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After a long period attempting to develop a process to upgrade rubber qualities (such as including nitric acid) that almost ruined him, in 1840 Goodyear discovered vulcanization, quite by accident. An interesting fact: in 1815, a humble sawyer-Hancock-became one of the leading manufacturers in the UK.
From the beginning of lawn tennis in the 1870s, India rubber, made from a vulcanisation process invented by Charles Goodyear in the 1850s, was used to manufacture lawn tennis balls. Originally tennis balls were made solely of rubber, but the wearing and playing properties of the balls were improved by covering them with flannel stitched around the rubber 'core'.