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Osmolality of blood increases with dehydration and decreases with overhydration. In normal people, increased osmolarity in the blood will stimulate secretion of antidiuretic hormone (ADH). This will result in increased water reabsorption, more concentrated urine, and less concentrated blood plasma.
Serum and Urine Osmolality. Osmolality of body fluid is a measure of its solute/water ratio. The osmolality of serum, urine, or other body fluids depends on the number of osmotically active ions and molecules dissolved in a kilogram of body water. Sodium, potassium, chloride, bicarbonate, glucose and urea are the osmotically important body fluid solutes.