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The theme song to Psych, I Know, You Know, is performed by series creator Steve Franks and his band, the Friendly Indians. WIKI. You can download the MP3 from the link I am providing. These lyrics were all I could find off of someone's blog.
The TV song is known as Nadia's Theme, although it was originally titled Cotton's Dream.. The sample was very fitting for this song, as drama is very much associated with the show. The writers of the theme - Perry Botkin and Barry Vorzon - are credited as writers on No More Drama because of the sample.