Related literature {#sec1}
==================

For related literature, see: Braunstein *et al.* (1997[@bb1]); Catalano *et al.* (2001[@bb3]); Durran *et al.* (2000[@bb4]); Field *et al.* (1997[@bb5]); Kuang *et al.* (1998[@bb6]); Li *et al.* (1996[@bb7]); Newkome (1993[@bb8]).

Experimental {#sec2}
============

 {#sec2.1}

### Crystal data {#sec2.1.1}

\[Pt~2~(C~16~H~11~N~2~)~2~(C~18~H~17~N~2~P)\](ClO~4~)~2~*M* *~r~* = 1343.92Monoclinic,*a* = 14.845 (3) Å*b* = 17.927 (4) Å*c* = 18.481 (4) Åβ = 109.697 (3)°*V* = 4630.5 (18) Å^3^*Z* = 4Mo *K*α radiationμ = 6.25 mm^−1^*T* = 294 (2) K0.40 × 0.20 × 0.10 mm

### Data collection {#sec2.1.2}

Bruker SMART APEX CCD area-detector diffractometerAbsorption correction: multi-scan (*SADABS*; Sheldrick, 1996[@bb9]) *T* ~min~ = 0.225, *T* ~max~ = 0.53322850 measured reflections8097 independent reflections5253 reflections with *I* \> 2σ(*I*)*R* ~int~ = 0.090

### Refinement {#sec2.1.3}

*R*\[*F* ^2^ \> 2σ(*F* ^2^)\] = 0.075*wR*(*F* ^2^) = 0.219*S* = 1.038097 reflections696 parameters16 restraintsH-atom parameters constrainedΔρ~max~ = 2.85 e Å^−3^Δρ~min~ = −2.38 e Å^−3^

 {#d5e580}

Data collection: *SMART* (Bruker, 2007[@bb2]); cell refinement: *SAINT* (Bruker, 2007[@bb2]); data reduction: *SAINT*; program(s) used to solve structure: *SHELXS97* (Sheldrick, 2008[@bb10]); program(s) used to refine structure: *SHELXL97* (Sheldrick, 2008[@bb10]); molecular graphics: *SHELXTL* (Sheldrick, 2008[@bb10]); software used to prepare material for publication: *SHELXTL*.

Supplementary Material
======================

Crystal structure: contains datablocks global, I. DOI: [10.1107/S1600536808024525/hy2138sup1.cif](http://dx.doi.org/10.1107/S1600536808024525/hy2138sup1.cif)

Structure factors: contains datablocks I. DOI: [10.1107/S1600536808024525/hy2138Isup2.hkl](http://dx.doi.org/10.1107/S1600536808024525/hy2138Isup2.hkl)

Additional supplementary materials: [crystallographic information](http://scripts.iucr.org/cgi-bin/sendsupfiles?hy2138&file=hy2138sup0.html&mime=text/html); [3D view](http://scripts.iucr.org/cgi-bin/sendcif?hy2138sup1&Qmime=cif); [checkCIF report](http://scripts.iucr.org/cgi-bin/paper?hy2138&checkcif=yes)

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: [HY2138](http://scripts.iucr.org/cgi-bin/sendsup?hy2138)).

We thank Henan Agricultural University for the generous support of this study.

Comment
=======

Pyridylphosphines have induced much interest as excellent ligands with both P-- and N-donor centres (Kuang *et al.*, 1998; Newkome, 1993). These pyridylphosphines display various coordination modes: P-coordination, N-coordination, P,*N*-chelating and P,*N*-bridging (Braunstein *et al.*, 1997; Catalano *et al.*, 2001; Durran *et al.*, 2000; Field *et al.*, 1997; Li *et al.*, 1996). Here, we report the crystal structure of the title compound, in which two Pt^II^ atoms are bridged by an *N*-\[(diphenylphosphino)methyl\]pyridin-2-amine (dppmp) ligand.

In the title compound (Fig. 1), the Pt1 atom is coordinated by one pyridyl N atom from the dppmp ligand, and one C atom and two N atoms from a 6-phenyl-2,2\'-bipyridine (pbpy) ligand in a square-planar geometry (Table 1). The Pt2 atom is coordinated by one P atom from the dppmp ligand, and one C atom and two N atoms from another pbpy ligand in a square-planar geometry. The atoms Pt1, N1, N2, N3 and C16 show a mean deviation of 0.01 (1)Å from the least-squares plane through them. The planarity of the coordination geometry around the Pt2 atom was accessed by fitting a least-squares plane to the atoms Pt2, P1, N5, N6 and C50, which show a mean deviation of 0.08 (1) Å. Dihedral angle between the planes defined by two Pt atoms and the corresponding coordinated atoms is 16.6 (2)°.

Experimental {#experimental}
============

A solution of K~2~(PtCl~4~) (0.088 g, 0.212 mmol) in water (5 ml) was treated with a solution of pbpy (0.052 g, 0.224 mmol) in MeCN (5 ml) and the mixture was heated to reflux for 20 h, allowing MeCN to evaporate slowly. The orange solid so obtained was collected by filtration, washed with water and water--EtOH (5:l, *v*/*v*) and dried *in vacuo*, yielding Pt(pbpy)Cl (yield 91%, 0.089 g). A 15 ml MeCN solution of Pt(pbpy)Cl (0.046 g, 0.1 mmol) was added to a 20 ml MeCN solution of dppmp (0.015 g, 0.05 mmol). The mixture was stirred for 10 h and then LiClO~4~ (0.021 g, 0.2 mmol) was added. Yellow crystals suitable for X-ray diffraction were formed by vapour diffusion of diethyl ether into the MeCN solution.

Refinement {#refinement}
==========

H atoms were positioned geometrically and refined as riding atoms, with C---H = 0.93 (aromatic) and 0.97 (CH~2~) Å, and N---H = 0.86 Å, and with *U*~iso~(H) = 1.2*U*~eq~(C,*N*). The highest residual electron density was found 0.98 Å from atom Pt2 and the deepest hole 1.00 Å from atom Pt2. Each perchlorate anion is disordered over two different orientations. The Cl---O distances were restrained to 1.44 (3) Å.

