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Vodka is made by the process of distillation of a fermented substance--often potatoes and rye or wheat grain--and less often, sugar beet molasses. Most vodka was traditionally made from potatoes and corn, but in recent years, most high-quality brands of vodka has been distilled from cereal grains.
Users claim it is the starch from the potatoes (vodka is made from potatoes) that stiffens the fabric. To make vodka spray starch you simply mix one part vodka to two parts water (I ued 1/3 cup vodka and 2/3 cup water).