(85990) 1999 JV6, Physical characteristics
1999 JV6 was discovered in May 1999 by the Lincoln Near-Earth Asteroid Research (LINEAR) program at the Lincoln Laboratory's Experimental Test Site near Socorro, New Mexico. Most properties of 1999 JV6 have been determined through photometry, spectroscopy, infrared radiometry, and radar imaging.


(85990) 1999 JV6, Physical characteristics
Binzel et al. (2001) have found that 1999 JV6 has a spectral class of an Xk-type asteroid. Thermal infrared observations using the WISE spacecraft by Mainzer et al. (2011) and the Spitzer Space Telescope by Mueller et al. (2011) give a diameter of 0.45 km (0.28 mi). Warner et al. (2014, 2015) suggest that 1999 JV6 has a highly elongated shape due to its large light curve amplitude of 0.9 magnitudes. Based on 1999 JV6's large brightness changes, they measured a rotation period of 6.54 hours.


(85990) 1999 JV6, Physical characteristics
In January 2015, radar imaging by the Arecibo Observatory and the Green Bank Observatory confirmed 1999 JV6's elongated shape and provided delay-Doppler images used to obtain a preliminary estimate of a 3D model for its shape. The radar data reveal an apparent concavity and suggest that 1999 JV6 is a contact binary.


(86039) 1999 NC43
(86039) 1999 NC43, is an asteroid on an eccentric orbit, classified as near-Earth object and potentially hazardous asteroid of the Apollo group, approximately 2 kilometers in diameter. This suspected tumbler and relatively slow rotator was discovered by LINEAR in 1999.


(86039) 1999 NC43, Discovery
The asteroid was discovered on 14 July 1999, by the Lincoln Near-Earth Asteroid Research (LINEAR) team at Lincoln Laboratory's Experimental Test Site, near Socorro, New Mexico, USA, at an apparent magnitude of 18, using a 1.0-meter reflector.


(86039) 1999 NC43, Discovery
Its first observation was made by the Catalina Sky Survey in June 1999, extending the asteroid's observation arc by one month prior to its official discovery observation.


(86039) 1999 NC43, Orbit and classification
1999 NC43 has a well-determined orbit with an uncertainty of 0. The body orbits the Sun at a distance of 0.7–2.8 AU once every 2 years and 4 months (852 days). Its orbit has an eccentricity of 0.58 and an inclination of 7° with respect to the ecliptic. Its Earth minimum orbit intersection distance is 0.0243 AU (3,640,000 km), which corresponds to 9.5 lunar distances. Its most notable close approach to Earth will be on 14 February 2173 at a distance of 0.03361 AU (5,028,000 km). The asteroid also makes close approaches to Venus and Mars.


(86039) 1999 NC43, Physical characteristics
The rare Q-type asteroid is one of only 20 characterized bodies of this spectral type in the SMASS taxonomic scheme.


(86039) 1999 NC43, Physical characteristics, Rotation period
Several rotational lightcurves were obtained from photometric observations by Czech astronomer Petr Pravec at Ondřejov Observatory and American astronomer Brian Warner at his private Palmer Divide Observatory, Colorado. Best rated results gave a rotation period of 34.49±0.18 hours with an exceptionally high brightness variation of 1.1 magnitude (U=n.a.). Pravec's alternative period of 122 hours was later not supported by Warner. However, there are still other periods possible due to sparse photometric data points. The asteroid is also suspected to be in a tumbling motion, which makes the determination of its period more complex. For an asteroid of its size, it is a relatively slow rotator.


(86039) 1999 NC43, Physical characteristics, Diameter and albedo
According to the survey carried out by the Japanese Akari satellite, the asteroid has a high albedo of 0.35 and a diameter of 1.43 kilometers. Observations by the Keck Observatory in the thermal infrared gave a refined albedo of 0.13–0.14 with a larger diameter of 2.22 kilometers.


