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The superior vena cava is a large vein located in the upper chest, which collects blood from the head and arms and delivers it back to the right atrium of the heart.he superior vena cava is a large vein located in the upper chest, which collects blood from the head and arms and delivers it back to the right atrium of the heart.
Superior vena cava syndrome is caused by the partial blockage of the superior vena cava, which is the vein that carries blood from the head, neck, chest, and arms to the heart.