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Home Â» Nonpolar molecule. Definition. noun, plural: nonpolar molecules. A molecule with nonpolar bonds or with polar bonds but arranged symmetrically. Supplement. Polar bonds may occur in both polar and nonpolar molecules. However, the polar bonds in nonpolar molecules are arranged symmetrically causing dipoles to cancel out each other. As a result, nonpolar molecules have no net dipole. An example of a nonpolar molecule with nonpolar bonds is H2 whereas a nonpolar molecule with polar bonds is CH4.
Within a molecule each polar bond has a bond dipole; A polar molecule always contains polar bonds, but some molecules with polar bonds are nonpolar. Polar Molecule. A molecule in which the bond dipoles present do not cancel each other out and thus results in a molecular dipole.(see below). Cancellation depends on the shape of the molecule or Stereochemistry and the orientation of the polar bonds. A result of the bond dipoles in a molecule. Examples: CO2 is a linear molecule with 2 bond dipoles that are equal and oppositely directed therefore the bond polarities cancel and the molecule is nonpolar.