(86039) 1999 NC43, Physical characteristics, Chelyabinsk meteor fragment
1999 NC43 is suspected to be related to the 20-meter Chelyabinsk meteor, which exploded as a bright fireball over Russia on 15 February 2013. Analysis showed similar orbits for both bodies and suggested that they were once part of the same object.


(86039) 1999 NC43, Numbering and naming
This minor planet was numbered by the Minor Planet Center on 30 August 2004. As of 2018, it has not been named.


(86047) 1999 OY3
(86047) 1999 OY3, also written as (86047) 1999 OY3, is a trans-Neptunian object that resides in the Kuiper belt beyond Pluto. It was discovered on July 18, 1999, at the Mauna Kea Observatory, Hawaii.


(86047) 1999 OY3, Haumea family
1999 OY3 is a candidate member of the Haumea family and probably has a very high albedo.


(86047) 1999 OY3, Haumea family
Of the known Haumea-family members, 2009 OY3 has the dimmest absolute magnitude (H) of the group at 6.8, suggesting that it is also the smallest member of the group.


(87269) 2000 OO67
(87269) 2000 OO67 (prov. designation: 2000 OO67) is a trans-Neptunian object, approximately 64 kilometers (40 miles) in diameter, on a highly eccentric orbit in the outermost region of the Solar System. It was discovered by astronomers at the Chilean Cerro Tololo Inter-American Observatory on 29 July 2000.


(87269) 2000 OO67, Description
At aphelion it is over 1,000 AU from the Sun and, with a perihelion of 21 AU, almost crosses the orbit of Uranus at closest approach. Astronomers with the Deep Ecliptic Survey classify it as a centaur rather than a trans-Neptunian object. 2000 OO67 came to perihelion in April 2005. Both 2000 OO67 and 2006 SQ372 take longer than Sedna to orbit the Sun using either heliocentric coordinates or barycentric coordinates.


(88710) 2001 SL9
(88710) 2001 SL9 is a sub-kilometer asteroid and binary system, classified as near-Earth object of Apollo group discovered by NEAT at Palomar Observatory on 18 September 2001. It measures approximately 960 meters in diameter, while its 2001-discovered minor-planet moon has an estimated diameter of 200 meters based on a secondary to primary mean-diameter ration of 0.28.


(88710) 2001 SL9, Near-Earth asteroid
Although 2001 SL9 is classified as a near-Earth object, it does not pose any threats. It has never, nor will it ever in the next century, come closer than 15,000,000 km (0.1 AU) from Earth or Venus. However, the asteroid would make a good target for a spacecraft flyby, as a flyby to 2001 SL9 would only require a delta-v of 5.4 km/s.


(88710) 2001 SL9, Moon
2001 SL9 has one minor-planet moon, S/2001 (88710) 1. It was discovered from lightcurve observations made by Czech astronomer Petr Pravec and collaborators. This moon is approximately 200 m (660 ft) in diameter. Its semi-major axis is 1.6 km (0.99 mi) and its orbital period is 16.4 hours.


(89830) 2002 CE
(89830) 2002 CE, provisional designation 2002 CE, is a stony asteroid, classified as near-Earth object and potentially hazardous asteroid of the Amor group, approximately 3.1 kilometers in diameter. It was discovered on 1 February 2002, by astronomers of the LINEAR program at Lincoln Laboratory's Experimental Test Site near Socorro, New Mexico, in the United States. This asteroid is one of the largest potentially hazardous asteroid known to exist.


(89830) 2002 CE, Orbit and classification
2002 CE is a member of the dynamical Amor group, which are Mars-crossing asteroids that approach the orbit of Earth from beyond, but do not cross it.


(89830) 2002 CE, Orbit and classification
It orbits the Sun at a distance of 1.0–3.1 AU once every 2 years and 12 months (1,094 days; semi-major axis of 2.08 AU). Its orbit has a high eccentricity of 0.51 and an inclination of 44° with respect to the ecliptic.


