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After a long period attempting to develop a process to upgrade rubber qualities (such as including nitric acid) that almost ruined him, in 1840 Goodyear discovered vulcanization, quite by accident. An interesting fact: in 1815, a humble sawyer-Hancock-became one of the leading manufacturers in the UK.
Charles Goodyear (1800â1860) invented vulcanization of rubber when he heated a mixture of rubber and sulfur. The Goodyear story is one of either pure luck or careful research. Goodyear insisted that it was the latter, though many contemporaneous accounts indicate the former.