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When the reactants are heated, the average kinetic energy of the molecules increases. This means that more molecules are moving faster and hitting each other with more energy. If more molecules hit each other with enough energy to react, then the rate of the reaction increases.
Rate-limiting reaction is the slowest reaction in a series of reactions. It is used to calculate the rate law of the overall reaction. Recall from thermochemistry that slow reactions tend to have higher activation energy (energy âhillâ). Slower reactions have to climb a higher energy hill to produce transition states and, subsequently, products; therefore, rate-limiting reaction will have the highest activation energy of all reactions in the series.