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Low and slow is the way to go for pulled pork. How large is your pork and what temp is the oven set at? When the meat is fork-tender, it's done. I don't usually bother with a thermometer, but 180 should be a good temp. Let it cook a little while longer, and serve some cocktails and nibbles to the anxious guests while they wait.
The weekend before the fourth of July I cooked a Boston butt for the first time. I cooked it outside on a gas grill (for shame ;-) ) @ 350 deg. for four hours. We made pulled pork out of it. Everyone loved it so much that they wanted me to cook one again this weekend. This one is bigger - 12 lbs vs. the other one which was, well - about 2/3's of that size. I think that some suggest around 30 or 45 min per pound at 350 deg. So, that would mean 6 - 9 hours for that heat level.