(89830) 2002 CE, Orbit and classification
The body's observation arc begins with a precovery from the Digitized Sky Survey taken at the Siding Spring Observatory, Australia, in May 1982, nearly 20 years prior to its official discovery observation at Socorro.


(89830) 2002 CE, Orbit and classification, Close approaches
With an absolute magnitude of 14.9, 2002 CE is one of the brightest and largest known potentially hazardous asteroid (see PHA-list). It has an Earth minimum orbital intersection distance of 0.0277 AU (4,140,000 km), which corresponds to 10.8 lunar distances.


(89830) 2002 CE, Physical characteristics
2002 CE has been characterized as a common, stony S-type asteroid by astronomers conducting spectroscopic observations using the New Technology Telescope at La Silla, Chile, and the 2.2-meter telescope of the Calar Alto Observatory in Spain.


(89830) 2002 CE, Physical characteristics, Rotation period
In October 2004, a rotational lightcurve of 2002 CE was obtained from photometric observations by Czech astronomer Petr Pravec at the Ondřejov Observatory. Lightcurve analysis gave a rotation period of 2.6149 hours with a low brightness amplitude of 0.09 magnitude (U=2-). Several longer periods are also possible.


(89830) 2002 CE, Physical characteristics, Diameter and albedo
According to the survey carried out by the NEOWISE mission of NASA's Wide-field Infrared Survey Explorer, 2002 CE measures 5.067 kilometers in diameter and its surface has a low albedo of 0.079. Conversely, the Collaborative Asteroid Lightcurve Link assumes a stony standard albedo of 0.20 and calculates a smaller diameter of 3.11 kilometers based on an absolute magnitude of 14.9.


(89830) 2002 CE, Numbering and naming
This minor planet was numbered by the Minor Planet Center on 30 August 2004. As of 2018, it has not been named.


(89958) 2002 LY45
(89958) 2002 LY45 is an asteroid, classified as near-Earth object of the Apollo group that is also a Mercury-crosser, Venus-crosser, and Mars-crosser. It was discovered by the LINEAR program on 14 June 2002.


(89959) 2002 NT7
(89959) 2002 NT7 (prov. designation: 2002 NT7) is a near-Earth object with a diameter of 1.4 kilometers and potentially hazardous asteroid of the Apollo group. It has a well determined orbit with an observation arc of 64 years including precovery images by Palomar Observatory dating back to 1954.


(89959) 2002 NT7
2002 NT7 became the first object observed by NASA's NEO program to be assigned a positive rating on both the Torino Scale and the Palermo Technical Impact Hazard Scale, for a small chance of an impact on 1 February 2019, although it has now been known for years that it would pass Earth at roughly 0.4078 AU (61,010,000 km; 37,910,000 mi) on 13 January 2019 with an uncertainty region of around ±108 km.


(89959) 2002 NT7, Discovery
It was discovered on 9 July 2002 by the Lincoln Near-Earth Asteroid Research team (LINEAR) at the U.S. Lincoln Laboratory Experimental Test Site near Socorro, New Mexico. At the time of discovery it only had a 6-day observation arc of 9–14 July which poorly constrained possible future positions of the asteroid.


(89959) 2002 NT7, Discovery
Despite inflammatory press reports, the object had a "low probability" of impact of approximately one in a million for 1 February 2019. On 22 July 2002, NEODyS posted a positive 0.18 Palermo Scale rating. Further observations of the object quickly lowered the probability. On 25 July 2002, the hazard rating on the Palermo scale was lowered to -0.25. However, the discovery of the object with a Palermo initial rating of 0.06 was a historical event for the NEO observation program.


(89959) 2002 NT7, Discovery
2002 NT7 was removed from the Sentry Risk Table on 1 August 2002, (23 days after discovery) so there is no risk of an impact by it in the next 100 years. On 13 January 2019, the asteroid safely passed 0.4078 AU (61,010,000 km; 37,910,000 mi) from Earth with a 3-sigma uncertainty region of about ±108 km. Between 1900 and 2195 the closest approach to Earth will occur on 15 January 2099 at a distance of roughly 0.3739 AU (55,930,000 km; 34,760,000 mi) with uncertainty region of about ±430 km.


