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Bitters usually do contain an alcohol content, with some ranging as high as 45%. However, it would be pretty hard to get a buzz from bitters because they are usually used in such small amounts to flavor a drink.
What Drinks Do You Put Bitters In? By Eric Jeffs Just as the name says, bitters are an alcoholic spirit with a bitter or bittersweet flavor made from a mixture of plants and herbs. Bitters were originally sold as medicine since...  Bitters were originally sold as medicine since they are known to aid digestion. Many popular and retro cocktails contain bitters but only in small amounts since the flavor is extremely potent.