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(A) Calculate the specific heat capacity at constant volume of water vapor, assuming the nonlinear tri-atomic molecules has three translational and three rotational degree of freedom and that vibrational motion does not contribute. The molar mass of water is 18 g/mol.(B) The actual specific heat capacity of water vapor at low pressure is about 2000 J/kg*K. Compare this with your calculation and comment on the actual role of vibrational motion.he molar mass of water is 18 g/mol. (B) The actual specific heat capacity of water vapor at low pressure is about 2000 J/kg*K. Compare this with your calculation and comment on the actual role of vibrational motion.
In vapor-pressure terms, the boiling point of water is the temperature at which the vapor pressure of the liquid is equal to that of the gas phase. Lower the surrounding pressure and you lower the boiling point, but the liquid will still not evaporate if you have 100% relative humidity.