Smart glass is seen in use in White Collar season 1 episode 8 ``Hard Sell'' when Neal comes to tell Daniel Reed that Avery plans to betray him. Daniel flips a switch and his office window becomes frosted over, preventing Avery from peeking inside while they talk. Smart glass was featured in the 2012 James Bond movie Skyfall, revealing Raoul Silva to M after he is captured.
Raoul Silva
M