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Osmolality of blood increases with dehydration and decreases with overhydration. In normal people, increased osmolarity in the blood will stimulate secretion of antidiuretic hormone (ADH). This will result in increased water reabsorption, more concentrated urine, and less concentrated blood plasma.
Major Electrolytes Located Outside the Cell (Extracellular) Sodium and Calcium Sodium is a major electrolyte in extracellular fluid and it exercises most of its influence outside the cell. The concentration of sodium affects serum osmolality (solute concentration in 1 L of water) and extracellular fluid volume. Sodium also assists nerves and muscle cells to interact.