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Carbonic acid, which is a weak acid, forms when rainwater and carbon dioxide in the air react with one another. When carbonic acid comes into contact with limestone or calcium carbonate, it can cause it to dissolve over a long period of time. In nature, this reaction leads to the formation of caves.
It isn't so much soluble in vinegar as much as it reacts with the acetic acid. Vinegar is a mixture of 5% acetic acid in water. The calcium carbonate, which is insoluble i â¦ n water, reacts with the acetic acid to produce water, carbon dioxide, and calcium acetate.The calcium acetate is water soluble.2 people found this useful.inegar is a mixture of 5% acetic acid in water. The calcium carbonate, which is insoluble i â¦ n water, reacts with the acetic acid to produce water, carbon dioxide, and calcium acetate. The calcium acetate is water soluble. 2 people found this useful.