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After a long period attempting to develop a process to upgrade rubber qualities (such as including nitric acid) that almost ruined him, in 1840 Goodyear discovered vulcanization, quite by accident. An interesting fact: in 1815, a humble sawyer-Hancock-became one of the leading manufacturers in the UK.
In 1839, Charles Goodyear invented rubber vulcanization, but the first rubber condom was not produced until 1855. Just a few short years later, the majority of rubber companies were producing condoms as well. These condoms were reusable, which meant they were much more affordable.