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In organic chemistry sigma bonds (Ï) are always the first bond between two atoms, resulting from overlap along the bonding axis (of hybrid orbitals), while pi bonds (Ï) are second and third bonds resulting from the overlap of p orbitals, above and below (or in front and back of) the bonding axis.
Covalent bonds include interactions of the sigma and pi orbitals; therefore, covalent bonds lead to formation of single, double, triple, and quadruple bonds. Example 2: \(PCl_3\) In this example, a phosphorous atom is sharing its 3 unpaired electrons with 3 chlorine atoms.