Out here in the stroma, a bunch of different enzymes use the carbon dioxide molecules and hydrogen ions made during the light dependent phase to assemble sugar fragments which are half of a glucose molecule (just 3 carbon atoms, instead of the 6 required to make a complete glucose molecule).
An alkane, by definition, only has single bonds. Even if your second diagram made sense (it doesn't for the reason above) it would not be an alkane at all because there is a double bond. Alkanes are a functional group. It's called alkil. As a functional group they have the generic formula R(CH2)nH.
There are a number of functional groups that contain a carbon-oxygen double bond, which is commonly referred to as a carbonyl. Ketones and aldehydes are two closely related carbonyl-based functional groups that react in very similar ways. In a ketone, the carbon atom of a carbonyl is bonded to two other carbons.