The ground state electron configuration for phosphorus is P: 1s^(2) 2s^(2) 2p^(6) 3s^(2) 3p^(3) I'll use the noble gas shorthand notation from this point on. P: [Ne] 3s^(2) 3p^(3) Now, an excited state configuration has one electron promoted from a lower to a higher energy level. Looking at the ground state configuration, you could have one electron from the 3s sub-level promoted to the 3p sublevel.
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