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From Wikipedia, the free encyclopedia. The ligand cone angle (a common example being the Tolman cone angle or Î¸) is a measure of the size of a ligand. It is defined as the solid angle formed with the metal at the vertex and the hydrogen atoms at the perimeter of the cone (see figure). Tertiary phosphine ligands are commonly classified using this parameter, but the method can be applied to any ligand.
The base radius of a circular cone is the radius of its base; often this is simply called the radius of the cone. The aperture of a right circular cone is the maximum angle between two generatrix lines; if the generatrix makes an angle Î¸ to the axis, the aperture is 2 Î¸. A cone with its apex cut off by a plane is called a truncated cone; if the truncation plane is parallel to the cone's base, it is called a frustum.