**Photocatalytic Hydrogen Evolution**

Special Issue Editors

**Misook Kang Vignesh Kumaravel**

MDPI • Basel • Beijing • Wuhan • Barcelona • Belgrade • Manchester • Tokyo • Cluj • Tianjin

*Special Issue Editors* Misook Kang Yeungnam University Korea

Vignesh Kumaravel Institute of Technology Sligo Ireland

*Editorial Office* MDPI St. Alban-Anlage 66 4052 Basel, Switzerland

This is a reprint of articles from the Special Issue published online in the open access journal *Catalysts* (ISSN 2073-4344) (available at: https://www.mdpi.com/journal/catalysts/special issues/hydrogen evolution).

For citation purposes, cite each article independently as indicated on the article page online and as indicated below:

LastName, A.A.; LastName, B.B.; LastName, C.C. Article Title. *Journal Name* **Year**, *Article Number*, Page Range.

**ISBN 978-3-03936-310-0 (Pbk) ISBN 978-3-03936-311-7 (PDF)**

Cover image courtesy of Vignesh Kumaravel.

c 2020 by the authors. Articles in this book are Open Access and distributed under the Creative Commons Attribution (CC BY) license, which allows users to download, copy and build upon published articles, as long as the author and publisher are properly credited, which ensures maximum dissemination and a wider impact of our publications.

The book as a whole is distributed by MDPI under the terms and conditions of the Creative Commons license CC BY-NC-ND.

## **Contents**

## **About the Special Issue Editors**

**Misook Kang** (Professor) obtained her Ph.D. in energy and hydrocarbon chemistry from Kyoto University, Japan in 1998. She was a full-time Research Professor at Sungkyunkwan and KyungHee University in Korea from 1999 to 2005, and was involved in photocatalysis research work. Since 2006, she has been a professor at the school of chemistry and biochemistry of Yeungnam University in Gyeongbuk. Her research interests are in the area of renewable energy, particularly focused on hydrogen production from photo- and thermal-catalysis using various nanomaterials. She has, to date, published more than 250 papers on energy and environment-related topics in peer-reviewed SCI(E) journals. In addition, she has received numerous academic awards, including the Gyeongbuk Science and Technology Award (the Women's S & T Award) in 2015. She served as a member of the Editorial Board of the *Journal of Industrial Engineering and Chemistry* (JIEC) from 2008 to 2014. Currently, she is the Acting Financial Director in the Korean Society of Industrial and Engineering Chemistry (KSIEC).

**Vignesh Kumaravel** (Senior Research Fellow) obtained his Ph.D. in Chemistry from Madurai Kamaraj University, India in 2013. He later worked as a Research Professor at Yeungnam University, Republic of Korea. He was then awarded a post-doctoral fellowship for an industrial project at Universiti Sains Malaysia. In October 2016, he joined Texas A & M University, Qatar, as an Assistant Research Scientist. Since March 2018 Vignesh has been working at IT Sligo as a Senior Research Fellow in the Renewable Engine project. He has published several scientific research articles in international peer-reviewed journals and presented his research findings at several international conferences. He has also delivered various invited international talks in the Republic of Korea, Spain, India, etc. He is acting as a co-investigator for three major research grants sponsored by Malaysian funding agencies. He is also acting as a potential reviewer for many Elsevier, ACS, RSC and Wiley journals. To his credit, he has reviewed more than 50 research articles.

### *Editorial* **Photocatalytic Hydrogen Evolution**

**Vignesh Kumaravel 1,\* and Misook Kang 2,\***

Received: 21 April 2020; Accepted: 26 April 2020; Published: 1 May 2020

Solar energy conversion is one of the sustainable technologies that tackles the global warming and energy crisis. Photocatalytic hydrogen (H2) production is a clean technology to produce eco-friendly fuel with the help of semiconductor nanoparticles and abundant sunlight irradiation. Titanium oxide (TiO2), graphitic-carbon nitride (g-C3N4) and cadmium sulfide (CdS) are the most widely explored photocatalysts in recent decades for water splitting.

As the guest editors, we have comprehensively investigated the role of sacrificial agents on the H2 production efficiency of TiO2, g-C3N4 and CdS photocatalysts [1]. The activity of the catalysts was evaluated without any noble metal co-catalysts. The effects of the most widely reported sacrificial agents were evaluated in this work. The activity of the catalysts was influenced by the number of hydroxyl groups, alpha hydrogen and carbon chain length of the sacrificial agent. We found that glucose and glycerol are the most suitable sacrificial agents to produce H2 with minimum toxicity to the solution. The findings of this study would be highly favorable for the selection of a suitable sacrificial agent for photocatalytic H2 production.

Hong et al. demonstrated the photoelectrochemical (PEC) efficiency of MoSe2/Si nanostructures for H2 production and carbon dioxide (CO2) reduction [2]. PEC deposition coupled with the rapid thermal annealing method was applied to fabricate the electrodes on the Si substrate. PEC H2 evolution and CO2 conversion efficiencies of the MoSe2/Si electrode were higher in visible light irradiation as compared to dark conditions.

Kim et al. synthesised monodispersed spherical TiO2 particles with a disordered rutile surface for photocatalytic H2 production [3]. The photocatalyst was synthesised through sol-gel and a chemical reduction technique using Li/ethylenediamine (Li/EDA) solution. The samples were calcined at various temperatures to tune the anatase to the rutile phase ratio. The disordered rutile surface and mixed crystalline phase of TiO2 significantly increased the H2 production under solar light irradiation.

Idrees et al. reported the photocatalytic activity of Nb2O5/g-C3N4 heterostructures for molecular H2 production under simulated solar light irradiation [4]. A hydrothermal technique was utilised to develop the three dimensional Nb2O5/g-C3N4 heterostructure with a high surface area. H2 production efficiency of Nb2O5/g-C3N4 (10 wt. %) was higher than that of pure Nb2O5 and g-C3N4. The photogenerated electron hole pairs were successfully separated through a direct Z-scheme mechanism at the heterojunction.

Kim and Woodward described the band gap modulation of tantalum (V) perovskite by anion control [5]. Perovskites such as BaTaO2N, SrTaO2N, CaTaO2N, KTaO3, NaTaO3 and TaO2F were studied in this work. Pt-loaded CaTaO2N was utilised as a visible-light-driven photocatalyst for H2 production using CH3OH as the sacrificial agent.

Son et al. reported the impact of sulfur defects on the H2 production efficiency of a CuS@CuGaS2 heterojunction under visible light irradiation [6]. The activity of the CuS@CuGaS2 heterojunction was higher as compared to pure CuS. This was ascribed to the introduction of structural defects to promote the photo-generated electron hole separation.

The recent accomplishments in the synthesis and application of various photocatalysts for H2 production are briefly reviewed by Zhang et al. [7]

Tremendous efforts should be taken in the future to commercialise this photocatalytic technology at the industry level. The studies should also be performed with cheap materials, industrial wastewater and seawater for H2 production.

Finally, we would like to convey our sincere thanks to all the authors for their significant contributions in this special issue.

**Author Contributions:** Conceptualization, V.K. and M.K.; Review and editing, V.K and M.K. All authors have read and agreed to the published version of the manuscript.

**Conflicts of Interest:** The authors declare no conflict of interest

#### **References**

© 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).

## *Article* **Photocatalytic Hydrogen Production: Role of Sacrificial Reagents on the Activity of Oxide, Carbon, and Sulfide Catalysts**

#### **Vignesh Kumaravel 1,2,\*, Muhammad Danyal Imam 3, Ahmed Badreldin 3, Rama Krishna Chava 4, Jeong Yeon Do 4, Misook Kang 4,\* and Ahmed Abdel-Wahab 3,\***

Received: 15 February 2019; Accepted: 11 March 2019; Published: 18 March 2019

**Abstract:** Photocatalytic water splitting is a sustainable technology for the production of clean fuel in terms of hydrogen (H2). In the present study, hydrogen (H2) production efficiency of three promising photocatalysts (titania (TiO2-P25), graphitic carbon nitride (*g*-C3N4), and cadmium sulfide (CdS)) was evaluated in detail using various sacrificial agents. The effect of most commonly used sacrificial agents in the recent years, such as methanol, ethanol, isopropanol, ethylene glycol, glycerol, lactic acid, glucose, sodium sulfide, sodium sulfite, sodium sulfide/sodium sulfite mixture, and triethanolamine, were evaluated on TiO2-P25, *g*-C3N4, and CdS. H2 production experiments were carried out under simulated solar light irradiation in an immersion type photo-reactor. All the experiments were performed without any noble metal co-catalyst. Moreover, photolysis experiments were executed to study the H2 generation in the absence of a catalyst. The results were discussed specifically in terms of chemical reactions, pH of the reaction medium, hydroxyl groups, alpha hydrogen, and carbon chain length of sacrificial agents. The results revealed that glucose and glycerol are the most suitable sacrificial agents for an oxide photocatalyst. Triethanolamine is the ideal sacrificial agent for carbon and sulfide photocatalyst. A remarkable amount of H2 was produced from the photolysis of sodium sulfide and sodium sulfide/sodium sulfite mixture without any photocatalyst. The findings of this study would be highly beneficial for the selection of sacrificial agents for a particular photocatalyst.