Figures
=======

![Molecular structure of the title compound. Displacement ellipsoids are drawn at the 40% probability level. H atoms and the minor disordered positions of the perchlorate anions have been omitted for clarity.](e-64-m1146-fig1){#Fap1}

Crystal data {#tablewrapcrystaldatalong}
============

  ---------------------------------------------------------- ---------------------------------------
  \[Pt~2~(C~16~H~11~N~2~)~2~(C~18~H~17~N~2~P)\](ClO~4~)~2~   *F*~000~ = 2600
  *M~r~* = 1343.92                                           *D*~x~ = 1.928 Mg m^−3^
  Monoclinic, *P*2~1~/*n*                                    Mo *K*α radiation λ = 0.71073 Å
  Hall symbol: -P 2yn                                        Cell parameters from 7716 reflections
  *a* = 14.845 (3) Å                                         θ = 2.3--26.6º
  *b* = 17.927 (4) Å                                         µ = 6.25 mm^−1^
  *c* = 18.481 (4) Å                                         *T* = 294 (2) K
  β = 109.697 (3)º                                           Block, yellow
  *V* = 4630.5 (18) Å^3^                                     0.40 × 0.20 × 0.10 mm
  *Z* = 4                                                    
  ---------------------------------------------------------- ---------------------------------------

Data collection {#tablewrapdatacollectionlong}
===============

  ------------------------------------------------------------ --------------------------------------
  Bruker SMART APEX CCD area-detector diffractometer           8097 independent reflections
  Radiation source: fine-focus sealed tube                     5253 reflections with *I* \> 2σ(*I*)
  Monochromator: graphite                                      *R*~int~ = 0.090
  *T* = 294(2) K                                               θ~max~ = 25.0º
  φ and ω scans                                                θ~min~ = 1.6º
  Absorption correction: multi-scan(SADABS; Sheldrick, 1996)   *h* = −17→16
  *T*~min~ = 0.225, *T*~max~ = 0.534                           *k* = −17→21
  22850 measured reflections                                   *l* = −20→21
  ------------------------------------------------------------ --------------------------------------

Refinement {#tablewraprefinementdatalong}
==========

  ---------------------------------------------------------------- ----------------------------------------------------------------------------------------------------
  Refinement on *F*^2^                                             Secondary atom site location: difference Fourier map
  Least-squares matrix: full                                       Hydrogen site location: inferred from neighbouring sites
  *R*\[*F*^2^ \> 2σ(*F*^2^)\] = 0.075                              H-atom parameters constrained
  *wR*(*F*^2^) = 0.219                                               *w* = 1/\[σ^2^(*F*~o~^2^) + (0.0656*P*)^2^ + 39.0816*P*\] where *P* = (*F*~o~^2^ + 2*F*~c~^2^)/3
  *S* = 1.03                                                       (Δ/σ)~max~ = 0.001
  8097 reflections                                                 Δρ~max~ = 2.85 e Å^−3^
  696 parameters                                                   Δρ~min~ = −2.38 e Å^−3^
  16 restraints                                                    Extinction correction: none
  Primary atom site location: structure-invariant direct methods   
  ---------------------------------------------------------------- ----------------------------------------------------------------------------------------------------

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å^2^) {#tablewrapcoords}
==================================================================================================

