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If size is important to you... The average discharge of water into the Atlantic Ocean by the Amazon is approximately 175,000 m3 per second, or between 1/5th and 1/6th of the total discharge into the oceans of all of the world's rivers!
The actual river with the name Amazon runs through Peru and then Brazil. But when you consider all the tributaries of the Amazon that contribute to its flow, then we can also include Bolivia, Equador, Colombia, and a little bit of Venezuela. See map here: http://www.rainforesteducation.com/photo...