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Any of various solid substances, such as silicon or germanium, that conduct electricity more easily than insulators but less easily than conductors. Semiconductors are able to do this because they have a small number of electrons that have escaped from the bonds between the atoms, leaving open spaces.ny of various solid substances, such as silicon or germanium, that conduct electricity more easily than insulators but less easily than conductors. Semiconductors are able to do this because they have a small number of electrons that have escaped from the bonds between the atoms, leaving open spaces.
Silicon tends to resemble germanium far more than it does carbon, and this resemblance is enhanced by the d-block contraction resulting in the size of the germanium atom being much closer to that of the silicon atom than periodic trends would predict.