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An alkaline solution is one that is a pH higher than 7.0. For instance, venous blood, at a pH of 7.3, is an alkaline solution, as is household ammonia at a pH of 12. Generally, as you advance from 7.1 up through a pH of 14, the concentration of hydroxyl ions (OH-) also increases in solution.
An alkali is any substance that produces OH-ions in water. Compare this with the definition of an definition of an acid. OH-ions are called hydroxide ions. An alkali has a pH of more than 7. substance that will neutralise an acid, but does not dissolve in water, is called a base. For example, copper(II) oxide, iron(II) oxide and zinc carbonate are bases, they do not dissolve in water (see salts made from bases or carbonates). Any base that dissolves in water is called an alkali.