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The Karman line, at 100 km (62 miles), is also frequently used as the boundary between atmosphere and outer space. For all intents and purposes, space starts at about 62 miles. And no, it has absolutely zero to due with the Earth's gravity.
As it approaches our Roche limit (approximately 28,300 km from the surface), it begins to break up 23.6 minutes before impact. At about 120 km above the ground the pieces encounter a tenuous atmosphere. In the next few seconds before impact many more pieces are created from atmospheric shock.