use chemicals. Feed the ants cornmeal, which they are unable to digest. Mix it with powdered sugar to make it more appealing. Spray ants directly with vinegar or a solution of water and baking soda.
Try white vinegar and water. Ants really hate vinegar, and you can make a cheap, easy pesticide just using vinegar and water. Mix a 50/50 solution of vinegar and water in a spray bottle. Spray it directly onto the ants to kill them, then wipe up the ants using a damp paper towel and discard them.1  You can also use vinegar and water as a deterrent; spray it around your windowsills, doorways and other places where you see ants coming inside.ix a 50/50 solution of vinegar and water in a spray bottle. Spray it directly onto the ants to kill them, then wipe up the ants using a damp paper towel and discard them. 1  You can also use vinegar and water as a deterrent; spray it around your windowsills, doorways and other places where you see ants coming inside.