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In organic chemistry sigma bonds (Ï) are always the first bond between two atoms, resulting from overlap along the bonding axis (of hybrid orbitals), while pi bonds (Ï) are second and third bonds resulting from the overlap of p orbitals, above and below (or in front and back of) the bonding axis.
Double and triple covalent bonds are stronger than single covalent bonds and they are characterized by the sharing of four or six electrons between atoms, respectively. Double and triple bonds are comprised of sigma bonds between hybridized orbitals, and pi bonds between unhybridized p orbitals.