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While Ichigo Kurosaki underwent training to gain his own Shinigami powers, Kisuke Urahara puts Ichigo's soul through a process called Encroachment, where if Ichigo does not gain Shinigami powers on his own, he will become a Hollow. Tessai Tsukabishi severs Ichigo's Chain of Fate.
Now this episode was seriously OMG. It was amazing. I really hate Muramasa. I think he doesn't belong to anyone. I bet he is tricking everyone. I felt sorry for Ichigo. He was in such pain when Zangetsu was pulled out. That had to hurt. Zangetsu was overpowering Ichigo. He barely said a word to him even if he's his Zanpakutou. That is not cool. I thought that would be the end for Ichigo but no. I was so surprised when his inner hollow took control.