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Vitamins are classified as either fat soluble (vitamins A, D, E and K) or water soluble (vitamins B and C). This difference between the two groups is very important. It determines how each vitamin acts within the body. The fat soluble vitamins are soluble in lipids (fats).
1 The four fat-soluble vitamins are vitamins A, D, E, and K. 2  There are nine water-soluble vitamins. 3  The body must use water-soluble vitamins right away. 4  Any left over water-soluble vitamins leave the body through the urine. 5  Vitamin B12 is the only water-soluble vitamin that can be stored in the liver for many years. There are nine water-soluble vitamins. 2  The body must use water-soluble vitamins right away. 3  Any left over water-soluble vitamins leave the body through the urine. 4  Vitamin B12 is the only water-soluble vitamin that can be stored in the liver for many years.