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Vitamins for headaches, such as B2 and niacin may provide headache relief. Good nutrition is the foundation to good health. For each one of us to function property we need a sufficient supply of over forty key nutrients. The bottom line is, vitamins are essential to you, and me for health and growth.he daily dose for relief of migraines and headaches would be around 400mg taken for several months. The top vitamin for headache hands down, is B2 or Riboflavin, and evidence shows that a migraine sufferer may have a lifelong deficiency of some forms of this vitamin. Vitamin B can be destroyed by excessive amounts of:
1 Vitamin A and beta-carotene-necessary for night vision. 2  Vitamin B complex-the B complex vitamins may help prevent high homocysteine levels developing in the blood. 3  These are associated with vascular problems that affect the retina.4  Vitamin C-may reduce the risk of cataracts. Vitamin A and beta-carotene-necessary for night vision. 2  Vitamin B complex-the B complex vitamins may help prevent high homocysteine levels developing in the blood. 3  These are associated with vascular problems that affect the retina.