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One way to measure a bond's volatility is to track its spread against another bond. Basically, you will need to compare the bond's performance over time to a relatively stable bond. The most stable bonds are US Government Bonds. Start with a federal bond and track interest rate over a time period of 1 to 5 years.
Usually the wider range of fluctuations (higher volatility) means higher trading risks involved. In this manner volatility is esteemed as a random value and its mathematical modeling provides basis for all risk assessment methods, used on Foreign Exchange market. For volatility measurement statistical standard deviation is calculated. It also determines exposure of financial investments.