qnli question: After what event in France did  asphalt begin to be used for pavements and assorted other uses? sentence: One hundred years after the fall of Constantinople in 1453, Pierre Belon described in his work Observations in 1553 that pissasphalto, a mixture of pitch and bitumen, was used in Dubrovnik for tarring of ships from where it was exported to a market place in Venice where it could be bought by anyone.