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One way to measure a bond's volatility is to track its spread against another bond. Basically, you will need to compare the bond's performance over time to a relatively stable bond. The most stable bonds are US Government Bonds. Start with a federal bond and track interest rate over a time period of 1 to 5 years.
There are many different types of volatility, but options traders tend to focus on historical and implied volatilities. Historical volatility is the annualized standard deviation of past stock price movements. It measures the daily price changes in the stock over the past year.