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The 10 biggest silver mines in the world. Mexico, the world's biggest silver producing country, and Poland host three each of the world's 10 biggest silver mines. Bolivia, Turkey, Peru and Australia host the remaining four. Mining-technology.com profiles the 10 biggest silver mines in the world, based on contained silver reserves.
Throughout the 17th and 18th centuries, the state remained Mexicoâs most prolific mining center. In 1772, silver was discovered in the local mountains of Real de Catorce, located in San Luis PotosÃ­âs desert region.