It is divided into two settlements, Pavliani proper or Ano Pavliani (Άνω Παύλιανη) and Nea Pavliani (Νέα Παύλιανη) or Kato Pavliani (Κάτω Παύλιανη).
Pavliani is split into two distinct settlements: Ano Pavliani (Upper Pavliani) and Nea Pavliani (New Pavliani), or Kato Pavliani (Lower Pavliani).