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(a) The specific heat capacity at constant volume (c v) is defined as the quantity of heat required to raise the temperature of 1 kg of the gas by 1 K if the volume of the gas remains constant.he molar heat capacity at constant volume (C V) is the quantity of heat required to raise the temperature of 1 mole of the gas by 1 K if the volume of the gas remains constant.
Boiling occurs when the vapor pressure reaches or exceeds the surrounding pressure from the atmosphere or whatever else is in contact with the liquid. At standard atmospheric pressure (1 atmosphere = 0.101325 MPa), water boils at approximately 100 degrees Celsius. That is simply another way of saying that the vapor pressure of water at that temperature is 1 atmosphere. At higher pressures (such as the pressure generated in a pressure cooker), the temperature must be higher before the vapor pressure reaches the surrounding pressure, so water under pressure boils at a higher temperature.