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Three oxygen compounds of iron are known: ferrous oxide, FeO; ferric oxide, Fe2O3; and ferrosoferric oxide, or ferroferric oxide, Fe3O4, which contains iron in both +2 and +3 oxidation states. Ferrous oxide is a greenish to black powder used primarily as a pigment for glasses.
Rusting is an oxidation reaction. The iron reacts with water and oxygen to form hydrated iron(III) oxide, which we see as rust. Here is the word equation for the reaction: iron + water + oxygen â hydrated iron(III) oxide. In the experiment below, the nail does not rust when air-containing oxygen-or water is not present:usting is an oxidation reaction. The iron reacts with water and oxygen to form hydrated iron(III) oxide, which we see as rust. Here is the word equation for the reaction: iron + water + oxygen â hydrated iron(III) oxide. In the experiment below, the nail does not rust when air-containing oxygen-or water is not present: