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An alkaline solution is one that is a pH higher than 7.0. For instance, venous blood, at a pH of 7.3, is an alkaline solution, as is household ammonia at a pH of 12. Generally, as you advance from 7.1 up through a pH of 14, the concentration of hydroxyl ions (OH-) also increases in solution.
Your question is confusing, since you state the answer in your question. Alkaline water, with a low pH, is high in negative ions, such as OH. Acidic water is high in positive ions, such as H. Acidic water (pH 4-6) is carrying positive charges and alkaline water(pH 9.5) is carryiing negative charges.