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http://socratic.org/chemistry. We'll look at what happens when you dissolve ionic and covalent compounds in water. Ionic compounds break apart into the ions that make them up, a process called dissociation, while covalent compounds only break into the molecules, not the individual atoms.ttp://socratic.org/chemistry. We'll look at what happens when you dissolve ionic and covalent compounds in water. Ionic compounds break apart into the ions that make them up, a process called dissociation, while covalent compounds only break into the molecules, not the individual atoms.
A: Ionic compounds conduct electricity when dissolved in water because the movement of their negatively-charged and positively-charged particles forms an electrical current, explains About.com. In this liquid state, the charged ions separate and move freely, creating a current of electrical particles that conducts electricity.