(89959) 2002 NT7, Discovery
On 30 January 2020, the asteroid safely passed 0.02718 AU (4,066,000 km; 2,527,000 mi) from 2 Pallas.


(90075) 2002 VU94
(90075) 2002 VU94, provisional designation 2002 VU94, is an asteroid on an eccentric orbit, classified as near-Earth object and potentially hazardous asteroid of the Apollo group, approximately 2.5 kilometers in diameter. It was discovered on 13 November 2002, by astronomers of the Near-Earth Asteroid Tracking program at Palomar Observatory in California, United States. It is one of the largest potentially hazardous asteroids known.


(90075) 2002 VU94, Orbit and classification
2002 VU94 is a member of the dynamical Apollo group, which are Earth-crossing asteroids. Apollo asteroids are the largest subgroup of near-Earth objects. It orbits the Sun at a distance of 0.9–3.4 AU once every 3 years and 1 month (1,138 days; semi-major axis of 2.13 AU). Its orbit has an eccentricity of 0.58 and an inclination of 9° with respect to the ecliptic.


(90075) 2002 VU94, Orbit and classification
The body's observation arc begins with a precovery from the Digitized Sky Survey taken at the Palomar Observatory in October 1955, or 47 years prior to its official discovery observation.


(90075) 2002 VU94, Orbit and classification, Close approaches
With an absolute magnitude of 15.3, 2002 VU94 is one of the brightest and largest known potentially hazardous asteroid (see PHA-list). It has an Earth minimum orbital intersection distance of 0.0301 AU (4,500,000 km), which translates into 11.7 lunar distances. On 18 May 2092, the body will make its closest near-Earth encounter at a nominal distance of 0.095 AU (37 LD). The asteroid is also Mars-crosser, crossing the orbit of the Red Planet at 1.66 AU.


(90075) 2002 VU94, Physical characteristics, Rotation period
In 2014 and 2017, several rotational lightcurves of 2002 VU94 were obtained from photometric observations by American astronomer Brian Warner at the Palmer Divide Station (U82) in California. Lightcurve analysis gave a consolidated rotation period of 7.879 hours with a brightness amplitude between 0.31 and 0.64 magnitude (U=3-).


(90075) 2002 VU94, Physical characteristics, Rotation period
In 2017, Warner also modeled the photometric data and determined a sidereal period of 7.878512 hours, as well as a spin axis of (73.0°, −50.0°) in ecliptic coordinates (λ, β).


(90075) 2002 VU94, Physical characteristics, Diameter and albedo
According to the survey carried out by the NEOWISE mission of NASA's Wide-field Infrared Survey Explorer, 2002 VU94 measures 2.233 kilometers in diameter and its surface has an albedo of 0.294, while the Collaborative Asteroid Lightcurve Link assumes a standard albedo for stony asteroids of 0.20, and calculates a diameter of 2.59 kilometers based on an absolute magnitude of 15.3.


(90075) 2002 VU94, Numbering and naming
This minor planet was numbered by the Minor Planet Center on 30 August 2004. As of 2018, it has not been named.


(90568) 2004 GV9
(90568) 2004 GV9 is a trans-Neptunian object that was discovered on April 13, 2004 by NEAT. It has been listed as a cubewano by the Minor Planet Center.


(90568) 2004 GV9, Discovery
It was discovered on 13 April 2004 by NEAT. It has been observed forty-seven times, with precovery images back to 1954.


(90568) 2004 GV9, Size estimate
Brown estimates that is very likely a dwarf planet. A diameter of 680±34 km has been determined from combined observations of the Herschel and Spitzer space telescopes. Tancredi notes that light-curve-amplitude analysis shows only small deviations, suggesting that (90568) 2004 GV9 could be a spheroid with small albedo spots and hence a dwarf planet. However, its low albedo suggests it has never been resurfaced and thus is unlikely to have planetary geology.


