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When a level of 0.3 ppm is reached, a good pool shocking is indicated. Shocking the pool to a level that is 100x greater than your chloramine is effective at chloramine removal. For a level at 0.3 ppm CAC, add enough chlorine to reach a level of 30 ppm in the pool. Chlorine is a great algaecide, I like to say.
Pool shock is either chlorine or non-chlorine chemicals that you add to the pool to destroy any contaminates in the water. The goal is to raise the free chlorine levels to a point where it will destroy any algae or bacteria growing in the pool.