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After a long period attempting to develop a process to upgrade rubber qualities (such as including nitric acid) that almost ruined him, in 1840 Goodyear discovered vulcanization, quite by accident. An interesting fact: in 1815, a humble sawyer-Hancock-became one of the leading manufacturers in the UK.
1 Carbon disulfide, a compound of sulfur, can be used to make cellophane and rayon (a material used in clothes). 2  Sulfur is used to vulcanize rubber. 3  Vulcanization makes rubber tougher. 4  It ensures that rubber maintains its shape. 5  Car tires, shoe soles, hoses and ice hockey pucks are all made from vulcanized rubber.