In 1966, Buckley began hosting Firing Line, a political talk show on National Educational Television, the forerunner of PBS. 1,429 weekly episodes were produced over the next 33 years, until Buckley stepped down in 2000.
Hence, the anion of a ketone, where there are extra alkyl groups is less stable than that of an aldehyde, and so, a ketone is less acidic. In the ester, there is also a resonance donation from the alkoxy group towards the carbonyl that competes with the stabilisation of the enolate charge.
Physical Properties Aldehydes and ketones are polar because they contain a carbonyl group (oxygen is very electronegative compared to carbon). Aldehydes and ketones can form hydrogen bonds with water, so small aldehydes and ketones are water-soluble.