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Vaginal infections are a very common cause for the pH of the vagina to rise. The most common vaginal infection in my practice (and in all doctor's offices) is Bacterial Vaginosis which causes the normal vaginal pH to rise to above 4.5. Odor usually occurs with Bacterial Vaginosis.
pH balance is a fundamental component of vaginal health. While the vagina's pH changes over the course of a woman's lifetime (see graph for more information), a healthy vagina generally tends towards a more acidic pH, ideally between 4.2 and 5. This results from the presence of lactobacillus, normally occurring bacteria that produce lactic acid.