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Pimento Cheese. Pimientos are large, sweet, heart-shaped peppers that are typically used for canning. Pimento cheeseâthe simple combination of grated cheddar cheese with mayonnaise and pimientosâis a Southern staple often served on crackers or vegetables.imento cheeseâthe simple combination of grated cheddar cheese with mayonnaise and pimientosâis a Southern staple often served on crackers or vegetables.
Pimentos start out in life as a variety of chili pepper called âcherry peppers.â Small and red (hence the name), they are sweeter than bell peppers and very mild, with the lowest Scoville scale rating of all the chilies.