In 1867, she married Amadeo, then Duke of Aosta, second son of King Victor Emmanuel II of Italy. In 1870, her husband became the king of Spain, making her queen consort.
In 1867, she married Amadeo, who at that time held the title of Duke of Aosta and was the second son of King Victor Emmanuel II of Italy. In 1870, her husband ascended to the throne of Spain, becoming queen consort.