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Adj. 1. immiscible - (chemistry, physics) incapable of mixing. non-miscible, unmixable. natural philosophy, physics-the science of matter and energy and their interactions; his favorite subject was physics.
Solubility of a solid in water (without reaction) suggests it is ionic. There are exceptions to this, of course. Sugar (sucrose) is soluble in water despite being a covalent molecule. It is capable of extensive hydrogen bonding with water molecules. And there are a lot of ionic compounds which are insoluble in water, of course.