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Apart from spawning in swamps (added in 1.4), slimes can only spawn in every 10th chunk in average (Slime Chunks). Chunks are 16x16 blocks wide (x and z axis) and 256 blocks high (y axis). Slime Chunks are predetermined by your savegame seed, and are always the same for a specific seed, just like the generated terrain.
You can only identify slime chunks if they spawn slimes in the chunk. Check in swamps at night, but it is best to look for them on the night of a full moon. Thanks! No, but it can spawn in swamps, lakes, and (rarely) in grassy biomes.