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After a long period attempting to develop a process to upgrade rubber qualities (such as including nitric acid) that almost ruined him, in 1840 Goodyear discovered vulcanization, quite by accident. An interesting fact: in 1815, a humble sawyer-Hancock-became one of the leading manufacturers in the UK.
Charles Goodyear, the man most associated with rubber, solved both problems in 1839 by adding sulfur, a process he called â vulcanization .â Rubber erasers first found their way onto pencils in 1858, but the US denied Hymen L. Lipman a patent for the combination because it simply joined two existing inventions.