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The main emissions of a car engine are: 1  Nitrogen gas (N2) - Air is 78-percent nitrogen gas, and most of this passes right through the car engine. 2  Carbon dioxide (CO2) - This is one product of combustion. 3  Water vapor (H2O) - This is another product of combustion.
Evidently there's a coolant leak. If the car is blowing white smoke out the exhaust and has a sweet smell, then you have a blown head gasket - the coolant is entering the combustion chamber and being burned. If not, then the leak is elsewhere.