**Keywords:** photocatalysis; TiO2; *g*-C3N4; CdS; energy

#### **1. Introduction**

Photocatalytic hydrogen (H2) production via water splitting is a sustainable and renewable energy production technology with negligible impact on the environment [1] (Figure 1). H2 is one of the most promising and clean energy sources for the future, with water as the only combustion product. After the invention of photo-electrochemical water splitting in 1972 [2] by Fujishima and Honda, nearly 9000 research articles have been published, outlining the use of various photocatalysts. In particular, most of the research works have been carried out using powder photocatalysts (except photo-electrochemical studies). The reported materials in the recent years are categorized as oxide [3–149], carbon [3,81,150–237], and sulfide [3,14,17,35,58,59,113,114,119,128,133,154,164,169,177,181,

195,203,208,210,215,220,227,230,235,238–345] photocatalysts. Titanium oxide–P25 (TiO2-P25), graphitic carbon nitride (*g*-C3N4), and cadmium sulfide (CdS) are the most extensively studied photocatalysts for water splitting. Many review articles have also been published [1,116,163,167,225,237,238,245,346–419] discussing the various features of the photocatalytic water splitting, such as fundamental concepts, theoretical principles, nature (morphology, surface characteristics, and optical properties) of the photocatalyst, role of co-catalyst/sacrificial reagents, mechanism, kinetics, etc. Nevertheless, there is still not many comprehensive studies to identify an appropriate sacrificial reagent with respect to the nature of a photocatalyst.

**Figure 1.** Schematic representation of the water-splitting process on a photocatalyst surface under light irradiation [1]. Reproduced with permission from Ref. [1]. Copyright 2019, Elsevier.

Sacrificial agents or electron donors/hole scavengers play a prominent role in photocatalytic H2 production because the water splitting is energetically an uphill reaction (ΔH0 = 286 kJ mol−1). It is realized that methanol, triethanolamine, and sodium sulfide/sodium sulfite are the most commonly used sacrificial reagents for oxide, carbon, and sulfide photocatalysts, respectively. In most of the cases, fresh water (e.g., deionized water or double distilled water) has been used to evaluate the H2 production efficiency in a micro photo-reactor (volume in the range of 30 to 70 mL) with a strong light irradiation source (nearly ≤ 300 W). However, the vitality and utilization of this technology have not been comprehensively studied in a real environment. Moreover, the commercialization of this technology is still restrained by its poor efficiency and the use of expensive noble metals (like Pt, Au, Pd, Rh) as co-catalysts. Most of the published results do not have much consistency in terms of efficiency. For example, different efficiency values have been reported for pure TiO2 using methanol as a scavenger (Table 1). This discrepancy is ascribed to the following reasons: photo-reactor design, inert gas (Ar or N2) purging flow rate, light irradiation source, gas sampling method, gas chromatography (GC) analysis conditions, calculations, etc.

**Table 1.** Photocatalytic H2 production efficiency of TiO2 using methanol sacrificial agent.

The photochemical reactions of sacrificial agents (methanol, ethanol, isopropanol, ethylene glycol, glycerol, glucose, lactic acid, triethanolamine, sodium sulfide, sodium sulfite, and sodium sulfide/sodium sulfite mixture) and their degradation products during H2 production are summarized as follows:

#### **Methanol [422] (MeOH):**

$$\rm H\_2O\_{(l)} + h^+ \rightarrow \rm \rm \rm OH + H^+ \tag{1}$$

$$\text{CH}\_3\text{OH}\_{(l)} + \text{"OH} \rightarrow \text{"CH}\_2\text{OH} + \text{H}\_2\text{O}\_{(l)}\tag{2}$$

$$\text{\textbullet CH}\_2\text{OH} \rightarrow \text{HCHO}\_{(\text{l})} + \text{H}^+ + \text{e}^- \tag{3}$$

$$2\text{H}^+ + 2\text{e}^- \rightarrow \text{H}\_2\text{ (g)}\tag{4}$$

$$\text{HCHO}\_{\text{(l)}} + \text{H}\_2\text{O}\_{\text{(l)}} \rightarrow \text{HCOOH}\_{\text{(l)}} + \text{H}\_2\text{(g)}\tag{5}$$

$$\text{HCOOH (l)} \rightarrow \text{CO2 (g)} + \text{H}\_2\text{ (g)}\tag{6}$$

Overall reaction:

$$\text{CH}\_3\text{OH}\_{\text{(l)}} + \text{H}\_2\text{O}\_{\text{(l)}} \rightarrow \text{CO}\_2\text{ (g)} + \text{3H}\_2\text{ (g)}\tag{7}$$

**Ethanol [423] (EtOH):**

$$\text{CH}\_3\text{CH}\_2\text{OH} + \text{TiO}\_2 \rightarrow \text{ (S)}\text{CH}\_3\text{CH}\_2\text{O} - \text{Ti}^{4+} + \text{(S)}\text{OH} \tag{8}$$

$$\text{TiO}\_2 + \text{UV light} \rightarrow 2\text{e}^-\_{\text{(a)}} + 2\text{h}^+ \tag{9}$$

$$\text{C}\_{\text{(s)}}\text{CH}\_{\text{3}}\text{CH}\_{2}\text{O}-\text{Ti}^{4+} + 2\text{h}^{+} \rightarrow \text{(s)}\text{CH}\_{\text{3}}\text{CHO} + \text{Ti}^{4+} \tag{10}$$

$$\text{H}\_{\text{(s)}}\,\text{2OH} + \text{e}^-\_{\text{(a)}} \rightarrow \text{H}\_2 + \text{}\_{\text{(S)}}\,\text{2O}^{2+}\tag{11}$$

Here, (s) represents the photocatalyst surface and (a) denotes the photo-excited electrons by UV light.

**Isopropanol [424] (IPA):**

$$\left[\mathrm{^{S}\_{\mathrm{Cd}^{2+}}} > (\mathrm{CdS})\right]\_{2} + \mathrm{H\_{2}O} \rightarrow \mathrm{^{S}\_{\mathrm{Cd}^{2+}}} > \mathrm{Cd(II)}\mathrm{SH} + \mathrm{^{S}\_{\mathrm{Cd}^{2+}}} > \mathrm{S(-II)}\mathrm{Cd(II)OH} \tag{12}$$

$$\rm{^{S^{2-}}\_{\rm Cd^{2+}}} > \rm{CdSH^{+}\_{2}} \rightarrow \rm{^{S^{2-}}\_{\rm Cd^{2+}}} > \rm{CdSH + H^{+}} \tag{13}$$

$$^{\rm S^{2-}}\_{\rm Cd^{2+}} > \rm CdSH \rightarrow ^{\rm S^{2-}}\_{\rm Cd^{2+}} > \rm CdS- \ + H^{+} \tag{14}$$

$$\mathrm{^{S}\_{\mathrm{Cd}^{2+}}} > \mathrm{CdOH}\_{2}^{+} \to \mathrm{^{S}\_{\mathrm{Cd}^{2+}}} > \mathrm{CdOH} \, + \,\mathrm{H}^{+} \tag{15}$$

$$\rm{^{S^{2-}}\_{Cd^{2+}}} > \rm{CdOH} \rightarrow \rm{^{S^{2-}}\_{Cd^{2+}}} > \rm{CdO-} \rightarrow \rm{H^{+}} \tag{16}$$

$$\mathrm{^{S}\_{\mathrm{Cd}^{2+}}} > \mathrm{Cd(+\mathrm{I})S(0)^{+}} + \mathrm{C\_3H\_7OH} \rightarrow \mathrm{^{S}\_{\mathrm{Cd}^{2+}}} > \mathrm{Cd(+\mathrm{I})S(-\mathrm{I})H^{+} + \mathrm{C\_3H\_6^{\bullet}OH}} \tag{17}$$

$$\mathrm{^{S^{2-}}\_{\mathrm{Cd^{2+}}}} > \mathrm{Cd(+\Pi)\mathrm{S(-I)H^{+}} + \mathrm{C\_3H\_7OH} \rightarrow \mathrm{^{S^{2-}}\_{\mathrm{Cd^{2+}}}} > \mathrm{Cd(+\Pi)\mathrm{S(-II)H^{+}\_{2}} + \mathrm{C\_3H\_6^{\*}OH} \tag{18}$$

$$2\text{H}^\* \to \text{H}\_2\tag{19}$$

$$2\,\mathrm{C}\_{3}\mathrm{H}\_{6}^{\bullet}\mathrm{OH}^{\bullet}\to 2\,\mathrm{C}\_{3}\mathrm{H}\_{5}\mathrm{O}^{\bullet}+\mathrm{H}\_{2}\tag{20}$$

$$\mathrm{^{S}\_{\mathrm{Cd}^{2+}}} > \mathrm{Cd}(\mathrm{+II})\mathrm{S}(-\mathrm{II})\mathrm{H}\_{2}^{+} \rightarrow \mathrm{^{S}\_{\mathrm{Cd}^{2+}}} > \mathrm{Cd}(\mathrm{+II})\mathrm{S}(-\mathrm{II})\mathrm{H} + \mathrm{H}^{+} \tag{21}$$

$$\mathrm{^{S^{2-}}\_{\mathrm{Cd^{2+}}}} > \mathrm{CdOH} \, + \, \mathrm{e^{-}\_{\mathrm{CB}}} \to \mathrm{^{S^{2-}}\_{\mathrm{Cd^{2+}}}} > \mathrm{CdO^{-}} \, + \, \mathrm{H^{+}} \tag{22}$$

