List the bond type and the bond ID of the atom 45.
bond ID of atom 45 refers to SUBSTR(atom_id, 7, 2) + 0 = 45; double bond refers to bond_type = ' = '; single bond refers to bond_type = '-'; triple bond refers to bond_type = '#';
SELECT T1.bond_type, T1.bond_id FROM bond AS T1 INNER JOIN connected AS T2 ON T1.bond_id = T2.bond_id WHERE SUBSTR(T2.atom_id, 7, 2) = '45'