  ------ ------------- -------------- -------------- -------------------- ------------
         *x*           *y*            *z*            *U*~iso~\*/*U*~eq~   Occ. (\<1)
  Pt1    0.96899 (4)   0.15372 (3)    0.47609 (3)    0.0324 (2)           
  Pt2    0.71657 (4)   0.21672 (3)    0.51620 (3)    0.0326 (2)           
  P1     0.7571 (3)    0.3339 (2)     0.55627 (19)   0.0325 (8)           
  N1     0.9510 (9)    0.1645 (8)     0.3600 (6)     0.040 (3)            
  N2     0.8943 (8)    0.0657 (8)     0.4355 (6)     0.033 (3)            
  N3     1.0503 (9)    0.2462 (8)     0.5165 (5)     0.038 (3)            
  N4     0.9260 (9)    0.3020 (8)     0.5450 (7)     0.040 (3)            
  H4     0.9029        0.2582         0.5464         0.048\*              
  N5     0.7113 (10)   0.1553 (8)     0.6155 (8)     0.047 (3)            
  N6     0.6669 (8)    0.1175 (7)     0.4717 (7)     0.033 (3)            
  C1     0.9763 (13)   0.2199 (10)    0.3226 (9)     0.047 (4)            
  H1     1.0069        0.2613         0.3504         0.056\*              
  C2     0.9588 (14)   0.2184 (12)    0.2437 (10)    0.060 (5)            
  H2     0.9781        0.2579         0.2198         0.072\*              
  C3     0.9137 (15)   0.1595 (13)    0.2027 (9)     0.065 (6)            
  H3     0.9037        0.1572         0.1503         0.078\*              
  C4     0.8816 (12)   0.1013 (11)    0.2385 (9)     0.053 (5)            
  H4A    0.8477        0.0616         0.2095         0.064\*              
  C5     0.9009 (11)   0.1032 (9)     0.3175 (8)     0.040 (4)            
  C6     0.8704 (10)   0.0466 (10)    0.3612 (7)     0.039 (4)            
  C7     0.8170 (11)   −0.0157 (11)   0.3327 (9)     0.053 (5)            
  H7     0.7987        −0.0268        0.2806         0.063\*              
  C8     0.7905 (12)   −0.0622 (11)   0.3821 (10)    0.056 (5)            
  H8     0.7547        −0.1050        0.3638         0.068\*              
  C9     0.8179 (10)   −0.0437 (10)   0.4582 (9)     0.042 (4)            
  H9     0.7979        −0.0733        0.4912         0.050\*              
  C10    0.8741 (10)   0.0176 (9)     0.4873 (7)     0.034 (3)            
  C11    0.9076 (10)   0.0489 (9)     0.5636 (8)     0.035 (3)            
  C12    0.8939 (11)   0.0107 (11)    0.6275 (8)     0.047 (4)            
  H12    0.8600        −0.0338        0.6203         0.056\*              
  C13    0.9321 (14)   0.0416 (13)    0.6992 (9)     0.063 (5)            
  H13    0.9226        0.0182         0.7409         0.076\*              
  C14    0.9833 (13)   0.1055 (13)    0.7101 (9)     0.061 (5)            
  H14    1.0103        0.1242         0.7597         0.073\*              
  C15    0.9969 (12)   0.1443 (10)    0.6490 (8)     0.045 (4)            
  H15    1.0298        0.1894         0.6580         0.054\*              
  C16    0.9616 (9)    0.1158 (11)    0.5751 (7)     0.042 (4)            
  C17    1.1411 (10)   0.2502 (11)    0.5117 (9)     0.044 (4)            
  H17    1.1649        0.2090         0.4933         0.053\*              
  C18    1.1961 (13)   0.3111 (10)    0.5326 (10)    0.049 (4)            
  H18    1.2581        0.3103         0.5311         0.059\*              
  C19    1.1611 (10)   0.3767 (10)    0.5568 (8)     0.041 (4)            
  H19    1.1970        0.4203         0.5681         0.049\*              
  C20    1.0709 (11)   0.3726 (9)     0.5628 (7)     0.039 (4)            
  H20    1.0464        0.4131         0.5814         0.047\*              
  C21    1.0161 (10)   0.3071 (9)     0.5406 (6)     0.030 (3)            
  C22    0.8681 (9)    0.3651 (9)     0.5475 (8)     0.034 (3)            
  H22A   0.8554        0.3943         0.5009         0.041\*              
  H22B   0.9018        0.3965         0.5909         0.041\*              
  C23    0.7700 (12)   0.3500 (8)     0.6562 (8)     0.040 (4)            
  C24    0.8588 (12)   0.3455 (11)    0.7132 (9)     0.054 (5)            
  H24    0.9141        0.3432         0.7003         0.065\*              
  C25    0.8646 (16)   0.3446 (13)    0.7892 (10)    0.077 (7)            
  H25    0.9242        0.3390         0.8271         0.092\*              
  C26    0.7854 (14)   0.3515 (12)    0.8103 (10)    0.059 (5)            
  H26    0.7902        0.3514         0.8618         0.070\*              
  C27    0.6987 (15)   0.3588 (12)    0.7532 (9)     0.064 (6)            
  H27    0.6440        0.3635         0.7666         0.077\*              
  C28    0.6894 (13)   0.3592 (12)    0.6757 (9)     0.055 (5)            
