In 1966, Buckley began hosting Firing Line, a political talk show on National Educational Television, the forerunner of PBS. 1,429 weekly episodes were produced over the next 33 years, until Buckley stepped down in 2000.
Hence, the anion of a ketone, where there are extra alkyl groups is less stable than that of an aldehyde, and so, a ketone is less acidic. In the ester, there is also a resonance donation from the alkoxy group towards the carbonyl that competes with the stabilisation of the enolate charge.
Ch18 Ketones and Aldehydes (landscape) Page 5 A ketone or aldehyde group can also be named as a substituent on a molecule with another functional group as its root. The ketone carbonyl is given the prefix oxo -, and the aldehyde group is named as a formyl-group.(This is especially common for carboxylic acids).h18 Ketones and Aldehydes (landscape) Page 13 However, to circumvent this problem, carboxylic acids can be converted first into a functional group that is easier to reduce than an aldehyde group. The group of choice is an acid chloride.