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In organic chemistry sigma bonds (Ï) are always the first bond between two atoms, resulting from overlap along the bonding axis (of hybrid orbitals), while pi bonds (Ï) are second and third bonds resulting from the overlap of p orbitals, above and below (or in front and back of) the bonding axis.
The electron density of these two bonding electrons is concentrated in the region between the two atoms, which is the defining quality of a sigma bond. Two p-orbitals forming a pi-bond. A double bond between two atoms is formed by the sharing of two pairs of electrons, one in a sigma bond and one in a pi bond, with electron density concentrated on two opposite sides of the internuclear axis.