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The NO2 Lewis structure has a total of 17 valence electrons. It's not common to have an odd number of valence electrons in a Lewis structure. Because of this we'll try to get as close to an octet as we can on the central Nitrogen (N) atom.This will mean that it will only have 7 valence electrons.or the NO2 Lewis structure, calculate the total number of valence electrons for the NO2 molecule. After determining how many valence electrons there are in NO2, place them around the central atom to complete the octets. It is helpful if you:
nitrogen by itself is a diatomic molecule at STP (and pretty much in all conditions for that matter). This is so because Nitrogen has 5 valence electrons so each shares 3 electrons with the other. This gives each an unshared electron pair plus the 6 being shared between the two Nitrogen atoms.