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After a long period attempting to develop a process to upgrade rubber qualities (such as including nitric acid) that almost ruined him, in 1840 Goodyear discovered vulcanization, quite by accident. An interesting fact: in 1815, a humble sawyer-Hancock-became one of the leading manufacturers in the UK.
Although the curing of rubber has been carried out since prehistoric times, the modern process of vulcanization, named after Vulcan, the Roman god of fire, was not developed until the 19th century.