  H28    0.6298        0.3656         0.6380         0.067\*              
  C29    0.6740 (10)   0.4050 (9)     0.5055 (7)     0.035 (3)            
  C30    0.5850 (11)   0.3829 (11)    0.4536 (7)     0.043 (4)            
  H30    0.5689        0.3328         0.4450         0.051\*              
  C31    0.5226 (16)   0.4377 (15)    0.4159 (10)    0.074 (7)            
  H31    0.4637        0.4239         0.3807         0.089\*              
  C32    0.5421 (17)   0.5077 (13)    0.4274 (12)    0.072 (7)            
  H32    0.4966        0.5432         0.4022         0.086\*              
  C33    0.6317 (15)   0.5307 (12)    0.4777 (13)    0.069 (6)            
  H33    0.6462        0.5813         0.4842         0.083\*              
  C34    0.6956 (13)   0.4806 (10)    0.5160 (10)    0.048 (4)            
  H34    0.7547        0.4959         0.5498         0.058\*              
  C35    0.7382 (16)   0.1770 (13)    0.6886 (10)    0.067 (6)            
  H35    0.7650        0.2241         0.7019         0.080\*              
  C36    0.7269 (18)   0.1308 (15)    0.7452 (13)    0.081 (7)            
  H36    0.7504        0.1458         0.7963         0.097\*              
  C37    0.6828 (16)   0.0650 (16)    0.7270 (13)    0.085 (8)            
  H37    0.6692        0.0361         0.7638         0.102\*              
  C38    0.6578 (15)   0.0413 (13)    0.6510 (12)    0.070 (6)            
  H38    0.6328        −0.0062        0.6375         0.084\*              
  C39    0.6702 (11)   0.0888 (9)     0.5949 (9)     0.044 (4)            
  C40    0.6436 (12)   0.0660 (11)    0.5145 (11)    0.055 (5)            
  C41    0.6049 (13)   −0.0013 (11)   0.4835 (11)    0.059 (5)            
  H41    0.5944        −0.0383        0.5151         0.070\*              
  C42    0.5824 (13)   −0.0137 (12)   0.4087 (13)    0.065 (6)            
  H42    0.5563        −0.0591        0.3875         0.078\*              
  C43    0.5988 (13)   0.0432 (12)    0.3620 (12)    0.066 (6)            
  H43    0.5805        0.0366         0.3091         0.079\*              
  C44    0.6428 (10)   0.1095 (10)    0.3956 (9)     0.042 (4)            
  C45    0.6726 (11)   0.1717 (10)    0.3581 (8)     0.038 (4)            
  C46    0.6645 (13)   0.1717 (12)    0.2834 (9)     0.056 (5)            
  H46    0.6359        0.1316         0.2523         0.068\*              
  C47    0.6988 (14)   0.2316 (14)    0.2526 (9)     0.067 (6)            
  H47    0.6976        0.2300         0.2019         0.081\*              
  C48    0.7345 (13)   0.2930 (12)    0.2973 (9)     0.060 (5)            
  H48    0.7558        0.3339         0.2765         0.072\*              
  C49    0.7389 (12)   0.2942 (11)    0.3716 (8)     0.049 (4)            
  H49    0.7612        0.3374         0.3999         0.059\*              
  C50    0.7124 (10)   0.2355 (9)     0.4077 (7)     0.034 (4)            
  Cl1    0.9289 (4)    0.2821 (3)     0.0174 (3)     0.0685 (14)          
  Cl2    0.4595 (5)    0.0612 (3)     0.8325 (2)     0.0868 (19)          
  O1     0.8360 (8)    0.3152 (11)    0.0026 (12)    0.045 (7)            0.49 (3)
  O2     0.9880 (13)   0.3037 (16)    0.0961 (7)     0.085 (11)           0.49 (3)
  O3     0.9732 (14)   0.3115 (14)    −0.0339 (11)   0.066 (10)           0.49 (3)
  O4     0.9225 (17)   0.2030 (5)     0.0144 (18)    0.099 (12)           0.49 (3)
  O1\'   0.8580 (14)   0.3177 (12)    0.0424 (16)    0.084 (10)           0.51 (3)
  O2\'   0.9950 (14)   0.2415 (15)    0.0795 (12)    0.115 (12)           0.51 (3)
  O3\'   0.9770 (13)   0.3359 (10)    −0.0133 (11)   0.043 (6)            0.51 (3)
  O4\'   0.8809 (18)   0.2289 (13)    −0.0433 (12)   0.105 (12)           0.51 (3)
  O5     0.5418 (15)   0.0136 (14)    0.8519 (16)    0.126 (14)           0.52 (2)
  O6     0.465 (2)     0.1108 (12)    0.8945 (10)    0.089 (10)           0.52 (2)
  O7     0.452 (2)     0.1028 (12)    0.7643 (9)     0.070 (9)            0.52 (2)
  O8     0.3747 (15)   0.0152 (14)    0.8177 (17)    0.150 (17)           0.52 (2)
  O5\'   0.4931 (16)   −0.0120 (7)    0.8234 (11)    0.058 (8)            0.48 (2)
  O6\'   0.5415 (14)   0.1089 (12)    0.8684 (15)    0.125 (15)           0.48 (2)
  O7\'   0.4045 (15)   0.0923 (11)    0.7596 (8)     0.052 (7)            0.48 (2)
  O8\'   0.4025 (19)   0.0581 (17)    0.8818 (14)    0.163 (18)           0.48 (2)
  ------ ------------- -------------- -------------- -------------------- ------------

Atomic displacement parameters (Å^2^) {#tablewrapadps}
=====================================

