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After a long period attempting to develop a process to upgrade rubber qualities (such as including nitric acid) that almost ruined him, in 1840 Goodyear discovered vulcanization, quite by accident. An interesting fact: in 1815, a humble sawyer-Hancock-became one of the leading manufacturers in the UK.
Although vulcanization is a nineteenth-century invention, the history of rubber cured by other means goes back to prehistoric times. [citation needed] The name of the first major civilization in Guatemala and Mexico, the Olmec, means rubber people in the Aztec language.