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Actually potatoes that are left out overnight are perfectly fine to eat. as long as they do not have much milk or butter on them. even if they have butter they will be fine to eat. plain cooked potatoes, such as baked can stay out for up to 3 days.
Quick Answer. Soak raw potatoes in water for several hours when they are left sitting out without any harmful effects, or soak them overnight as long as they are refrigerated. Soaking raw potatoes in water helps to remove amylose, which is the starch molecule responsible for giving mashed potatoes a paste-like texture.