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UPS Corporate Office Headquarters HQ. UPS is famous for shipping parcels worldwide. UPS is the largest package shipper in the world. UPS's main competitor is Fedex and the US Postal Service USPS. UPS's toll-free customer service number is 1-800-742-5877.
Quick Answer. The phone number for the UPS national human resources department is 1-800-877-1508 as of 2015. This line is primarily used for salary and employment verification by former employees, although live employee assistance is provided. There are also many regional human resources offices with phone numbers that vary depending on location.