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Vaginal infections are a very common cause for the pH of the vagina to rise. The most common vaginal infection in my practice (and in all doctor's offices) is Bacterial Vaginosis which causes the normal vaginal pH to rise to above 4.5. Odor usually occurs with Bacterial Vaginosis.
Vaginal pH is a measure of the acidity of the vaginal environment and in healthy women vaginal pH is typically 3.5 to 4.5. This of course is slightly acidic, falling a little below a neutral rating of 7. The Importance of pH.