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No worries about cooking for the week. They'll be safe to eat, but in our house they'd never last that long. I'd probably nibble away at them. Depends on the vegetable and how it was cooked. Safety-wise, 3-5 days should be fine for pretty much all of it, but optimum nutrition, taste, and texture are going to vary.
Properly stored, cooked rice will last for 4 to 6 days in the refrigerator. How long can cooked rice be left at room temperature? Bacteria grow rapidly at temperatures between 40 Â°F and 140 Â°F; rice should be discarded if left out for more than 2 hours at room temperature.