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Next is the Stalactite layer, where you'll find iron. Then the lava layer, which has diamonds. Finally the corrupt layer, with diamonds and lumite. Best bet for finding obsidian is to check all the surface caves in the area. If one cave doesn't have any, move onto the next one. Eventually you'll hit a vein.
The translation into English of Natural History written by Pliny the Elder of Rome shows a few sentences on the subject of a volcanic glass called obsidian (lapis obsidianus), discovered in Ethiopia by Obsidius, a Roman explorer. Obsidian is the rock formed as a result of quickly cooled lava, which is the parent material.