  ------ ------------ ------------ ------------- ------------- ------------- --------------
         *U*^11^      *U*^22^      *U*^33^       *U*^12^       *U*^13^       *U*^23^
  Pt1    0.0415 (4)   0.0279 (4)   0.0241 (3)    0.0019 (2)    0.0060 (2)    −0.0019 (2)
  Pt2    0.0420 (4)   0.0225 (4)   0.0301 (3)    −0.0007 (2)   0.0079 (2)    −0.0017 (2)
  P1     0.044 (2)    0.025 (2)    0.0253 (17)   0.0033 (17)   0.0066 (14)   −0.0016 (14)
  N1     0.057 (8)    0.037 (9)    0.030 (6)     −0.001 (7)    0.021 (6)     −0.006 (5)
  N2     0.035 (7)    0.039 (8)    0.020 (5)     −0.002 (6)    0.003 (4)     0.002 (5)
  N3     0.048 (7)    0.049 (9)    0.013 (5)     0.001 (7)     0.004 (5)     −0.001 (5)
  N4     0.046 (8)    0.034 (8)    0.044 (7)     −0.011 (6)    0.021 (6)     −0.007 (6)
  N5     0.046 (8)    0.033 (9)    0.059 (9)     0.000 (6)     0.012 (6)     0.006 (6)
  N6     0.030 (7)    0.026 (7)    0.044 (7)     0.009 (5)     0.014 (5)     −0.007 (5)
  C1     0.066 (11)   0.035 (11)   0.040 (8)     −0.002 (9)    0.019 (7)     0.003 (7)
  C2     0.078 (13)   0.064 (16)   0.047 (10)    0.018 (11)    0.032 (9)     0.021 (9)
  C3     0.087 (14)   0.078 (17)   0.026 (8)     0.003 (12)    0.014 (8)     −0.005 (9)
  C4     0.066 (11)   0.042 (12)   0.041 (9)     0.015 (9)     0.003 (7)     −0.006 (8)
  C5     0.052 (9)    0.029 (9)    0.034 (7)     0.017 (8)     0.009 (6)     −0.002 (6)
  C6     0.040 (8)    0.047 (11)   0.027 (7)     0.018 (8)     0.006 (6)     −0.006 (6)
  C7     0.050 (10)   0.055 (13)   0.041 (9)     0.004 (9)     −0.001 (7)    −0.016 (8)
  C8     0.060 (11)   0.037 (11)   0.059 (11)    −0.012 (9)    0.004 (8)     −0.019 (8)
  C9     0.037 (8)    0.033 (10)   0.063 (10)    −0.002 (7)    0.025 (7)     0.005 (7)
  C10    0.044 (8)    0.023 (8)    0.034 (7)     0.003 (7)     0.011 (6)     0.006 (6)
  C11    0.035 (8)    0.033 (9)    0.035 (7)     0.005 (7)     0.008 (6)     0.006 (6)
  C12    0.043 (9)    0.054 (12)   0.041 (8)     0.001 (8)     0.010 (7)     0.013 (8)
  C13    0.082 (13)   0.074 (16)   0.034 (9)     0.002 (12)    0.020 (8)     0.015 (9)
  C14    0.075 (13)   0.078 (17)   0.028 (8)     −0.007 (12)   0.013 (7)     −0.003 (8)
  C15    0.061 (10)   0.043 (11)   0.026 (7)     −0.002 (8)    0.009 (7)     0.003 (6)
  C16    0.017 (7)    0.079 (14)   0.026 (7)     0.000 (8)     0.002 (5)     −0.015 (7)
  C17    0.035 (9)    0.052 (12)   0.059 (9)     0.011 (8)     0.033 (7)     0.011 (8)
  C18    0.055 (10)   0.027 (10)   0.063 (10)    −0.002 (8)    0.015 (8)     0.004 (7)
  C19    0.031 (8)    0.043 (11)   0.043 (8)     −0.020 (7)    0.006 (6)     −0.001 (7)
  C20    0.059 (10)   0.023 (9)    0.027 (7)     −0.013 (7)    0.002 (6)     −0.004 (6)
  C21    0.039 (8)    0.034 (9)    0.015 (6)     0.001 (7)     0.005 (5)     −0.010 (5)
  C22    0.031 (8)    0.046 (10)   0.028 (7)     0.004 (7)     0.013 (6)     −0.002 (6)
  C23    0.069 (11)   0.012 (8)    0.033 (7)     0.003 (7)     0.008 (7)     −0.010 (5)
  C24    0.050 (10)   0.068 (15)   0.039 (9)     −0.005 (9)    0.009 (7)     0.000 (8)
  C25    0.095 (16)   0.085 (19)   0.029 (9)     −0.025 (13)   −0.007 (9)    −0.012 (9)
  C26    0.079 (14)   0.062 (15)   0.037 (9)     −0.010 (11)   0.022 (9)     −0.016 (8)
  C27    0.094 (15)   0.067 (16)   0.037 (9)     0.004 (11)    0.031 (9)     −0.007 (8)
  C28    0.062 (11)   0.064 (14)   0.040 (9)     0.031 (10)    0.017 (8)     0.011 (8)
  C29    0.041 (8)    0.033 (10)   0.028 (7)     0.016 (7)     0.009 (6)     0.003 (6)
  C30    0.053 (10)   0.051 (12)   0.021 (7)     0.013 (8)     0.008 (6)     −0.004 (6)
  C31    0.092 (15)   0.09 (2)     0.035 (9)     0.043 (14)    0.015 (9)     0.016 (10)
  C32    0.098 (17)   0.050 (15)   0.083 (14)    0.053 (13)    0.050 (13)    0.046 (11)
  C33    0.084 (15)   0.048 (15)   0.096 (15)    0.008 (12)    0.058 (13)    0.039 (12)
  C34    0.066 (11)   0.031 (11)   0.063 (10)    0.018 (8)     0.042 (9)     0.016 (8)
  C35    0.111 (16)   0.051 (13)   0.036 (9)     0.010 (12)    0.021 (9)     0.015 (8)
  C36    0.123 (19)   0.067 (17)   0.065 (13)    −0.010 (15)   0.048 (13)    0.026 (11)
  C37    0.094 (16)   0.09 (2)     0.083 (16)    0.003 (14)    0.044 (13)    0.055 (14)
  C38    0.092 (15)   0.041 (13)   0.081 (14)    −0.008 (11)   0.034 (11)    0.006 (10)
  C39    0.046 (9)    0.024 (9)    0.063 (10)    0.002 (7)     0.020 (7)     0.000 (7)
  C40    0.047 (10)   0.033 (11)   0.070 (11)    −0.004 (8)    0.001 (8)     −0.015 (9)
  C41    0.068 (12)   0.028 (11)   0.075 (12)    0.014 (9)     0.018 (9)     −0.003 (9)
  C42    0.049 (11)   0.039 (13)   0.106 (16)    −0.006 (9)    0.022 (10)    −0.020 (11)
  C43    0.058 (11)   0.044 (13)   0.074 (12)    −0.003 (10)   −0.007 (9)    −0.037 (10)
  C44    0.027 (8)    0.044 (11)   0.048 (9)     0.007 (7)     0.005 (6)     −0.009 (7)
  C45    0.041 (9)    0.036 (10)   0.026 (7)     0.007 (7)     −0.002 (6)    −0.003 (6)
  C46    0.069 (12)   0.051 (13)   0.029 (8)     0.026 (10)    −0.010 (7)    −0.013 (8)
  C47    0.084 (14)   0.083 (18)   0.026 (8)     0.039 (13)    0.007 (8)     0.007 (9)
  C48    0.071 (12)   0.053 (13)   0.043 (9)     0.020 (10)    0.004 (8)     0.006 (8)
  C49    0.065 (11)   0.050 (12)   0.026 (7)     −0.016 (9)    0.006 (7)     0.001 (7)
  C50    0.034 (8)    0.040 (10)   0.030 (7)     0.008 (7)     0.012 (6)     −0.020 (6)
  Cl1    0.070 (3)    0.057 (4)    0.091 (4)     0.007 (3)     0.044 (3)     0.023 (3)
  Cl2    0.158 (6)    0.043 (3)    0.038 (2)     0.008 (3)     0.005 (3)     0.000 (2)
  O1     0.043 (10)   0.049 (11)   0.046 (10)    −0.003 (8)    0.021 (7)     −0.006 (7)
  O2     0.092 (13)   0.083 (14)   0.076 (13)    0.002 (9)     0.022 (9)     0.009 (9)
  O3     0.071 (12)   0.066 (13)   0.059 (12)    −0.008 (9)    0.021 (8)     −0.007 (9)
  O4     0.099 (14)   0.097 (15)   0.110 (15)    0.004 (9)     0.046 (10)    0.002 (9)
  O1\'   0.080 (13)   0.087 (14)   0.088 (13)    −0.008 (9)    0.033 (9)     −0.001 (9)
  O2\'   0.119 (14)   0.116 (15)   0.112 (14)    0.010 (9)     0.041 (10)    0.016 (9)
  O3\'   0.043 (9)    0.042 (10)   0.043 (9)     −0.010 (7)    0.014 (7)     −0.008 (8)
  O4\'   0.104 (14)   0.105 (16)   0.107 (15)    −0.004 (9)    0.034 (10)    −0.001 (9)
  O5     0.123 (16)   0.120 (17)   0.129 (16)    0.006 (10)    0.034 (10)    0.009 (10)
  O6     0.100 (13)   0.085 (13)   0.073 (12)    −0.003 (9)    0.018 (8)     −0.013 (9)
  O7     0.081 (12)   0.055 (12)   0.067 (11)    −0.005 (9)    0.018 (8)     0.012 (8)
  O8     0.153 (18)   0.143 (19)   0.144 (19)    −0.007 (10)   0.038 (10)    0.002 (10)
  O5\'   0.069 (11)   0.046 (11)   0.047 (10)    0.006 (8)     0.003 (7)     −0.001 (8)
  O6\'   0.129 (17)   0.118 (17)   0.120 (17)    −0.004 (10)   0.030 (10)    −0.006 (10)
  O7\'   0.043 (10)   0.047 (11)   0.057 (10)    −0.002 (8)    0.007 (7)     0.006 (8)
  O8\'   0.167 (19)   0.17 (2)     0.161 (19)    0.005 (10)    0.062 (11)    0.007 (10)
  ------ ------------ ------------ ------------- ------------- ------------- --------------

