1. Electrophilic substitution reaction. Table: Various electrophilic substitution reactions of Benzene. 1  Reaction of AlCl 3 with chlorine molecule (Cl 2) to form Chlorinium ion (Cl +) which acts as electrophile and attack on benzene ring.ince six pi electrons are delocalized over whole ring, therefore the cyclically conjugated double bonds represents by a circle and the carbon-carbon bond length becomes equal. This structure of benzene is called as resonance hybrid of benzene and generally used to represents the benzenemolecule.
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