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Cocoa beans contain caffeine, so the higher the percentage of cocoa in a chocolate bar, the higher its caffeine content. Likewise for coffee: Ounce for ounce, the more diluted the coffee drink, the less caffeine.
Keri Glassman. A byproduct of cocoa beans, cocoa powder is what is left over after cocoa butter is extracted from the bean. While cocoa butter is high in fat and calories, the powder is low in calories, loaded with fiber and nutrients, and provides a host of health benefits. Studies have shown that cocoa powder is associated with decreased blood pressure and improved cholesterol levels. These heart-healthy benefits can be attributed to the flavonoids found in cocoa.