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Making the world better, one answer at a time. I think both phosphorylases as well water molecules (hydrolysis) can break those P-O-P bonds in ATP.
ATP works like a rechargeable battery. Energy can be released by converting ATP to ADP, which is the uncharged form. Likewise, by binding to a third phosphate group, ADP can be converted back to ATP, the charged form. When you eat lunch, many complex chemical reactions occur.