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After a long period attempting to develop a process to upgrade rubber qualities (such as including nitric acid) that almost ruined him, in 1840 Goodyear discovered vulcanization, quite by accident. An interesting fact: in 1815, a humble sawyer-Hancock-became one of the leading manufacturers in the UK.
Inventor of Vulcanized Rubber. By the mid 1830s, it seemed as though the rubber industry in America was going under. The problem with the new material was that it was unstable â becoming completely solid and cracking in the winter, then melting into goo in the summer.