Helium was discovered in 1868 by French astronomer Pierre Janssen, who first detected the substance as an unknown yellow spectral line signature in light from a solar eclipse. In 1903, large reserves of helium were found in the natural gas fields of the United States, which is by far the largest supplier of the gas. The substance is used in cryogenics, in deep-sea breathing systems, to cool superconducting magnets, in helium dating, for inflating balloons, for providing lift in airships, and as a protective gas for industrial uses such as arc welding and growing silicon wafers. Inhaling a small volume of the gas temporarily changes the timbre and quality of the human voice. The behavior of liquid helium-4's two fluid phases, helium I and helium II, is important to researchers studying quantum mechanics and the phenomenon of superfluidity in particular, and to those looking at the effects that temperatures near absolute zero have on matter, such as with superconductivity.