Geometric parameters (Å, °) {#tablewrapgeomlong}
===========================

  ----------------------- ------------- ----------------------- -------------
  Pt1---N2                1.928 (13)    C24---C25               1.38 (2)
  Pt1---C16               1.990 (15)    C24---H24               0.9300
  Pt1---N3                2.038 (14)    C25---C26               1.36 (3)
  Pt1---N1                2.079 (11)    C25---H25               0.9300
  Pt2---N6                1.993 (13)    C26---C27               1.37 (3)
  Pt2---C50               2.014 (14)    C26---H26               0.9300
  Pt2---N5                2.164 (14)    C27---C28               1.39 (2)
  Pt2---P1                2.241 (4)     C27---H27               0.9300
  P1---C22                1.799 (14)    C28---H28               0.9300
  P1---C29                1.802 (14)    C29---C34               1.39 (2)
  P1---C23                1.814 (14)    C29---C30               1.40 (2)
  N1---C1                 1.34 (2)      C30---C31               1.37 (3)
  N1---C5                 1.41 (2)      C30---H30               0.9300
  N2---C6                 1.342 (17)    C31---C32               1.29 (3)
  N2---C10                1.394 (18)    C31---H31               0.9300
  N3---C21                1.342 (19)    C32---C33               1.40 (3)
  N3---C17                1.381 (19)    C32---H32               0.9300
  N4---C21                1.370 (18)    C33---C34               1.33 (2)
  N4---C22                1.43 (2)      C33---H33               0.9300
  N4---H4                 0.8600        C34---H34               0.9300
  N5---C35                1.33 (2)      C35---C36               1.39 (3)
  N5---C39                1.34 (2)      C35---H35               0.9300
  N6---C40                1.33 (2)      C36---C37               1.34 (4)
  N6---C44                1.338 (19)    C36---H36               0.9300
  C1---C2                 1.39 (2)      C37---C38               1.39 (3)
  C1---H1                 0.9300        C37---H37               0.9300
  C2---C3                 1.34 (3)      C38---C39               1.40 (3)
  C2---H2                 0.9300        C38---H38               0.9300
  C3---C4                 1.40 (3)      C39---C40               1.46 (2)
  C3---H3                 0.9300        C40---C41               1.38 (3)
  C4---C5                 1.39 (2)      C41---C42               1.33 (3)
  C4---H4A                0.9300        C41---H41               0.9300
  C5---C6                 1.46 (2)      C42---C43               1.41 (3)
  C6---C7                 1.37 (2)      C42---H42               0.9300
  C7---C8                 1.39 (3)      C43---C44               1.40 (2)
  C7---H7                 0.9300        C43---H43               0.9300
  C8---C9                 1.37 (2)      C44---C45               1.46 (2)
  C8---H8                 0.9300        C45---C46               1.35 (2)
  C9---C10                1.37 (2)      C45---C50               1.46 (2)
  C9---H9                 0.9300        C46---C47               1.39 (3)
  C10---C11               1.44 (2)      C46---H46               0.9300
  C11---C16               1.42 (2)      C47---C48               1.37 (3)
  C11---C12               1.44 (2)      C47---H47               0.9300
  C12---C13               1.37 (2)      C48---C49               1.35 (2)
  C12---H12               0.9300        C48---H48               0.9300
  C13---C14               1.35 (3)      C49---C50               1.37 (2)
  C13---H13               0.9300        C49---H49               0.9300
  C14---C15               1.40 (2)      Cl1---O4                1.421 (8)
  C14---H14               0.9300        Cl1---O3                1.424 (8)
  C15---C16               1.39 (2)      Cl1---O3\'              1.427 (8)
  C15---H15               0.9300        Cl1---O2\'              1.432 (8)
  C17---C18               1.34 (2)      Cl1---O1\'              1.434 (8)
  C17---H17               0.9300        Cl1---O1                1.440 (8)
  C18---C19               1.42 (3)      Cl1---O4\'              1.461 (9)
  C18---H18               0.9300        Cl1---O2                1.474 (8)
  C19---C20               1.38 (2)      Cl2---O6                1.430 (9)
  C19---H19               0.9300        Cl2---O7\'              1.431 (8)
  C20---C21               1.41 (2)      Cl2---O5\'              1.434 (8)
  C20---H20               0.9300        Cl2---O5                1.435 (9)
  C22---H22A              0.9700        Cl2---O7                1.437 (8)
  C22---H22B              0.9700        Cl2---O8\'              1.439 (9)
  C23---C28               1.37 (2)      Cl2---O6\'              1.452 (9)
  C23---C24               1.39 (2)      Cl2---O8                1.453 (9)
                                                                
