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Caffeine by Starbucks Decaf Coffee Cup Size. The above amounts are posted by Starbucks, however, other independent tests found different results. Tests undertaken by the University of Florida showed that a 16oz serving of decaffeinated brewed coffee had caffeine concentrations of 12 to 13.4 milligrams.
So UF researchers set out to conduct a two-phase study designed to gauge just how much caffeine is likely to turn up in decaffeinated coffees. First they purchased 10 16-ounce decaffeinated drip-brewed coffee beverages from nine national chains or local coffee houses and tested them for caffeine content.