4.7. 
The sample preparation for the All NMR experiments were acquired using TopSpin 3.6.2 software in a 14.1 Tesla Bruker spectrometer (600 MHz for hydrogen frequency), equipped with a 5 mm TCI cryoprobe at 298 K. For the Additionally, 2D COrrelated SpectroscopY (COSY), Hetero Single Quantum Coherence (HSQC), and Heteronuclear Multiple Bond Correlation (HMBC) experiments were used to auxiliate in the identification of the most relevant compounds initially annotated by Chenomx software. The assumed parameters for 2D experiments were as follows: SWF1 = 10 ppm and SWF2 = 10 ppm, d1 = 2 s, size of fid in F1 = 256 and F2 = 4096, and ns = 32 for COSY experiment; SWF1 238.82 ppm and SWF2 10 ppm, d1 = 2 s, size of fid in F1 = 256 and F2 = 4096 for both HSQC and HMBC experiments, ns = 128 and ns = 256 for HSQC and HMBC experiments, respectively.