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the half life of the amount of caffeine in a normal severing (8oz) of coffee is 5 hours, meaning that the effects of the coffee will last 5 hours... Well caffiene does honestly depend on how reactive you are to stimulants, I am in concerta 27mg and I accidentally ate some chocolate today a Swiss roll specifically.
How long does coffee stay fresh? A good rule to use is two weeks. Now, if you happen to have found a great price on bulk coffee, and you don't plan on using it within two weeks, the freezer can be an acceptable one-time shot. What this means is that once you take it out of the freezer, it should never go back in.