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This basically means that the digits of pi that are to the right of the decimal go forever without repeating in a pattern, and that it is impossible to write the exact value of pi as a number. Pi can only be approximated, or measured to a value that is close enough for practical purposes. A value close to pi is 3.1415926535987932384626433...
Pi doesn't equal any number of degrees because pi without a unit is just a number. The point is that pi radians is equal to 180 degrees. Radians are a unit of measurement for angles, just like degrees are, and pi is just the number of radians that makes up that angle. Just as one radian is equal to 57.3 degrees (approximately).