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Other Ways to Kill Sugar Ants. Try a natural home remedy to kill sugar ants if you don't want to use chemicals. Feed the ants cornmeal, which they are unable to digest. Mix it with powdered sugar to make it more appealing. Spray ants directly with vinegar or a solution of water and baking soda.
Ants. A common natural way to get rid of ants is by using vinegar. Put vinegar in a spray bottle and spray it where ants commonly appear. Black pepper or cayenne pepper can also be used to defend areas from ants by sprinkling it in places where ants show up.