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PU is an exaggerated pronunciation of pew, an interjection that is appropriate when you smell something foul.
Pure natural gas is colourless and odourless. This means if there is a leak people will not be able to detect it until it builds up enough to become explosive. For this reason a chemical called Mercaptan is added to the gas to make is smell. Mercaptan is harmless, non-toxic and has a strong rotten egg smell.