In 1966, Buckley began hosting Firing Line, a political talk show on National Educational Television, the forerunner of PBS. 1,429 weekly episodes were produced over the next 33 years, until Buckley stepped down in 2000.
Hence, the anion of a ketone, where there are extra alkyl groups is less stable than that of an aldehyde, and so, a ketone is less acidic. In the ester, there is also a resonance donation from the alkoxy group towards the carbonyl that competes with the stabilisation of the enolate charge.
Aldehyde vs Ketone. Aldehydes and ketones are known as organic molecules with a carbonyl group. In a carbonyl group, carbon atom has a double bond to oxygen. The carbonyl carbon atom is sp2 hybridized. So, aldehydes and ketones have a trigonal planar arrangement around the carbonyl carbon atom. The carbonyl group is a polar group, thus, aldehydes and ketones have higher boiling points compared to the hydrocarbons having the same weight.