  N2---Pt1---C16          82.8 (6)      C23---C28---H28         120.8
  N2---Pt1---N3           178.1 (4)     C27---C28---H28         120.8
  C16---Pt1---N3          98.7 (6)      C34---C29---C30         119.3 (14)
  N2---Pt1---N1           79.5 (5)      C34---C29---P1          122.1 (12)
  C16---Pt1---N1          162.3 (6)     C30---C29---P1          118.6 (13)
  N3---Pt1---N1           99.0 (5)      C31---C30---C29         118 (2)
  N6---Pt2---C50          81.7 (6)      C31---C30---H30         121.1
  N6---Pt2---N5           77.4 (5)      C29---C30---H30         121.1
  C50---Pt2---N5          158.8 (6)     C32---C31---C30         123 (2)
  N6---Pt2---P1           173.4 (4)     C32---C31---H31         118.7
  C50---Pt2---P1          95.0 (5)      C30---C31---H31         118.7
  N5---Pt2---P1           106.2 (4)     C31---C32---C33         120.4 (18)
  C22---P1---C29          102.7 (7)     C31---C32---H32         119.8
  C22---P1---C23          104.9 (7)     C33---C32---H32         119.8
  C29---P1---C23          103.7 (7)     C34---C33---C32         120 (2)
  C22---P1---Pt2          114.5 (5)     C34---C33---H33         119.9
  C29---P1---Pt2          115.5 (5)     C32---C33---H33         119.9
  C23---P1---Pt2          114.2 (5)     C33---C34---C29         119.7 (19)
  C1---N1---C5            118.6 (13)    C33---C34---H34         120.1
  C1---N1---Pt1           130.0 (12)    C29---C34---H34         120.1
  C5---N1---Pt1           111.3 (10)    N5---C35---C36          121 (2)
  C6---N2---C10           120.0 (14)    N5---C35---H35          119.4
  C6---N2---Pt1           121.8 (11)    C36---C35---H35         119.4
  C10---N2---Pt1          117.9 (9)     C37---C36---C35         121 (2)
  C21---N3---C17          117.7 (15)    C37---C36---H36         119.6
  C21---N3---Pt1          122.7 (10)    C35---C36---H36         119.6
  C17---N3---Pt1          119.3 (12)    C36---C37---C38         117.7 (17)
  C21---N4---C22          123.9 (14)    C36---C37---H37         121.2
  C21---N4---H4           118.1         C38---C37---H37         121.2
  C22---N4---H4           118.1         C37---C38---C39         120 (2)
  C35---N5---C39          120.2 (15)    C37---C38---H38         119.9
  C35---N5---Pt2          128.9 (13)    C39---C38---H38         119.9
  C39---N5---Pt2          110.8 (11)    N5---C39---C38          119.5 (16)
  C40---N6---C44          121.2 (15)    N5---C39---C40          118.8 (15)
  C40---N6---Pt2          120.5 (11)    C38---C39---C40         121.7 (17)
  C44---N6---Pt2          117.4 (11)    N6---C40---C41          121.1 (18)
  N1---C1---C2            122.9 (18)    N6---C40---C39          111.9 (15)
  N1---C1---H1            118.6         C41---C40---C39         126.9 (19)
  C2---C1---H1            118.6         C42---C41---C40         120 (2)
  C3---C2---C1            119.2 (18)    C42---C41---H41         119.9
  C3---C2---H2            120.4         C40---C41---H41         119.9
  C1---C2---H2            120.4         C41---C42---C43         118.9 (19)
  C2---C3---C4            120.3 (16)    C41---C42---H42         120.6
  C2---C3---H3            119.9         C43---C42---H42         120.6
  C4---C3---H3            119.9         C44---C43---C42         119.6 (18)
  C5---C4---C3            119.6 (18)    C44---C43---H43         120.2
  C5---C4---H4A           120.2         C42---C43---H43         120.2
  C3---C4---H4A           120.2         N6---C44---C43          118.6 (17)
  C4---C5---N1            119.2 (16)    N6---C44---C45          113.6 (15)
  C4---C5---C6            124.8 (16)    C43---C44---C45         127.7 (16)
  N1---C5---C6            115.9 (12)    C46---C45---C44         123.5 (17)
  N2---C6---C7            121.5 (15)    C46---C45---C50         121.4 (17)
  N2---C6---C5            111.3 (15)    C44---C45---C50         115.2 (13)
  C7---C6---C5            127.0 (13)    C45---C46---C47         120.2 (18)
  C6---C7---C8            119.5 (15)    C45---C46---H46         119.9
  C6---C7---H7            120.2         C47---C46---H46         119.9
  C8---C7---H7            120.2         C48---C47---C46         119.6 (17)
  C9---C8---C7            118.6 (16)    C48---C47---H47         120.2
  C9---C8---H8            120.7         C46---C47---H47         120.2
  C7---C8---H8            120.7         C49---C48---C47         120 (2)
  C8---C9---C10           121.8 (15)    C49---C48---H48         119.9
  C8---C9---H9            119.1         C47---C48---H48         119.9
  C10---C9---H9           119.1         C48---C49---C50         123.8 (18)
  C9---C10---N2           117.9 (12)    C48---C49---H49         118.1
  C9---C10---C11          131.1 (13)    C50---C49---H49         118.1
  N2---C10---C11          110.3 (13)    C49---C50---C45         114.7 (13)
  C16---C11---C12         120.6 (13)    C49---C50---Pt2         134.0 (12)
  C16---C11---C10         117.9 (12)    C45---C50---Pt2         111.3 (12)
  C12---C11---C10         121.3 (15)    O4---Cl1---O3           112.5 (8)
  C13---C12---C11         118.4 (17)    O4---Cl1---O3\'         134.0 (12)
  C13---C12---H12         120.8         O4---Cl1---O2\'         62.8 (14)
  C11---C12---H12         120.8         O3---Cl1---O2\'         112.1 (14)
  C14---C13---C12         121.0 (16)    O3\'---Cl1---O2\'       111.2 (8)
  C14---C13---H13         119.5         O4---Cl1---O1\'         114.2 (13)
  C12---C13---H13         119.5         O3---Cl1---O1\'         127.1 (13)
  C13---C14---C15         121.8 (15)    O3\'---Cl1---O1\'       110.3 (8)
  C13---C14---H14         119.1         O2\'---Cl1---O1\'       110.3 (8)
  C15---C14---H14         119.1         O4---Cl1---O1           110.9 (8)
  C16---C15---C14         120.3 (17)    O3---Cl1---O1           110.4 (8)
  C16---C15---H15         119.9         O3\'---Cl1---O1         102.8 (13)
  C14---C15---H15         119.9         O2\'---Cl1---O1         135.7 (12)
  C15---C16---C11         117.8 (14)    O4---Cl1---O4\'         46.4 (13)
  C15---C16---Pt1         131.4 (14)    O3---Cl1---O4\'         86.9 (13)
  C11---C16---Pt1         110.7 (9)     O3\'---Cl1---O4\'       108.4 (8)
  C18---C17---N3          122.5 (17)    O2\'---Cl1---O4\'       108.0 (8)
  C18---C17---H17         118.8         O1\'---Cl1---O4\'       108.5 (8)
  N3---C17---H17          118.8         O1---Cl1---O4\'         86.3 (12)
  C17---C18---C19         120.9 (17)    O4---Cl1---O2           108.1 (8)
  C17---C18---H18         119.5         O3---Cl1---O2           107.8 (8)
  C19---C18---H18         119.5         O3\'---Cl1---O2         90.2 (12)
  C20---C19---C18         116.7 (16)    O2\'---Cl1---O2         47.4 (13)
  C20---C19---H19         121.6         O1\'---Cl1---O2         79.8 (12)
  C18---C19---H19         121.6         O1---Cl1---O2           107.0 (7)
  C19---C20---C21         120.1 (15)    O4\'---Cl1---O2         154.4 (13)
  C19---C20---H20         120.0         O6---Cl2---O7\'         111.9 (14)
  C21---C20---H20         120.0         O6---Cl2---O5\'         137.2 (13)
  N3---C21---N4           116.8 (14)    O7\'---Cl2---O5\'       110.9 (8)
  N3---C21---C20          122.0 (14)    O6---Cl2---O5           110.9 (8)
  N4---C21---C20          121.2 (14)    O7\'---Cl2---O5         129.3 (14)
  N4---C22---P1           109.6 (11)    O6---Cl2---O7           110.4 (8)
  N4---C22---H22A         109.8         O5\'---Cl2---O7         107.4 (14)
  P1---C22---H22A         109.8         O5---Cl2---O7           109.5 (8)
  N4---C22---H22B         109.8         O6---Cl2---O8\'         53.3 (14)
  P1---C22---H22B         109.8         O7\'---Cl2---O8\'       110.0 (8)
  H22A---C22---H22B       108.2         O5\'---Cl2---O8\'       109.9 (8)
  C28---C23---C24         119.8 (14)    O5---Cl2---O8\'         116.9 (15)
  C28---C23---P1          119.0 (12)    O7---Cl2---O8\'         133.6 (14)
  C24---C23---P1          120.8 (13)    O6---Cl2---O6\'         57.0 (13)
  C25---C24---C23         119.6 (17)    O7\'---Cl2---O6\'       109.1 (8)
  C25---C24---H24         120.2         O5\'---Cl2---O6\'       108.7 (8)
  C23---C24---H24         120.2         O5---Cl2---O6\'         73.9 (14)
  C26---C25---C24         121.8 (18)    O7---Cl2---O6\'         84.2 (13)
  C26---C25---H25         119.1         O8\'---Cl2---O6\'       108.3 (8)
  C24---C25---H25         119.1         O6---Cl2---O8           108.4 (8)
  C25---C26---C27         117.7 (16)    O7\'---Cl2---O8         82.0 (12)
  C25---C26---H26         121.2         O5\'---Cl2---O8         76.8 (14)
  C27---C26---H26         121.2         O5---Cl2---O8           108.6 (8)
  C26---C27---C28         122.5 (18)    O7---Cl2---O8           109.0 (8)
  C26---C27---H27         118.8         O8\'---Cl2---O8         55.9 (14)
  C28---C27---H27         118.8         O6\'---Cl2---O8         163.8 (14)
  C23---C28---C27         118.5 (16)                            
                                                                
