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After a long period attempting to develop a process to upgrade rubber qualities (such as including nitric acid) that almost ruined him, in 1840 Goodyear discovered vulcanization, quite by accident. An interesting fact: in 1815, a humble sawyer-Hancock-became one of the leading manufacturers in the UK.
THE FIRST elastic bands, made from vulcanised rubber, were patented on March 17, 1845, by Stephen Perry of Messrs Perry & Co, rubber manufacturers of London. Production of rubber bands 'for papers, letters, etc' was inaugurated by the firm at about the same time. Sean Tyler, Orpington, Kent. THE ENGLISHMAN Thomas Hancock invented the rubber band in about 1820. The bands invented at that time were not vulcanised and would soften on hot days or harden on cold ones.