Structure of Haemoglobin: Haemoglobin is an aggregation of four globular proteins (typically two alpha and two beta subunits), each with an embedded haeme group. Each haeme group allows the binding of an oxygen molecule.
Here's another intriguing case from the Guinness World Records. In 1964, a 17-year-old high school student named Randy Gardner beat the world record for sleep deprivation by staying awake for 264 hours (11 days) without using any stimulants.
Numerous other, less credible accounts abound, including one of a British woman in 1977 who won a competition to continuously rock in a rocking chair (presumably by a landslide) by doing so for 18 days. Overall, the jury is out on just how long a human could ever stay awake, but perhaps that's a good thing. Acknowledging the injury people might cause to themselves through intentional sleep deprivation, the Guinness Book of Records stopped keeping track of this particular superlative last decade.