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Textile fibers are normally broken down into two main classes, natural and man-made fibers. All fibers which come from natural sources (animals, plants, etc.) and do not require fiber formation or reformation are classed as natural fibers.
More Info: Though rayon may start out as a natural fiber, the chemicals through which it is processed transform it to a synthetic fiber. The American Heritage Dictionary defines rayon as any of several synthetic textile fibers produced by forcing a cellulose solution through fine spinnerets and solidifying the resulting filaments.