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An XMP file is a metadata file used by Adobe programs such as Photoshop and Bridge. It contains the edits made to a camera raw file, such as a .CR2 or .NEF file, and is automatically generated and saved in the same directory as the corresponding camera raw file.
The TMP file type is primarily associated with Temporary File/Folder and is used for a wide variety of tasks. After these files have served the purpose for which they were created, they are usually deleted. There is software that create temporary files and then leave them behind without deleting them.