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An alkaline solution is one that is a pH higher than 7.0. For instance, venous blood, at a pH of 7.3, is an alkaline solution, as is household ammonia at a pH of 12. Generally, as you advance from 7.1 up through a pH of 14, the concentration of hydroxyl ions (OH-) also increases in solution.
The reason alkalinity is sometimes confused with pH is because the term alkaline is used to describe pH conditions greater than 7 (basic). The most important compounds in water that determine alkalinity include the carbonate (CO3 2-) and bicarbonate (HCO3 -) ions.arbonate ions are able to react with and neutralize 2 hydrogen ions (H +) and the bicarbonate ions are able to neutralize H + or hydroxide ions (OH -) present in water. The ability to resist changes in pH by neutralizing acids or bases is called buffering.