**Ethylene Glycol [76,425] (EG):**

$$\text{OHCH}\_2-\text{CH}\_2\text{OH} + \text{H}\_2\text{O} \xrightarrow{\text{TiO}\_2, \text{hv}} \text{OHCH}\_2-\text{CHO} \tag{23}$$

$$\text{OH}\\ \text{CH}\_2\text{-}-\text{CHO} \xrightarrow{\bullet \text{OH}} \text{OH}\\ \text{CH}\_2\text{-}-\text{COOH} \tag{24}$$

$$\text{OH}\\ \text{CH}\_2-\text{COOH} \rightarrow \text{CH}\_3\text{COOH} \tag{25}$$

$$\text{OHCH}\_2-\text{COOH} \rightarrow \text{HOOC}-\text{COOH} \tag{26}$$

$$\text{HCOOC} - \text{COOH} \rightarrow \text{HCOOH} \tag{27}$$

$$\text{HCOOH} \left(\text{or}\right) \text{CH}\_3\text{COOH} \left(\text{or}\right) \text{HOOC}-\text{COOH} \rightarrow \text{CO}\_2 + \text{H}\_2 + \text{CH}\_4 + \text{C}\_2\text{H}\_4 + \text{C}\_2\text{H}\_6 + \text{H}\_2\text{O} \text{ (28)}$$
  $\text{Clurolol 17201 (C19)}$

$$\text{Glycerol [130] (GLY):}$$

$$\begin{aligned} \text{C}\_3\text{H}\_8\text{O}\_3 + 3\text{H}\_2\text{O} + 14\text{h}^+\_{\text{(VB)}} &\rightarrow \text{intermediate} \begin{aligned} \text{C}\_2\text{H}\_4\text{O}\_2 &\rightarrow \text{intermediate} \begin{aligned} \text{C}\_2\text{H}\_4\text{O}\_2 &\rightarrow \text{C}\_2\text{H}\_4\text{O}\_3 &\rightarrow \text{C}\_3\text{H}\_6\text{O}\_3 &\text{ etc} \end{aligned} \\ &\rightarrow 3\text{CO}\_2 + 14\text{H}^+ \end{aligned} \end{aligned} \tag{29}$$

$$14\text{H}^{+} + 14\text{e}\_{\text{CB}}^{-} \rightarrow 7\text{H}\_{2}\text{ (g)}\tag{30}$$

**Glucose [9] (GLU):**

$$\rm C\_6H\_{12}O\_6 + H\_2O \text{ (anaerobic)} \rightarrow \rm C\_5H\_{10}O\_5 + HCOOH \text{ + } H\_{2(g)} \tag{31}$$

$$\rm C\_5H\_{10}O\_5 + H\_2O \rightarrow C\_4H\_8O\_4 + HCOOH + H\_2 \,\tag{32}$$

$$\text{H}\_{4}\text{H}\_{8}\text{O}\_{4} + \text{H}\_{2}\text{O} + \text{HCOOH} + \text{H}\_{2}\text{(g)}\\\text{(aeroic)} \rightarrow \text{HCOOH} + \text{H}\_{2(g)} + \text{CO}\_{2}\text{(g)}\tag{33}$$

$$\text{C}\_6\text{H}\_{12}\text{O}\_6 \xrightarrow{\text{TiO}\_2, \text{ hv}, \text{H}\_2\text{O}, \text{O}\_2} \text{C}\_6\text{H}\_{12}\text{O}\_7\tag{34}$$

$$\text{C}\_6\text{H}\_{12}\text{O}\_7 \xrightarrow{\text{TiO}\_2, \text{ hv}, \text{H}\_2\text{O}, \text{O}\_2} \text{C}\_6\text{H}\_{10}\text{O}\_8 \tag{35}$$

$$\text{C}\_6\text{H}\_{10}\text{O}\_8 \xrightarrow{\text{TiO}\_2, \text{ hv}, \text{H}\_2\text{O}, \text{O}\_2} \text{HCOOH} \text{ + } \text{H}\_{2(g)} + \text{CO}\_{2(g)}\tag{36}$$

**Lactic Acid [426] (LA):**

$$\text{CHg}-\text{CH(OH)}-\text{COOH} + \text{H}\_2\text{O} \xrightarrow{\text{TiO}\_2, \text{hv}} \text{CO}\_2 + \text{H}\_2 + \text{CHg}-\text{CO}-\text{COOH} \tag{37}$$

**Triethanolamine [427] (TEOA):**

$$\rm{C}\_{6}\rm{H}\_{15}\rm{NO}\_{3} \rightarrow \rm{C}\_{6}\rm{H}\_{15}\rm{NO}\_{3}^{+} + e^{-} \tag{38}$$

$$\rm{C}\_{6}\rm{H}\_{15}\rm{NO}\_{3}^{+} \rightarrow \rm{C}\_{6}\rm{H}\_{14}\rm{NO}\_{3}^{\bullet} + \rm{H}^{+} \tag{39}$$

$$\rm{C}\_6\rm{H}\_{14}\rm{NO}\_3^\bullet \rightarrow \rm{C}\_6\rm{H}\_{14}\rm{NO}\_3^+ + e^- \tag{40}$$

*Catalysts* **2019**, *9*, 276

$$\rm C\_6H\_{14}NO\_3^+ + H\_2O \rightarrow C\_4H\_{11}NO\_3 + CH\_3CHO + H^+ \tag{41}$$

**Sodium sulfide (Na2S) [428]:**

$$\text{Na2S} + \text{H2O} \rightarrow \text{2Na}^+ + \text{S}^{2-} \tag{42}$$

$$\rm{^{1}S^{2-}} + \rm{^{H}\_{2}O} \rightarrow \rm{HS^{-}} + \rm{OH^{-}} \tag{43}$$

$$\text{HS}^- + \text{hv} \to \text{HS}^- \tag{44}$$

$$\rm{HS^{-\*}} + \rm{HS^{-}} \rightarrow \ [(\rm{HS})\_2]^{-\*} \rightarrow \rm{H}\_2 + \rm{S\_2^{2-}} \tag{45}$$

**Sodium sulfite (Na2SO3) [429]:**

$$\text{Irradiation} : \text{ SO}\_3^{2-} \stackrel{\text{hv}}{\longrightarrow} \text{SO}\_3^{2-\*} \tag{46}$$

$$\text{Oxidation}: \text{SO}\_3^{2-\*} + 2\text{OH}^- \rightarrow \text{SO}\_4^{2-} + \text{H}\_2\text{O} + 2\text{e}^- \tag{47}$$

$$\text{Reduction} : \text{2H}\_2\text{O} + \text{2e}^- \rightarrow \text{H}\_2 + \text{2OH}^- \tag{48}$$

$$\text{Oxidation} : 2\text{SO}\_3^{2-} \rightarrow \text{S}\_2\text{O}\_6^{2-} + 2\text{e}^- \tag{49}$$

$$\text{Reduction}: \text{ 2H}\_2\text{O} + \text{ 2e}^- \rightarrow \text{H}\_2 + \text{2OH}^- \tag{50}$$

#### **Sodium sulfide and sodium sulfite mixture (Na2S and Na2SO3) [430]:**

Two different reaction pathways are involved when sodium sulfide and sodium sulfite mixture is used as a sacrificial agent.

$$\rm{HS}^{-}\_{\rm{(aq)}} \rightarrow \rm{HS}^{-}\_{\rm{(ads)}} \tag{51}$$

$$\text{HS}^- \text{(ads)} \stackrel{\text{hv}}{\longrightarrow} [\text{HS}^- \text{(ads)}]^\* \tag{52}$$

