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Bitters usually do contain an alcohol content, with some ranging as high as 45%. However, it would be pretty hard to get a buzz from bitters because they are usually used in such small amounts to flavor a drink.
You can also try to make your own recipe. Other options for citrusy bitters include Scrappy's Bitters in lime and Fee Brothers in lemon. Add a kick to your drinks with bitters that recall spicy cuisines like Mexican and Thai. Parsons recommends Bittermens Xocolatl mole bitters, which contains cacao, cinnamon, and spices and is recommended for use with aged liquors. Bad Dog's Fire and Damnation bitters contains a hint of smoke and capsaicin spice.