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When you are a liquid and want to become a gas, you need to find a lot of energy. Once you can direct that energy into your molecules, they will start to vibrate. If they vibrate enough, they can escape the limitations of the liquid environment and become a gas. When you reach your boiling point, the molecules in your system have enough energy to become a gas. The reverse is true if you are a gas.
Examples of Gas to Solid (Deposition) Under certain circumstances, gas can transform directly into a solid. This process is called deposition. Water vapor to ice - Water vapor transforms directly into ice without becoming a liquid, a process that often occurs on windows during the winter months. Physical vapor to film - Thin layers of material known as film are deposited onto a surface using a vaporized form of the film.