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Why ice is lighter than water? Hydrogen bonding gives ice a rather open structure with wide holes. Thus for same volume of water and ice , ice has less mass so it is lighter than water.
Hot water will certainly evaporate faster, and produce a lot more condensation than cold water, and that's what we are seeing here. The water itself is not freezing, it's the evaporation (the steam) that is condensing and then freezing. So boiling water will produce more ice fog than cold water.