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Vaginal infections are a very common cause for the pH of the vagina to rise. The most common vaginal infection in my practice (and in all doctor's offices) is Bacterial Vaginosis which causes the normal vaginal pH to rise to above 4.5. Odor usually occurs with Bacterial Vaginosis.
Dilution drives the pH value of an acidic or basic solution toward 7. The pH values of acidic solutions increase with dilution, while the pH values of basic solutions decrease with dilution.