Results: Proceeding of the synthesized heptakis (2, 3, 6-tri-O-acetyl) - β-CD, heptakis [2, 3, 6-tri-O - (2-bromo-isobutyl)] - β-CD, heptakis [2, 3, 6-tri-O - (2-morpholinyl isobutyryl)] - β-CD, heptakis (6-O-tert-butyldimethylsilyl) - β-CD, heptakis (2, 3-di-O-acetyl-6-O-tert-butyldimethylsilyl) - β-CD were established.