**Path A:**

$$\left[\text{HS}^{-}\left(\text{ads}\right)\right]^{\*} \rightarrow \text{H}^{\*} + \text{S}^{-}\left(\text{ads}\right) \tag{53}$$

$$\rm{^{1}S^{-} (ads) + } \rm{[HS^{-} (ads)]^{\*} \to [HS\_{2}^{2-}] \,\rm{q}} \tag{54}$$

$$\left[\mathrm{HS}\_{2}^{2-}\right]\mathrm{op}\rightarrow\mathrm{H}^{\*}+\mathrm{S}\_{2}^{2-}\text{ (ads)}\tag{55}$$

$$\text{H}^\* \text{H}^\* \to \text{H}\_2 \tag{56}$$

**Path B:**

$$\left[\mathrm{HS}^{-}\left(\mathrm{ads}\right)\right]^{\*} + \mathrm{S}^{0}\left(\mathrm{ads}\right) \rightarrow \left[\mathrm{HS}\_{2}^{-}\right]\mathrm{p} \tag{57}$$

$$\left[\mathrm{HS}\_{2}^{-}\right]\mathrm{p} + \mathrm{OH}^{-} + \mathrm{SO}\_{3}^{2-} + \mathrm{S}^{0}\mathrm{(ads)} \rightarrow \left[\mathrm{HS}\_{2}^{2-}\right]\mathrm{p} + \mathrm{OH}^{\bullet} + \mathrm{S}\_{2}\mathrm{O}\_{3}^{2-} \tag{58}$$

$$\mathrm{OH^{\bullet}} + \mathrm{SO\_{3}^{2-}} \stackrel{\mathrm{hy}}{\rightarrow} \mathrm{SO\_{4}^{2-}} + \mathrm{H^{\*}} \tag{59}$$

$$\text{2H}^\* \to \text{H}\_2$$

$$\rm{S}\left[\rm{HS}^{-}\rm{(ads)}\right]^{\*} + \rm{H}\_{2}\rm{O} \rightarrow \rm{S}^{0}\rm{(ads)} + \rm{H}\_{2} + \rm{OH}^{-}\tag{61}$$

$$\text{H}\_{2}\text{[HS}\_{2}^{-}\text{]}\text{q} + \text{OH}^{-} \rightarrow \text{H}\_{2}\text{O} + \text{S}\_{2}^{2-} \tag{62}$$

where (ads) denotes adsorption and Ǽ represents species, which can undergo intramolecular charge transfer.

The previous articles reported H2 production efficiencies with various combinations of photocatalysts and sacrificial reagents. This study provides detailed information on the selection of sacrificial reagents and photocatalysts for H2 production. The efficiencies of TiO2-P25, *g*-C3N4, and CdS were evaluated using methanol (MeOH), ethanol (EtOH), isopropanol (IPA), ethylene glycol (EG), glycerol (GLY), lactic acid (LA), glucose (GLU), sodium sulfide (Na2S), sodium sulfite (Na2SO3), sodium sulfide/sodium sulfite mixture (Na2S/Na2SO3), and triethanolamine (TEOA) as sacrificial reagents (organic and inorganic). The efficiency of a photocatalyst was described in terms of pH of medium and nature of the sacrificial agent (carbon chain length, alpha hydrogen, hydroxyl groups, binding interactions, etc). Besides, control experiments were executed to investigate the H2 production with only sacrificial reagents under solar light irradiation in the absence of photocatalyst.

#### **2. Results and Discussion**

#### *2.1. TiO2 P25*

Figure 2 shows the H2 production efficiency of TiO2 P25 using various sacrificial agents. H2 production efficiencies of TiO2/EG, TiO2/GLY, TiO2/Na2S/Na2SO3, TiO2/GLU, TiO2/Na2S were found to be 190.2 μmol, 130.8 μmol, 126 μmol, 120 μmol, and 120 μmol, respectively. H2 production efficiency of TiO2/MeOH system reduced to 81.6 μmol for the same period. The use of TEOA, EtOH, IPA, and Na2SO3 as sacrificial reagents resulted in poor H2 production, yielding 61.8 μmol, 49.8 μmol, 46.2 μmol, and 40.8 μmol, respectively. TiO2/LA mixture displayed the lowest yield of H2 production (only 27.6 μmol). TiO2/EG mixture showed the maximum H2 production (190.2 μmol) efficiency as compared to all other combinations. This is ascribed to the faster charge transfer reaction in the TiO2/EG system compared to the photo-generated electron-hole recombination process [431,432]. The length of the carbon chain, the number of hydroxyl groups, and dehydrogenation/decarbonylation characteristics of sacrificial agents are the primary features in controlling the H2 production efficiency. Moreover, the following properties of sacrificial agents could also strongly influence the efficiency: polarity and electron donating ability, adsorption capability on the photocatalyst surface, the formation of by-products, and the selectivity for reaction with photo-generated holes (e.g., decarboxylation process) [10,94,431–436]. Carbon monoxide (CO) is one of the main intermediates for the alcohols with a short carbon chain. Hence, the adsorption of CO on the active sites of TiO2 via chemisorption restricts further adsorption of alcohol on the photocatalyst surface [437]. The removal of CO as CO2 is the rate-determining step in H2 production. It depends on the adsorption efficiency and the number of alpha hydrogens of the sacrificial agent [437]. During the water-splitting process, the hydroxyl radical (•OH) abstracts alpha hydrogen from the alcohol to create •RCH2-OH radical, which gets further oxidized into an aldehyde, carboxylic acid, and CO2 [437]. Bahruji et al. [437] suggested that alkyl groups connected to the alcohol (e.g., CxHyOH) could yield the respective alkanes (e.g., Cx−1) during the water-splitting process. The alkane production rate was decreased with the increase of OH groups in alcohol [438]. In the case of polyols, the hydrogen atoms from the alpha carbon could be easily extracted and evolved in the form of H2 [438]. The alpha carbon atoms could be oxidized into CO2. The C atoms without OH groups (other than alpha C atoms) would be evolved in the form of alkanes [438]. Time-resolved transient absorption spectroscopy results revealed that carbohydrates and polyols (C2–C6) could rapidly react with ~50–60% holes (h+) within 6 ns as compared to other alcohols [439,440]. The OH groups could act as an anchor for the chemisorption of alcohols on the photocatalyst surface [438]. The coordination efficiency of alcohols with the Ti sites relies on the number of OH groups and the carbon chain length. This type of linkage could be beneficial for the utilization of holes to improve the H2 production and suppress the charge carrier recombination [438]. The first principle calculations showed that the formation of gap levels in TiO2 via the adsorption polyols could accelerate the hole trapping process [441]. Though EG showed maximum efficiency for TiO2-P25, glycerol and glucose are the most appropriate sacrificial agents for any kind of oxide photocatalyst. This owes to their (glucose and glycol) most abundance, less toxicity, low cost, and they can readily undergo dehydrogenation as compared to other alcohols [40,63,435].

**Figure 2.** Photocatalytic H2 production efficiency of TiO2-p25 using various sacrificial agents.

#### *2.2. g-C3N4*

H2 production efficiency of *g*-C3N4 with various sacrificial agents is shown in Figure 3. In this case, only the use of TEOA, Na2S, Na2SO3, and Na2S/Na2SO3 resulted in H2 production. H2 production efficiency of *g*-C3N4/Na2S (139.8 μmol) system was higher than that of *g*-C3N4/Na2S/Na2SO3 (127.2 μmol) and *g*-C3N4/Na2SO3 (5.4 μmol). *g*-C3N4/TEOA mixture showed the best efficiency (247.2 μmol) when compared to all other sacrificial agents. This can be ascribed to the fact that photo-corrosion and degradation of π conjugated structure [304] of amine rich *g*-C3N4 is secured by the effective binding of TEOA on the catalyst surface [112]. TEOA excellently consumes the photo-generated holes, improves the dispersion of photocatalyst, and acts as a binding ligand to improve the interaction of *g*-C3N4 with water molecules [204,442]. The results shown in Figure 3 also suggest that alcohols and glucose are not strongly adsorbed on the *g*-C3N4 surface for water-splitting reaction. This is attributed to the absence of hydrophilicity and surface characteristics (e.g., active sites, poor electrical conductivity, water oxidation ability) of *g*-C3N4 to facilitate a strong interfacial electron/hole transfer process on the catalyst surface. The poor crystallinity and basal planar structure of *g*-C3N4 endorse the electron-hole recombination [443]. Moreover, high activation energy and overpotential are required for H2 production on the *g*-C3N4 surface [182,211]. This could be rectified by the loading of noble metals or co-catalysts over *g*-C3N4 or fabricating Z-scheme photocatalysts. In most of the studies, it was reported that *g*-C3N4 acts as an outstanding template and there was no H2 production on *g*-C3N4 without any noble metal co-catalyst [444,445]. The results also demonstrated that the light absorption capability, chemical stability, and suitable band edge positions of narrow band-gap *g*-C3N4 are not the only decisive factors to enhance the H2 production efficiency.

