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From Wikipedia, the free encyclopedia. The ligand cone angle (a common example being the Tolman cone angle or Î¸) is a measure of the size of a ligand. It is defined as the solid angle formed with the metal at the vertex and the hydrogen atoms at the perimeter of the cone (see figure). Tertiary phosphine ligands are commonly classified using this parameter, but the method can be applied to any ligand.
All the way around the circle is 360o and the 50% wedge goes half way around so the central angle for the 50% wedge is 50% of 360o which is 1/2 Ã 360o = 180o. The 40% wedge uses 40% of 360o as its central angle and hence the angle is 40% of 360o or 40/100 Ã 360 = 144o.