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Energy is absorbed to break bonds. Bond-breaking is an endothermic process. Energy is released when new bonds form. Bond-making is an exothermic process. Whether a reaction is endothermic or exothermic depends on the difference between the energy needed to break bonds and the energy released when new bonds form. If more heat energy is released when making the bonds than was taken in when they broke, the reaction is exothermic.
Strain energy. In a molecule, strain energy is released when the constituent atoms are allowed to rearrange themselves in a chemical reaction or a change of chemical conformation in a way that: âangle strain, âtorsional strain, âring strain and/or steric strain, âAllylic strain, and âpentane interference are reduced.he strain energy in the form of elastic deformation is mostly recoverable in the form of mechanical work. For example, the heat of combustion of cyclopropane is higher than that of propane for each additional CH2 unit.