**Figure 3.** Photocatalytic H2 production efficiency of *g*-C3N4 using various sacrificial agents.

#### *2.3. CdS*

Photocatalytic H2 production efficiency of CdS using various sacrificial agents is shown in Figure 4. The use of TEOA, Na2S, Na2SO3, Na2S/Na2SO3, and LA as sacrificial reagents resulted in H2 formation. CdS/TEOA system showed the maximum efficiency of 283.2 μmol of H2 as compared to all other sacrificial agents. The efficiency of CdS/Na2S, CdS/Na2SO3, CdS/LA systems was found to be 181.2 μmol, 154.8 μmol, and 84 μmol, respectively. The mixture of CdS/Na2S/Na2SO3 showed the lowest H2 production of 54 μmol after 6 h. Bare CdS is not stable under prolonged light irradiation because the sulfide ions on its surface are rapidly oxidized into sulfur through the reaction with photo-generated holes (photo-corrosion – CdS + 2h+ → Cd2+ + S) [308,446,447]. The sulfide oxidation of CdS can occur before the oxidation of water by holes [308,447]. Hence, the H2 production efficiency of CdS highly relies on the effective binding of sacrificial agents on its surface. The results showed that amine and sulfide/sulfite might be strongly bound to the CdS surface and it could effectively consume the holes as compared to alcohol and sugars. It is obviously noted that H2 is produced in high alkaline (amine, sulfide, and sulfite) and acidic (LA) pH mixtures when compared to neutral pH (alcohols and sugar). LA is converted into pyruvic acid and CO2 during the water-splitting reaction; this may slightly influence the pH and polarity of the reaction mixture. The sulfide ions from Na2S stabilizes CdS surface to terminate the surface defects originated from photo-corrosion. The electron-hole recombination process is strongly restrained by the sulfide ions at alkaline pH. When CdS is suspended in a water medium, thiol (Cd-SH) and hydroxyl (Cd-OH) groups are developed on its surface, which are highly pH dependent [310]. In the case of Na2S, the pH of the medium is alkaline, sulfide (S2 −) and hydrogen sulfide (HS−) are formed when Na2S is dissolved in water [310]. During light irradiation, S2 <sup>−</sup> and HS- are quickly oxidized into sulfate (SO4 <sup>2</sup>−) and polysulfide (S4 <sup>2</sup>−, S5 <sup>2</sup>−) ions, respectively [310]. The oxidation of sulfide by the photo-generated holes is much preferential as compared to the photo-corrosion of CdS [112]. The precipitation of yellow colored polysulfide ions diminishes the photocatalytic efficiency via acting as an optical filter and competing

with the H2 generation reaction. This could be restricted by the addition of Na2SO3 to generate more HS- and S2O3 <sup>2</sup><sup>−</sup> ions to enhance the photocatalytic activity [292]. However, the results shown in Figure 4 suggest that H2 production efficiency of Na2S/CdS or CdS/Na2SO3 are higher than that of CdS/Na2S/Na2SO3. The reasons could be predicted by the photolysis experiments of sacrificial agents. The pH of TEOA/water mixture would be around 12, which could enhance the H2 production efficiency via strong interfacial bonding on the CdS surface and its reaction with photo-generated holes [204].

**Figure 4.** Photocatalytic H2 production efficiency of CdS using various sacrificial agents.

#### *2.4. Photolysis*

Photolysis experiments were carried out for all sacrificial agents in water for 6 h of light irradiation without the additions of photocatalysts. Control experiments were also carried out in the absence of sacrificial agents to evaluate the efficiency of the photocatalyst. There was no H2 production in the absence of any sacrificial agents for TiO2-p25, *g*-C3N4, and CdS. The results of photolysis experiments with sacrificial reagents under solar light in the absence of photocatalysts are shown in Figure 5. Interestingly, a remarkable amount of H2 was evolved from Na2S/water (159 μmol), Na2SO3/water (51 μmol), and Na2S/Na2SO3/water (134.4 μmol) systems without photocatalyst. It was observed that the H2 production efficiency was increased with respect to the concentration of sulfide or sulfite. When compared to results obtained in the presence of photocatalysts, it could be observed that the photocatalysts, such as TiO2-p25 and *g*-C3N4, surprisingly reduced the actual H2 production efficiency of sulfide system. There was not a significant increment in the efficiency of CdS/Na2S as compared to the photolysis of Na2S. However, the efficiency of CdS/Na2SO3 was higher than that of Na2SO3 photolysis. It is also noted that a high concentration of sulfide/sulfite mixture (in the range of 0.2 M to 1 M) was used in most of the studies for H2 production [246,264,273,300,448–451]. In such cases, the photolysis of sulfide or sulfite solutions were not evaluated. Hence, the H2 production should have been mainly originated via photolysis of sulfide/sulfite mixture rather than the photocatalytic

effect. The photochemical reactions involved in H2 generation from sulfide and sulfite solutions are described in detail from Equations (42)–(62) [428–430].

**Figure 5.** H2 production efficiency of sacrificial agents without photocatalyst (photolysis).

Li et al. [430] investigated the photochemical generation of H2 from sulfide and sulfite mixture solutions. They found that the pH of sulfide/sulfite mixture (~13.14) was slightly decreased (~12.94) after the completion of photolysis experiments. The addition of a small amount of sulfite into the sulfide solution could not amplify the H2 production. Nevertheless, the elemental sulfur or polysulfide originated from HS– is efficiently consumed by SO3 <sup>2</sup><sup>−</sup> to improve the photonic efficiency. It is strongly recommended to study the effect of photolysis when the sulfide/sulfite mixture is used as the sacrificial agent to evaluate the H2 production efficiency of the photocatalyst. The elemental sulfur could be filtered out by passing hydrogen sulfide (H2S) gas in the aqueous solution under nitrogen atmosphere [428]. The resulting filtrate could be reused for photolytic H2 production [428].

Wang et al. [112] suggested that Na2S/Na2SO3, MeOH, and TEOA were the most appropriate sacrificial agents for sulfide, oxide, and carbon-based photocatalysts. However, the experiments were not performed to study the effect of photolysis, especially the sulfide or sulfite solutions. A high concentration of sacrificial agents was used to evaluate the photocatalytic activity. The photocatalytic experiments were not described in detail. Moreover, the effect of most earth abundant glucose and glycerol were not investigated on the H2 production efficiency. Sulfur dioxide (SO2) emission from the flue gas can be absorbed as Na2SO3 solution using dilute sodium hydroxide. The photolysis of such sodium sulfite solution is an eco-friendly way to produce H2 gas [429]. Only a few studies were focused on using wastewater for H2 generation. Souza and Silva [310] studied the feasibility of using tannery sludge wastewater for photocatalytic H2 generation using CdS. The photolysis of sulfide-rich wastewater or industrial effluent is the foremost choice to produce green energy in a sustainable way via photocatalysis.

#### *2.5. TOC Analysis*

TOC analysis was carried out for solutions after the photocatalytic experiments, to assess the degradation of organic sacrificial agents in the solutions at the end of 6 h experiment. Table 2 summarizes the TOC results for the solutions of TiO2-p25. The results suggest the effective utilization of the organic sacrificial agents by TiO2-P25 for H2 production. TOC was reduced almost half for most of the sacrificial agents after 6 h except for glucose. This is ascribed to the formation of more organic intermediates when glucose is utilized as the sacrificial agent.

**Table 2.** TOC of solutions after the completion of the photocatalytic reaction.

#### **3. Experimental**

All the chemicals used were of analytical grade and used as received without further purification. TiO2 P25 was purchased from Sigma Aldrich (Darmstadt, Germany), *g*-C3N4 was synthesized by the calcination of urea at 550 ◦C for 2 h [452]. CdS was synthesized via the hydrothermal method [453]. Photocatalytic experiments were carried out using an immersion type reactor (Lelesil innovative systems, Thane, Maharashtra, India) as shown in Figure 6. All the reactions were carried out without any noble metal co-catalyst. The reactor is a tightly closed setup with a total volume of 1000 mL. Reactions were carried out using 500 mL of double distilled water with 0.5 g/L of photocatalyst and desired amount of sacrificial reagent (based on the literature). The empty headspace was kept constant at 500 mL for all reactions. The sacrificial agent concentration was fixed at 10% (alcohol, amine, acid) and 0.1 M (glucose, sodium sulfide, sodium sulfite, sodium sulfide/sodium sulfite mixture). The mixture was stirred under nitrogen purging for 1 h after which, the purging was stopped, and the reactor was closed immediately. The mixture was irradiated using a 300 W Xenon arc lamp without any UV cutoff filter (simulated solar light source). H2 sampling was carried out for every 1 h using a 250 μL sample lock gas tight syringe. At the end of the photoreaction time, when organic sacrificial reagents were used, the mixture was filtered using a 0.45 μm micro-filter, and the filtrate was analyzed using a total organic carbon (TOC; Shimadzu, Japan) analyzer to measure the loss of reagents by mineralization. H2 was analyzed using Agilent gas chromatography (USA) with thermal conductivity detector (TCD), manual injection, carrier gas N2, molecular sieve 5 A◦ column with 2-m length, front inlet temperature 140 ◦C, and detector temperature 150 ◦C.