  C50---Pt2---P1---C22    −59.8 (6)     Pt1---N3---C21---C20    −175.0 (9)
  N5---Pt2---P1---C22     118.4 (6)     C22---N4---C21---N3     −161.1 (12)
  C50---Pt2---P1---C29    59.2 (6)      C22---N4---C21---C20    20.9 (19)
  N5---Pt2---P1---C29     −122.6 (6)    C19---C20---C21---N3    3(2)
  C50---Pt2---P1---C23    179.3 (7)     C19---C20---C21---N4    −179.1 (13)
  N5---Pt2---P1---C23     −2.5 (7)      C21---N4---C22---P1     −178.1 (10)
  N2---Pt1---N1---C1      174.6 (16)    C29---P1---C22---N4     −148.3 (9)
  C16---Pt1---N1---C1     173.0 (18)    C23---P1---C22---N4     103.6 (10)
  N3---Pt1---N1---C1      −6.6 (16)     Pt2---P1---C22---N4     −22.4 (10)
  N2---Pt1---N1---C5      −2.8 (10)     C22---P1---C23---C28    155.5 (14)
  C16---Pt1---N1---C5     −4(2)         C29---P1---C23---C28    48.1 (16)
  N3---Pt1---N1---C5      176.0 (10)    Pt2---P1---C23---C28    −78.4 (15)
  C16---Pt1---N2---C6     −176.1 (12)   C22---P1---C23---C24    −31.1 (16)
  N1---Pt1---N2---C6      4.4 (11)      C29---P1---C23---C24    −138.5 (14)
  C16---Pt1---N2---C10    −2.9 (11)     Pt2---P1---C23---C24    95.0 (14)
  N1---Pt1---N2---C10     177.6 (11)    C28---C23---C24---C25   5(3)
  C16---Pt1---N3---C21    −72.3 (11)    P1---C23---C24---C25    −168.3 (16)
  N1---Pt1---N3---C21     107.6 (11)    C23---C24---C25---C26   −3(3)
  C16---Pt1---N3---C17    114.7 (11)    C24---C25---C26---C27   1(3)
  N1---Pt1---N3---C17     −65.4 (11)    C25---C26---C27---C28   0(3)
  N6---Pt2---N5---C35     177.4 (17)    C24---C23---C28---C27   −4(3)
  C50---Pt2---N5---C35    166.7 (16)    P1---C23---C28---C27    169.1 (16)
  P1---Pt2---N5---C35     −8.3 (17)     C26---C27---C28---C23   2(3)
  N6---Pt2---N5---C39     −6.1 (11)     C22---P1---C29---C34    −45.2 (13)
  C50---Pt2---N5---C39    −17 (2)       C23---P1---C29---C34    63.8 (13)
  P1---Pt2---N5---C39     168.1 (10)    Pt2---P1---C29---C34    −170.5 (10)
  C50---Pt2---N6---C40    −176.6 (13)   C22---P1---C29---C30    134.6 (11)
  N5---Pt2---N6---C40     7.4 (12)      C23---P1---C29---C30    −116.4 (12)
  C50---Pt2---N6---C44    −7.6 (10)     Pt2---P1---C29---C30    9.3 (12)
  N5---Pt2---N6---C44     176.3 (11)    C34---C29---C30---C31   −1(2)
  C5---N1---C1---C2       −3(3)         P1---C29---C30---C31    179.5 (12)
  Pt1---N1---C1---C2      −180.0 (13)   C29---C30---C31---C32   −1(3)
  N1---C1---C2---C3       1(3)          C30---C31---C32---C33   3(3)
  C1---C2---C3---C4       2(3)          C31---C32---C33---C34   −3(3)
  C2---C3---C4---C5       −3(3)         C32---C33---C34---C29   1(2)
  C3---C4---C5---N1       1(2)          C30---C29---C34---C33   1(2)
  C3---C4---C5---C6       179.2 (16)    P1---C29---C34---C33    −179.5 (12)
  C1---N1---C5---C4       2(2)          C39---N5---C35---C36    2(3)
  Pt1---N1---C5---C4      179.5 (12)    Pt2---N5---C35---C36    178.0 (16)
  C1---N1---C5---C6       −176.5 (14)   N5---C35---C36---C37    −5(4)
  Pt1---N1---C5---C6      1.3 (16)      C35---C36---C37---C38   7(4)
  C10---N2---C6---C7      7(2)          C36---C37---C38---C39   −6(3)
  Pt1---N2---C6---C7      −179.7 (12)   C35---N5---C39---C38    −2(3)
  C10---N2---C6---C5      −177.9 (12)   Pt2---N5---C39---C38    −178.4 (14)
  Pt1---N2---C6---C5      −4.7 (17)     C35---N5---C39---C40    −178.5 (17)
  C4---C5---C6---N2       −176.2 (14)   Pt2---N5---C39---C40    4.7 (19)
  N1---C5---C6---N2       1.9 (19)      C37---C38---C39---N5    4(3)
  C4---C5---C6---C7       −2(3)         C37---C38---C39---C40   −179.3 (18)
  N1---C5---C6---C7       176.5 (15)    C44---N6---C40---C41    8(3)
  N2---C6---C7---C8       −3(2)         Pt2---N6---C40---C41    176.8 (13)
  C5---C6---C7---C8       −177.0 (16)   C44---N6---C40---C39    −175.5 (13)
  C6---C7---C8---C9       1(3)          Pt2---N6---C40---C39    −6.9 (19)
  C7---C8---C9---C10      −3(3)         N5---C39---C40---N6     1(2)
  C8---C9---C10---N2      7(2)          C38---C39---C40---N6    −176.0 (16)
  C8---C9---C10---C11     177.0 (17)    N5---C39---C40---C41    176.8 (17)
  C6---N2---C10---C9      −9(2)         C38---C39---C40---C41   0(3)
  Pt1---N2---C10---C9     177.6 (11)    N6---C40---C41---C42    −6(3)
  C6---N2---C10---C11     179.0 (12)    C39---C40---C41---C42   178.6 (18)
  Pt1---N2---C10---C11    5.6 (16)      C40---C41---C42---C43   0(3)
  C9---C10---C11---C16    −176.9 (16)   C41---C42---C43---C44   3(3)
  N2---C10---C11---C16    −6.3 (19)     C40---N6---C44---C43    −5(2)
  C9---C10---C11---C12    8(3)          Pt2---N6---C44---C43    −173.6 (12)
  N2---C10---C11---C12    178.9 (13)    C40---N6---C44---C45    179.0 (14)
  C16---C11---C12---C13   2(2)          Pt2---N6---C44---C45    10.1 (17)
  C10---C11---C12---C13   176.4 (16)    C42---C43---C44---N6    −1(3)
  C11---C12---C13---C14   −2(3)         C42---C43---C44---C45   174.6 (17)
  C12---C13---C14---C15   2(3)          N6---C44---C45---C46    172.9 (14)
  C13---C14---C15---C16   −3(3)         C43---C44---C45---C46   −3(3)
  C14---C15---C16---C11   3(2)          N6---C44---C45---C50    −7(2)
  C14---C15---C16---Pt1   −178.8 (13)   C43---C44---C45---C50   176.9 (15)
  C12---C11---C16---C15   −3(2)         C44---C45---C46---C47   −176.8 (16)
  C10---C11---C16---C15   −177.5 (14)   C50---C45---C46---C47   3(3)
  C12---C11---C16---Pt1   179.0 (11)    C45---C46---C47---C48   −5(3)
  C10---C11---C16---Pt1   4.1 (17)      C46---C47---C48---C49   2(3)
  N2---Pt1---C16---C15    −178.8 (16)   C47---C48---C49---C50   2(3)
  N3---Pt1---C16---C15    2.4 (17)      C48---C49---C50---C45   −4(2)
  N1---Pt1---C16---C15    −177.2 (15)   C48---C49---C50---Pt2   176.0 (13)
  N2---Pt1---C16---C11    −0.7 (11)     C46---C45---C50---C49   1(2)
  N3---Pt1---C16---C11    −179.5 (10)   C44---C45---C50---C49   −179.1 (14)
  N1---Pt1---C16---C11    1(3)          C46---C45---C50---Pt2   −179.0 (12)
  C21---N3---C17---C18    2(2)          C44---C45---C50---Pt2   1.2 (16)
  Pt1---N3---C17---C18    175.7 (12)    N6---Pt2---C50---C49    −176.6 (17)
  N3---C17---C18---C19    −4(2)         N5---Pt2---C50---C49    −165.9 (15)
  C17---C18---C19---C20   4(2)          P1---Pt2---C50---C49    9.2 (16)
  C18---C19---C20---C21   −4(2)         N6---Pt2---C50---C45    3.1 (10)
  C17---N3---C21---N4     −179.9 (12)   N5---Pt2---C50---C45    14 (2)
  Pt1---N3---C21---N4     6.9 (16)      P1---Pt2---C50---C45    −171.1 (9)
  C17---N3---C21---C20    −1.9 (19)                             
  ----------------------- ------------- ----------------------- -------------

###### Selected geometric parameters (Å, °)

  ----------- ------------
  Pt1---N2    1.928 (13)
  Pt1---C16   1.990 (15)
  Pt1---N3    2.038 (14)
  Pt1---N1    2.079 (11)
  Pt2---N6    1.993 (13)
  Pt2---C50   2.014 (14)
  Pt2---N5    2.164 (14)
  Pt2---P1    2.241 (4)
  ----------- ------------

  ---------------- -----------
  N2---Pt1---C16   82.8 (6)
  N2---Pt1---N3    178.1 (4)
  C16---Pt1---N3   98.7 (6)
  N2---Pt1---N1    79.5 (5)
  C16---Pt1---N1   162.3 (6)
  N3---Pt1---N1    99.0 (5)
  N6---Pt2---C50   81.7 (6)
  N6---Pt2---N5    77.4 (5)
  C50---Pt2---N5   158.8 (6)
  N6---Pt2---P1    173.4 (4)
  C50---Pt2---P1   95.0 (5)
  N5---Pt2---P1    106.2 (4)
  ---------------- -----------
