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Vitamins are classified as either fat soluble (vitamins A, D, E and K) or water soluble (vitamins B and C). This difference between the two groups is very important. It determines how each vitamin acts within the body. The fat soluble vitamins are soluble in lipids (fats).
1 The difference (if any) between vitamins that are water soluble and those that are not -- There is a big difference between the water soluble vitamins and the fat soluble vitamins and this is absolutely a critical distinction.  2 Specifically Vitamin E -- Vitamin E is a fat soluble vitamin. Specifically Vitamin E -- Vitamin E is a fat soluble vitamin. 2  Although it can be water solubilized in the lab to help its absorption through the intestinal wall, once it is absorbed into the body it would appear to behave as a fat soluble vitamin does.