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Caffeine is absorbed by your hair follicles when used topically. The main study found that caffeine works by blocking the effects of a chemical known as DHT, which is known for its role in hair loss. It takes at least 2 minutes for caffeine to begin penetrating the scalp.
Hormones are a possible trigger for the curly hair gene. As well as affecting the quality of your hair, hormones can change your muscle tone too. This includes your scalp. The change of muscle tone could affect the shape of your hair follicles and their direction of growth. Straight hair follicles grow straight out but curly hair follicles have a hook shape. With my hair, puberty was the when my curls decided to appear and this fits with the hormone changes. For many women, pregnancy and birth have a significant impact on their hair too.