Results: Studied and evaluated procedures to quantify microelements in herbal Scutellaria barbata D Don by atomic absorption spectrometric method with high repeatability, specificity, and accuracy. Apply established procedure to determine the amount of microelements in purchased samples of herbal Scutellaria barbata D Don, the obtained results are: Cu content is in the range of 18 - 38 ppm (RSD = 3, 6%, 95% recovery rate), Zn content is about 80 ppm (RSD = 2, 37%, 91% recovery rate), whereas Fe content is in the range of 160 - 650 ppm (RSD = 3, 65%, 94% recovery rate), while Pb content is as low as 3 ppm (RSD = 3, 99%, 93% recovery rate).