**Figure 6.** (**a**) Schematic and (**b**) photograph of the reactor used for photocatalytic H2 production.

#### **4. Summary and Outlook**

Different types of photocatalysts have been successfully investigated for H2 production using various organic and inorganic sacrificial agents. The surface of an oxide photocatalyst would be more suitable for polyols and sugars for adsorption as compared to amines and sulfides. Amines are the most appropriate of sacrificial agents for carbon and sulfide photocatalysts. CdS/TEOA (283.2 μmol), *g*-C3N4/TEOA (247.2 μmol), and TiO2/EG (190.2 μmol) are the three best systems with maximum H2 production in this study. H2 could also be generated via the direct photolysis of sodium sulfide solution in the absence of any catalyst. TiO2-p25 and *g*-C3N4 suppress the self-H2 generation efficiency of Na2S photolysis. More technological developments are required for the practical application of water-splitting in a scalable and economically feasible way. Stable, affordable, and active co-catalysts should be developed in the future to replace the expensive noble metals to achieve a significant amount of H2 production. In most of the studies, precious fresh water with a high concentration of sacrificial agents was used in a small reactor to generate H2. Hence, future studies should be focused on a pilot scale using industrial wastewater and seawater rather than using fresh water.

**Author Contributions:** Conceptualization V.K. and A.A-W.; Supervision, V.K., A.A-W. and M.K.; Methodology, design, investigation, data creation and analysis, V.K.; Methodology, data analysis, and original draft preparation, M.D.I and A.B.; Methodology and data analysis, J.Y.D. and R.K.C.

**Funding:** The authors are grateful to Texas A&M University at Qatar and Qatar Foundation for financial support. **Conflicts of Interest:** The authors declare no conflict of interest.

#### **References**

© 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).


*<IP_ADDRESS>. MIE (Aerosol) scattering*

Mie scattering occurs when the particle diameter is equal or larger than one-tenth the incident laser beam wavelength, see Table 4. Mie scattering is the main cause of attenuation at laser wavelength of interest for FSO communication at terrestrial altitude. Transmitted optical beams in free space are attenuated most by the fog and haze droplets mainly due to dominance of Mie scattering effect in the wavelength band of interest in FSO (0.5 μm – 2 μm). This makes fog and haze a keys contributor to optical power/irradiance attenuation. The attenuation levels are too high and obviously are not desirable [22].

The attenuation due to Mie scattering can reach values of hundreds of dB/km [19,23] (with the highest contribution arising from fog). The Mie scattering coefficient expressed as follows [10]:

$$
\beta\_s = \alpha\_s N\_s \mathbf{1} \text{ 1/ km} \mathbf{j} \tag{14}
$$

Where:

αa: is the Mie scattering cross-section [km2 ].

Na: is the number density of air particles [1 / km3 ].

An aerosol's concentration, composition and dimension distribution vary temporally and spatially varying, so it is difficult to predict attenuation by aerosols. Although their concen‐ tration is closely related to the optical visibility, there is no single particle dimension distribu‐ tion for a given visibility [24]. Due to the fact that the visibility is an easily obtainable parameter, either from airport or weather data, the scattering coefficient βa can be expressed according to visibility and wavelength by the following expression [11]:

Free Space Optical Communications — Theory and Practices http://dx.doi.org/10.5772/58884 179

$$
\beta\_x = \left(\frac{3.91}{V}\right) \left(\frac{0.55\,\mu}{\lambda}\right)^{\nu} \tag{15}
$$

Where:

αm

N m

Where:

n

λ

N

Where:

αa

Na

of incident beam (

: is the Rayleigh scattering cross-section [

λ-4

178 Contemporary Issues in Wireless Communications

: is the index of refraction.

*<IP_ADDRESS>. MIE (Aerosol) scattering*

: is the incident light wavelength [

: is the number density of air molecules [1 /

: is the volumetric density of the molecules [1 /

are too high and obviously are not desirable [22].

: is the Mie scattering cross-section [

: is the number density of air particles [1 /

either from airport or weather data, the scattering coefficient

visibility and wavelength by the following expression [11]:

km2 ].

> km3 ].

> > km

km3 ].

The result is that Rayleigh scattering is negligible in the infrared waveband because Rayleigh

Mie scattering occurs when the particle diameter is equal or larger than one-tenth the incident laser beam wavelength, see Table 4. Mie scattering is the main cause of attenuation at laser wavelength of interest for FSO communication at terrestrial altitude. Transmitted optical beams in free space are attenuated most by the fog and haze droplets mainly due to dominance

fog and haze a keys contributor to optical power/irradiance attenuation. The attenuation levels

The attenuation due to Mie scattering can reach values of hundreds of dB/km [19,23] (with the highest contribution arising from fog). The Mie scattering coefficient expressed as follows [10]:

> km3 ].

An aerosol's concentration, composition and dimension distribution vary temporally and spatially varying, so it is difficult to predict attenuation by aerosols. Although their concen‐ tration is closely related to the optical visibility, there is no single particle dimension distribu‐ tion for a given visibility [24]. Due to the fact that the visibility is an easily obtainable parameter,

2 (13)

μm – 2 μ

(14)

can be expressed according to

βa m). This makes

Rayleigh scattering cross section is inversely proportional to fourth power of the wavelength

) as the following relationship:

m].

scattering is primarily significant in the ultraviolet to visible wave range [10].

of Mie scattering effect in the wavelength band of interest in FSO (0.5

βa= αaNa 1 / km

> km2 ].

3N 2 λ4

αm= 8π3(n2 - 1)2 V : is the visibility (Visual Range) km.

λ: is the incident laser beam wavelength μm.

i: is the size distribution of the scattering particles which typically varies from 0.7 to 1.6 corresponding to visibility conditions from poor to excellent.

Where:

$$i = 1.6 \text{ for } V > 50 \text{ km.}$$

$$i = 1.3 \text{ for } 6 \text{ km} \le V \le 50 \text{ km.}$$

$$i = 0.585 \text{ } V^{1/3} \text{ for } V < 6 \text{ km.}$$

Since we are neglecting the absorption attenuation at wavelength of interest and Rayleigh scattering at terrestrial altitude and according to Eq. 8 and Eq. 11 then:

$$
\beta\_{\text{scat}} = \beta\_s \tag{16}
$$

The atmospheric attenuation τis given as:

$$\tau = \exp\left(\cdot \beta\_s L\right) \tag{17}$$

The atmospheric attenuation in dB, τcan be calculated as follows:

$$
\pi = 4.3429 \,\beta\_s L \,\text{[dB]} \tag{18}
$$

#### *<IP_ADDRESS>. Rain*

Rain is formed by water vapor contained in the atmosphere. It consists of water droplets whose form and number are variable in time and space. Their form depends on their size: they are considered as spheres until a radius of 1 mm and beyond that as oblate spheroids: flattened ellipsoids of revolution [11].

#### **Rainfall effects on FSO systems:**

Scattering due to rainfall is called non-selective scattering, this is because the radius of raindrops (100 – 1000 μm) is significantly larger than the wavelength of typical FSO systems. The laser is able to pass through the raindrop particle, with less scattering effect occurring. The haze particles are very small and stay longer in the atmosphere, but the rain particles are very large and stay shorter in the atmosphere. This is the primary reason that attenuation via rain is less than haze [24]. An interesting point to note is that RF wireless technologies that use frequencies above approximately 10 GHz are adversely impacted by rain and little impacted by fog. This is because of the closer match of RF wavelengths to the radius of raindrops, both being larger than the moisture droplets in fog [14]. The rain scattering coefficient can be calculated using Stroke Law [25]:

$$\mathcal{B}\_{\text{train } \text{scat}} = \text{ } \pi \text{a}^2 \, N\_\text{a} \mathcal{Q}\_{\text{scat}} \left( \frac{\text{a}}{\text{\AA}} \right) \tag{19}$$

Where:

*a*: is the radius of raindrop, (cm).

Na : is the rain drop distribution, (cm-3).

Qscat: is the scattering efficiency.

The raindrop distribution Nacan be calculated using equation following:

$$N\_g = \frac{R}{1.33 \text{(}\pi s^3\text{)} \, V\_s} \tag{20}$$

Where:

*R*: is the rainfall rate (cm/s),

*V*a: is the limit speed precipitation.

Limiting speed of raindrop [25] is also given as:

$$\mathcal{V}\_{\mathfrak{s}} = \frac{2\mathcal{A}^2 \rho \mathbf{g}}{9\eta} \tag{21}$$

Where:

ρ: is water density, (ρ =1 g / cm3 ).

g: is gravitational constant, g = 980 cm / sec 2 .

η: is viscosity of air, η = 1.8 \* 10 -4 g / cm.sec.

The rain attenuation can be calculated by using Beer's law as:

$$\tau = \exp\left(\cdot \beta\_{\text{rain } \text{scat}} L\right) \tag{22}$$

For more details about several weather conditions and the corresponding visibility at various wavelengths readers can refer to references [26,27].


**Functional Ceramic Coatings**

Editors

**Bozena Pietrzyk ˙ Sebastian Miszczak**

MDPI • Basel • Beijing • Wuhan • Barcelona • Belgrade • Manchester • Tokyo • Cluj • Tianjin

*Editors* Bozena Pietrzyk ˙ Lodz University of Technology Poland

Sebastian Miszczak Lodz University of Technology Poland

*Editorial Office* MDPI St. Alban-Anlage 66 4052 Basel, Switzerland

This is a reprint of articles from the Special Issue published online in the open access journal *Coatings* (ISSN 2079-6412) (available at: https://www.mdpi.com/journal/coatings/special issues/ ceram coat).

