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There are 0 calories in a 1 can serving of La Croix Sparkling Water. Calorie breakdown: 0% fat, 0% carbs, 0% protein.
The sparkling part is carbon dioxide. If it's just sparkling water, then no it's not pop. It's just fizzy water. If it has added sugar or artificial sweeteners and flavourings then it would be similar to pop. I suppose it depends what aspect of pop you're trying to give up - sugar, artificial additives or bubbles.