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PU is an exaggerated pronunciation of pew, an interjection that is appropriate when you smell something foul.
Thanks for the answer request. I'm not a vet so i don't really know. My guess is that what you're smelling are sulphurous compounds associated with garlic and onions. Perhaps review what your donkey is eating. Some vegetables such as cabbage and other Brassicas can cause gas and sulphurous smells in humans, perhaps donkeys too.