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Calcium: Because of the nearly proving migraine prevention power of magnesium, migraine supplements will also often contain calcium, which is necessary for the effective use of magnesium. 3. Vitamin B2: The ability to calm the brain down is the secret to this potential migraine reducer.itamin B6: Responsible for helping to produce dopamine, serotonin and histamine, healthy levels of B6 are important to reduce allergy triggered migraines. 7. Vitamin B9: B9 is used to treat depression, inflammation and headaches and is showing promise as a potential prevention supplement. 8.
Getting to Know the B Vitamins. 1  1. Know that there are 8 vitamins in the B group. 2  2. Get more B1 (thiamine) to support a healthy immune system. 3  3. Eat foods rich in B2 (riboflavin) for healthy skin and to avoid headaches.  4. Take B3 (niacin) to boost your levels of HDL (good cholesterol), particularly if you drink regularly.