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The Cause of the Peloponnesian War. The immediate cause of the Peloponnesian War was Corinthian opportunism. Thucydides is mistaken in his famous assertion that [w]hat made war inevitable was the growth of Athenian power and the fear which this caused in Sparta.Both powers had demonstrated a reluctance for head-on war over matters peripheral to their respective spheres of influence.f we define the Peloponnesian War as that which began in 432/1 between the Peloponnesian League and the Athenian Empire, and if we accept the preponderance of the evidence available to us, then its etiology is manifest: The cause of the war was Corinthian aggression.
In a sense, the Peloponnesian war opened the door for the rise of the Kingdom of Macedon. From 350 - 338 BCE the kingdom of Macedon moved in from the north and conquered much of Greece, taking advantage of weak and disunited city-states.