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Rusting is an oxidation reaction. The iron reacts with water and oxygen to form hydrated iron(III) oxide, which we see as rust. Here is the word equation for the reaction: iron + water + oxygen â hydrated iron(III) oxide. In the experiment below, the nail does not rust when air-containing oxygen-or water is not present:usting is an oxidation reaction. The iron reacts with water and oxygen to form hydrated iron(III) oxide, which we see as rust. Here is the word equation for the reaction: iron + water + oxygen â hydrated iron(III) oxide. In the experiment below, the nail does not rust when air-containing oxygen-or water is not present: