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Most all citrus, oranges included, are naturally acidic on their exterior, but all fruits and vegetables promote an alkaline body once eaten. Oranges are a star here due to their high enzyme content, cleansing properties and immune-boosting properties.
Note that a food's acid or alkaline forming tendency in the body has nothing to do with the actual pH of the food itself. For example, lemons are very acidic, however the end products they produce after digestion and assimilation are very alkaline so, lemons are alkaline forming in the body. Likewise, meat will test alkaline