For citation purposes, cite each article independently as indicated on the article page online and as indicated below:

LastName, A.A.; LastName, B.B.; LastName, C.C. Article Title. *Journal Name* **Year**, *Volume Number*, Page Range.

**ISBN 978-3-0365-0732-3 (Hbk) ISBN 978-3-0365-0733-0 (PDF)**

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**Landscape Ecology Practices in Planning: Landscape Connectivity and Urban Networks**

Ebru Ersoy

[12] Habitat-III Turkey National Report [Internet]. December 2014. Available from http:// unhabitat.org/wp-content/uploads/2014/07/Turkey-national-report.pdf [accessed

[13] Dede, OM, Ayten, M. The role of spatial planning for sustainable tourism develop‐ ment: a theoretical model for Turkey. Tourism, 2012; 60(4): 431–445. UDC:

2015-12-10].

290 Sustainable Urbanization

338.484:502.131.1]:71(560).

Additional information is available at the end of the chapter

http://dx.doi.org/10.5772/62784

#### **Abstract**

The increasing need to conserve the nature and biodiversity and to maintain human well-being has motivated landscape planners and researchers to seek different planning approaches in urban environments. In this context, different approaches to planning urban networks have been developed to promote the sustainable use and functioning of landscapes, to conserve the nature and species, and increase its use and enjoyment by people [1, 2]. In principle, these approaches have been founded on the conserva‐ tion of natural areas/biodiversity and with a consensus on their benefits to nature, biodiversity and people [3–5]. However, they generally differ from each other with respect to their expected aims, and ecological and/or social functions [6]. Therefore, by examining different planning approaches to networks, this chapter clarifies what is meant by these concepts and approaches in the literature.

**Keywords:** landscape planning, landscape ecology, landscape connectivity, sustaina‐ ble landscapes, urban networks


**3.2 Congenital hemidysplasia with ichthyosiform erythroderma and limb defects syndrome**

Congenital hemidysplasia with ichthyosiform erythroderma and limb defects (CHILD) syndrome is a rare X-linked dominant disorder of cholesterol biosynthesis, with fewer than 100 cases discussed in the literature [58]. The earliest identification of the condition is thought to be in 1903 [59], through the proposal of the syndromic acronym in 1980 [60]. CHILD syndrome is nearly always male-lethal although perhaps two males with this syndrome have been identified, one with a 46, XY karyotype, postulated to have survived due to a postzygotic mutation [61]. The distinguishing hallmark of the condition is that of unilateral skin lesions with ipsilateral limb defects [60, 62, 63]. The characteristic yellow, scaly plaques are usually present at birth or emerge in the first few months of life and while there may be some resolution over time, they often remain for life [60]. These markings may follow the lines of Blaschko, but more commonly, there is a striking delineation at the midline with the lesions showing a unique lateralisation pattern [62]. This has been proposed to be due to interactions between X-inactivation and the organisation of left-right axis symmetry in the developing embryo [60]. The lateralisation of these lesions and their persistence is a distinguishing feature of CHILD syndrome compared to differentials such as CDPX2, a similar but distinct inborn error of cholesterol biosynthesis [64].

CHILD syndrome demonstrates complete limb aplasia, severe phocomelia or severe hypoplasia on the same side of the body as ichthyosiform lesions [60]. Infant radiography may show epiphyseal stippling such as that seen in CDPX2, as well as milder skeletal malformations such as scoliosis, hypo or hemi-plastic vertebrae, distal digit shortening, syndactyly or polydactyly [65]. Non-skeletal manifestations include alopecia, verruciform xanthoma, dystrophic nails and congenital malformations on the affected side that can involve the heart, kidneys and CNS [60, 65]. Intelligence may be normal or slightly reduced. Despite the severity of these symptoms, mild cases of CHILD syndrome with no skeletal and/or cutaneous involvement have been identified through molecular analysis [66].

Molecular investigation has identified various mutations in the *NSDHL* (NADH steroid dehydrogenase-like) gene as causative for CHILD syndrome [67]. *NSHDL* is located at Xq28 and encodes 3β-hydroxysteroid dehydrogenase, part of a three-part enzyme complex. This C4 demethylation complex acts on the sterol ring in the postsqualene pathway, converting 4,4-dimethylcholesta-8(9),24-dien-3β-ol to zymosterol and 4,4-diemthylcholesta-8(9)-en-3β-ol to cholesta-8(9)-en-3β-ol. Mutations are most often loss-of-function [68]. Cholesterol and sterol levels are normal and so a diagnosis requires clinical and molecular assessment. Various *NSDHL* mutations have been studied in the allelic 'bare patches' (*Bpa*) and 'striated' (S*tr*) murine models [69]. These have given insights into facets of CHILD syndrome and cholesterol synthesis disorders in general, for example, the roles of the maternal placenta [70] and Hedgehog signalling pathways [71] in disease presentation.

Treatment options for CHILD syndrome have generally focused on topical management of skin lesions with symptomatic remedies such as emollients or with pathogenesis-based therapies generally involving combinations of cholesterol and a cholesterol synthesis-inhibitor [72, 73], the latter with some efficacy.

#### **3.3 X-linked dominant chondrodysplasia punctata 2**

X-linked dominant chondrodysplasia punctata 2 (CDPX2), or Conradi-Hünermann-Happle syndrome, is estimated to have an incidence of 1/400,000 and, similarly to CHILD syndrome, is almost entirely male-lethal. The CDPX2 phenotype, like the other cholesterol biosynthesis disorders, is heavily based on the

**139**

*Human Cholesterol Biosynthesis Defects DOI: http://dx.doi.org/10.5772/intechopen.87150*

Cognition is usually normal [87].

located at Xp11.23 and encoding a Δ8

similarities with human CDPX2 [89].

**3.4 Lathosterolosis**

skeletal and cutaneous domains, and there can be significant variability even within family lines [74–76] with generational anticipation [74]. Severe manifestations can result in neonatal or infant death with considerable skeletal and internal abnormalities, while mild cases may be nearly asymptomatic. This range of phenotypic variability is likely due to the combination of somatic and/or gonadal mosaicism and X-inactivation patterns [76]. Occasional male patients are identified with CDPX2, usually due to somatic mosaicism [77, 78] with one case of 46,XXY [79]. Gonadal

Widespread epiphyseal stippling is seen on infant radiographs, often including not just the long bones but the trachea and vertebrae as well [81–83]. Additional skeletal stigmata include short stature and scoliosis (which can be congenital), clubfoot, joint contractures, and postaxial polydactyly [74, 77, 83]. Cutaneous manifestations include skin with patches of scaly hypo or hyper-pigmentation, which usually follows the lines of Blaschko. The initial skin scaling and erythroderma present at birth usually fades over the first few months of life, leaving follicular atrophoderma, pigmentation and alopecia, although ichthyosis can persist [84, 85]. The pattern and then resolution of skin scaling as well as its histological profile is a differentiating diagnostic feature for CDPX2 compared to CHILD syndrome. Diagnosis of CDPX2 in adulthood can be difficult due to the childhood resolution of the characteristic skin lesions and epiphyseal stippling [86]; however, a combination of cutaneous manifestations, asymmetric limb reduction and cataracts (found in 65% of patients) is a good suggestion of this condition for further investigation [86]. CDPX2 presents with characteristic facial features including frontal bossing, midface hypoplasia and flat nasal bridge [74, 81]. The condition is also associated with microphthalmia or microcornea, congenital heart disease, renal abnormalities including hypoplasia and hydronephrosis and sensorineural hearing loss [87].

CDPX2 is caused by mutations in the *EBP* (emopamil binding protein) gene [88, 89]

and are found throughout the entire length of the gene [74].

downstream of the C4-demethylation complex affected in CHILD syndrome and converts zymosterol and cholesta-8(9)-en-3β-ol to cholesta-7,24-dien-3β-ol and lathosterol, respectively. There is a phenotypic correlation with enzyme function with lethality of homozygous females and clinically affected heterozygous females; however, there is no clear genotype-phenotype correlation, presumably due to X-inactivation patterns [74, 76]. Surviving males with CDPX2 are almost always due to mosaic postzygotic mutations as a hemizygous male genotype is lethal *in utero*. CDPX2 mutations (including deletions, insertions, nonsense, missense and splice-site) of *EBP* have been identified as both *de novo* and inherited mutations

While there is no clear CDPX2 genotype-phenotype correlation, there is a distinct association between genotype and CDPX2 sterol profile [74], and plasma sterol assay is a highly specific indicator for an *EBP* mutation [83]. Plasma shows increased 8-dehydrocholesterol and 8(9)cholesterol levels, with the ratios compared to cholesterol increased 0.71–0.80% [74]. Plasma cholesterol is usually normal. Treatment and surveillance are symptomatic, and studies in these areas have been advanced by the 'tattered' (*Td*) mouse which shares both phenotypic and molecular

Lathosterolosis (OMIM 607330) results from impaired 3-hydroxysteroid-5-desaturase (SC5D) activity [90]. In the Kandutsch-Russel synthetic pathway, SC5D catalyses the conversion of lathosterol to 7-dehydrocholesterol (7DHC)

mosaicism is possible which is relevant for recurrence risk [80].

