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When the reactants are heated, the average kinetic energy of the molecules increases. This means that more molecules are moving faster and hitting each other with more energy. If more molecules hit each other with enough energy to react, then the rate of the reaction increases.
There are several factors that can influence chemical reaction rate. In general, a factor that increases the number of collisions between particles will increase the reaction rate and a factor that decreases the number of collisions between particles will decrease the chemical reaction rate.