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Wash the brush with ordinary water. Add a coat of gloss or semi-gloss latex paint to the primed plywood furniture using a mini roller. Apply to a small area and then smooth the paint using the cleaned brush. Continue until the plywood furniture is completely coated.
MDF offers a smoother surface than plywood, making it the optimal choice for painted cabinets, according to the National Kitchen and Bath Association. Plywood generally won't look as smooth or polished when painted, and is best used with a veneer finish rather than paint or stains.