Orléans married the Duke of Savoy by proxy at the Palais du Louvre on 4 March 1663. The couple met for the first time at Annecy on 3 April 1663 where they were married officially. The homesick princess soon died at the Royal Palace of Turin childless at the age of 15. She was buried at Turin Cathedral where she rests today. Her husband married again to Marie Jeanne of Savoy by whom he had a son.