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Other Ways to Kill Sugar Ants. Try a natural home remedy to kill sugar ants if you don't want to use chemicals. Feed the ants cornmeal, which they are unable to digest. Mix it with powdered sugar to make it more appealing. Spray ants directly with vinegar or a solution of water and baking soda.
Kill the queen. The best way to get rid of ants is to destroy their source: the ant queen. She produces a large number of ants and killing her will exterminate them; if you can, find and kill the queen inside the ant nest. She's rather shy and will hide in the bottom.