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Bitters usually do contain an alcohol content, with some ranging as high as 45%. However, it would be pretty hard to get a buzz from bitters because they are usually used in such small amounts to flavor a drink.
Additives make this alcohol bitter-tasting, to try to prevent people from drinking it. Isopropyl alcohol is toxic, in part because the body metabolizes it into acetone. Drinking this alcohol can cause headache, dizziness, nausea, vomiting, central nervous system depression, organ damage and potentially coma or death.