#### *Human Cholesterol Biosynthesis Defects DOI: http://dx.doi.org/10.5772/intechopen.87150*

*Apolipoproteins, Triglycerides and Cholesterol*

**defects syndrome**

**3.2 Congenital hemidysplasia with ichthyosiform erythroderma and limb**

involvement have been identified through molecular analysis [66].

and Hedgehog signalling pathways [71] in disease presentation.

**3.3 X-linked dominant chondrodysplasia punctata 2**

cholesterol synthesis-inhibitor [72, 73], the latter with some efficacy.

Molecular investigation has identified various mutations in the *NSDHL* (NADH steroid dehydrogenase-like) gene as causative for CHILD syndrome [67]. *NSHDL* is located at Xq28 and encodes 3β-hydroxysteroid dehydrogenase, part of a three-part enzyme complex. This C4 demethylation complex acts on the sterol ring in the postsqualene pathway, converting 4,4-dimethylcholesta-8(9),24-dien-3β-ol to zymosterol and 4,4-diemthylcholesta-8(9)-en-3β-ol to cholesta-8(9)-en-3β-ol. Mutations are most often loss-of-function [68]. Cholesterol and sterol levels are normal and so a diagnosis requires clinical and molecular assessment. Various *NSDHL* mutations have been studied in the allelic 'bare patches' (*Bpa*) and 'striated' (S*tr*) murine models [69]. These have given insights into facets of CHILD syndrome and cholesterol synthesis disorders in general, for example, the roles of the maternal placenta [70]

Treatment options for CHILD syndrome have generally focused on topical management of skin lesions with symptomatic remedies such as emollients or with pathogenesis-based therapies generally involving combinations of cholesterol and a

X-linked dominant chondrodysplasia punctata 2 (CDPX2), or Conradi-Hünermann-Happle syndrome, is estimated to have an incidence of 1/400,000 and, similarly to CHILD syndrome, is almost entirely male-lethal. The CDPX2 phenotype, like the other cholesterol biosynthesis disorders, is heavily based on the

Congenital hemidysplasia with ichthyosiform erythroderma and limb defects (CHILD) syndrome is a rare X-linked dominant disorder of cholesterol biosynthesis, with fewer than 100 cases discussed in the literature [58]. The earliest identification of the condition is thought to be in 1903 [59], through the proposal of the syndromic acronym in 1980 [60]. CHILD syndrome is nearly always male-lethal although perhaps two males with this syndrome have been identified, one with a 46, XY karyotype, postulated to have survived due to a postzygotic mutation [61]. The distinguishing hallmark of the condition is that of unilateral skin lesions with ipsilateral limb defects [60, 62, 63]. The characteristic yellow, scaly plaques are usually present at birth or emerge in the first few months of life and while there may be some resolution over time, they often remain for life [60]. These markings may follow the lines of Blaschko, but more commonly, there is a striking delineation at the midline with the lesions showing a unique lateralisation pattern [62]. This has been proposed to be due to interactions between X-inactivation and the organisation of left-right axis symmetry in the developing embryo [60]. The lateralisation of these lesions and their persistence is a distinguishing feature of CHILD syndrome compared to differentials such as CDPX2, a similar but distinct inborn error of cholesterol biosynthesis [64]. CHILD syndrome demonstrates complete limb aplasia, severe phocomelia or severe hypoplasia on the same side of the body as ichthyosiform lesions [60]. Infant radiography may show epiphyseal stippling such as that seen in CDPX2, as well as milder skeletal malformations such as scoliosis, hypo or hemi-plastic vertebrae, distal digit shortening, syndactyly or polydactyly [65]. Non-skeletal manifestations include alopecia, verruciform xanthoma, dystrophic nails and congenital malformations on the affected side that can involve the heart, kidneys and CNS [60, 65]. Intelligence may be normal or slightly reduced. Despite the severity of these symptoms, mild cases of CHILD syndrome with no skeletal and/or cutaneous

**138**

skeletal and cutaneous domains, and there can be significant variability even within family lines [74–76] with generational anticipation [74]. Severe manifestations can result in neonatal or infant death with considerable skeletal and internal abnormalities, while mild cases may be nearly asymptomatic. This range of phenotypic variability is likely due to the combination of somatic and/or gonadal mosaicism and X-inactivation patterns [76]. Occasional male patients are identified with CDPX2, usually due to somatic mosaicism [77, 78] with one case of 46,XXY [79]. Gonadal mosaicism is possible which is relevant for recurrence risk [80].

Widespread epiphyseal stippling is seen on infant radiographs, often including not just the long bones but the trachea and vertebrae as well [81–83]. Additional skeletal stigmata include short stature and scoliosis (which can be congenital), clubfoot, joint contractures, and postaxial polydactyly [74, 77, 83]. Cutaneous manifestations include skin with patches of scaly hypo or hyper-pigmentation, which usually follows the lines of Blaschko. The initial skin scaling and erythroderma present at birth usually fades over the first few months of life, leaving follicular atrophoderma, pigmentation and alopecia, although ichthyosis can persist [84, 85]. The pattern and then resolution of skin scaling as well as its histological profile is a differentiating diagnostic feature for CDPX2 compared to CHILD syndrome. Diagnosis of CDPX2 in adulthood can be difficult due to the childhood resolution of the characteristic skin lesions and epiphyseal stippling [86]; however, a combination of cutaneous manifestations, asymmetric limb reduction and cataracts (found in 65% of patients) is a good suggestion of this condition for further investigation [86]. CDPX2 presents with characteristic facial features including frontal bossing, midface hypoplasia and flat nasal bridge [74, 81]. The condition is also associated with microphthalmia or microcornea, congenital heart disease, renal abnormalities including hypoplasia and hydronephrosis and sensorineural hearing loss [87]. Cognition is usually normal [87].

CDPX2 is caused by mutations in the *EBP* (emopamil binding protein) gene [88, 89] located at Xp11.23 and encoding a Δ8 -Δ7 -sterol isomerase. This enzyme functions downstream of the C4-demethylation complex affected in CHILD syndrome and converts zymosterol and cholesta-8(9)-en-3β-ol to cholesta-7,24-dien-3β-ol and lathosterol, respectively. There is a phenotypic correlation with enzyme function with lethality of homozygous females and clinically affected heterozygous females; however, there is no clear genotype-phenotype correlation, presumably due to X-inactivation patterns [74, 76]. Surviving males with CDPX2 are almost always due to mosaic postzygotic mutations as a hemizygous male genotype is lethal *in utero*. CDPX2 mutations (including deletions, insertions, nonsense, missense and splice-site) of *EBP* have been identified as both *de novo* and inherited mutations and are found throughout the entire length of the gene [74].

While there is no clear CDPX2 genotype-phenotype correlation, there is a distinct association between genotype and CDPX2 sterol profile [74], and plasma sterol assay is a highly specific indicator for an *EBP* mutation [83]. Plasma shows increased 8-dehydrocholesterol and 8(9)cholesterol levels, with the ratios compared to cholesterol increased 0.71–0.80% [74]. Plasma cholesterol is usually normal. Treatment and surveillance are symptomatic, and studies in these areas have been advanced by the 'tattered' (*Td*) mouse which shares both phenotypic and molecular similarities with human CDPX2 [89].


**4. Conclusions**

An analytical survey revealed good practices and problems regarding design, construction, maintenance and management for the region of Western Greece, the region of Epirus in Greece and the region of Apulia in Italy. The summarised results that concern irrigation management for both agricultural and urban greenspaces irrigation systems were presented. The supervisors of irrigation systems welcomed this initiative. Good practices, problems and challenges were pointed out. The development of a practical surveying and auditing guide, approved by the relevant stakeholders, could be a very useful tool for planning relevant strategies and practical actions with an aim of continuous improvement of irrigation systems efficiency. The role of international irrigation stakeholders such as the European Irrigation Association could be crucial in this effort.

### **Supplementary Materials:** The following are available online at https://www.mdpi.com/article/10 .3390/ECWS-7-14186/s1.

**Funding:** The survey on which this work has been based on was co-financed by EU/ERDF (75%) and from national funds of Greece and Italy (25%) in the framework of the European Territorial Cooperation Programme (ETCP) GREECE-ITALY 2007–2013 (www.greece-italy.eu): IRMA project, subsidy contract no: I3.11.06.

**Institutional Review Board Statement:** Not applicable.

**Informed Consent Statement:** Not applicable.

**Data Availability Statement:** Full reports of the data presented in this study are available at: https: //www.irrigation-management.eu/tools/survey (accessed on 15 January 2022).

**Acknowledgments:** The author, who acted as project manager of the IRMA project, would like to express his gratitude to all the members of the project partners who worked on the survey and on the formation of the relevant project deliverables.

**Conflicts of Interest:** The author declares no conflict of interest.