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Wine vinegars do still contain some level of alcohol. The vinegar taste is actually due to acetic acid, but the chemical transformation is never fully complete just sitting around a kitchen. Vinegar would be much too gross to drink in the quantity it would take to intoxicate anyone.
Substitutes for Red Wine Vinegar. Red wine vinegar also has a mild taste and shouldn't be substituted with vinegar that is too strong. For red wine vinegars used for a dressing, a good substitute is 3 tbsp of cider vinegar and 1 tbsp of red wine for every 4 tbsp of red wine vinegar. Although red wine vinegar has a slightly stronger taste than white wine vinegar, they can often be used interchangeably on a 1 to 1 basis.