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(A) Calculate the specific heat capacity at constant volume of water vapor, assuming the nonlinear tri-atomic molecules has three translational and three rotational degree of freedom and that vibrational motion does not contribute. The molar mass of water is 18 g/mol.(B) The actual specific heat capacity of water vapor at low pressure is about 2000 J/kg*K. Compare this with your calculation and comment on the actual role of vibrational motion.he molar mass of water is 18 g/mol. (B) The actual specific heat capacity of water vapor at low pressure is about 2000 J/kg*K. Compare this with your calculation and comment on the actual role of vibrational motion.
The vapor pressure of any substance increases non-linearly with temperature according to the ClausiusâClapeyron relation. The atmospheric pressure boiling point of a liquid (also known as the normal boiling point) is the temperature at which the vapor pressure equals the ambient atmospheric pressure.quilibrium vapor pressure can be defined as the pressure reached when a condensed phase is in equilibrium with its own vapor. In the case of an equilibrium solid, such as a crystal, this can be defined as the pressure when the rate of sublimation of a solid matches the rate of deposition of its vapor phase.