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UPS Corporate Office Headquarters HQ. UPS is famous for shipping parcels worldwide. UPS is the largest package shipper in the world. UPS's main competitor is Fedex and the US Postal Service USPS. UPS's toll-free customer service number is 1-800-742-5877.
If you have any questions about shipping hazardous materials with UPS, please call the UPS Hazardous Materials Support Center at 1-800-554-9964. Note: The Emergency telephone number in conjunction with the E.R. Registrant information (when required) must be listed in accordance with IATA USG-12 and D.O.T.