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The itchy sensation you feel when a wound heals is coming from sensitive nerve cells that are reacting to both chemicals being released and structural stretch on the surrounding skin and wound tissue.
First, an immune response causes the wound to become inflamed to prevent infections. Second, new cells (a scab) form over the wound, and finally scar tissue forms to heal the wound. Some wounds heal easily while others can take longer, particularly if they are severe or the individual has a poor state of health.