(90568) 2004 GV9, Orbit
It has an orbital period of 273.88 years. Its maximum possible distance from the Sun (aphelion) is 45.62 AU, and its closest (perihelion) is 38.7 AU, and currently 39.7 AU from he sun. It has an inclination of 21.9718, and eccentricity of 0.082.


(91133) 1998 HK151
(91133) 1998 HK151, also written as (91133) 1998 HK151 is a resonant trans-Neptunian object from the Kuiper belt, located in the outermost region of the Solar System. It measures approximately 134 kilometers in diameter. It was discovered by astronomers at the Mauna Kea Observatory on 28 April 1998.


(91133) 1998 HK151, Description
1998 HK151 is classified as a plutino, a dynamical group named after Pluto. Members of this group stay in a 2:3 resonance with Neptune.


(91133) 1998 HK151, Description
1998 HK151 has the lowest, and thus bluest measured B-V color index of any TNO. On 24 May 2000, 1998 HK151 set a TNO record low B-V of 0.51. Reddening of the spectrum is caused by ultraviolet radiation and charged particles. Becoming bluer in the spectrum is caused by impact collisions exposing the interior of an object.


(91133) 1998 HK151, Description
Based on an absolute magnitude of 7.62, 1998 HK151, the Johnston's Archive estimates a diameter of 134 kilometers, assuming an albedo of 0.09.


(91205) 1998 US43
(91205) 1998 US43, provisional designation 1998 US43, is a resonant trans-Neptunian object of the plutino group, located in the Kuiper belt in the outermost region of the Solar System. The rather bluish body measures approximately 111 kilometers (69 miles) in diameter. It was discovered on 22 October 1998, by American astronomer Marc Buie at the Kitt Peak National Observatory in the United States. It is probably not a dwarf planet candidate.


(91205) 1998 US43, Classification and orbit
1998 US43 belongs to the plutino population, which are named after the group's largest member, Pluto. Plutinos are resonant trans-Neptunian objects in 2:3 resonance with Neptune, orbiting the Sun twice for every three orbits Neptune does.


(91205) 1998 US43, Classification and orbit
It orbits the Sun at a distance of 33.9–44.2 AU once every 244 years and 2 months (89,179 days; semi-major axis of 39.06 AU). Its orbit has an eccentricity of 0.13 and an inclination of 11° with respect to the ecliptic. The body's observation arc begins with its official discovery observation. Its orbit still has a fair amount of uncertainty.


(91205) 1998 US43, Numbering and naming
This minor planet was numbered by the Minor Planet Center on 28 October 2004 (M.P.C. 52912). As of 2018, it has not been named.


(91205) 1998 US43, Physical characteristics
Based on an absolute magnitude of 8.0 and an assumed albedo of 0.09, the Johnston's Archive estimates a diameter of 111 kilometers. The body's spectrum (BB–BR) suggests a somewhat bluish color. As of 2018, no rotational lightcurve of 1998 US43 has been obtained from photometric observations. 1998 US43 it an unlikely dwarf planet candidate due to its small size, estimated by Michael Brown to measure 154 kilometers with a low albedo of 0.04.


(95625) 2002 GX32
(95625) 2002 GX32, also written as (95625) 2002 GX32, is a trans-Neptunian object that resides in the Kuiper belt. It has a 3:7 resonance with Neptune. It was discovered on April 8, 2002 by Marc W. Buie, Amy B. Jordan, and James L. Elliot.


(95625) 2002 GX32
Assuming a generic TNO albedo of 0.09, it is about 153 km in diameter.


(95625) 2002 GX32, Resonance
Simulations by Emel'yanenko and Kiseleva in 2007 show that 2002 GX32 has a 99% probability of libration in a 3:7 resonance with Neptune.


(95625) 2002 GX32, Resonance
The Neptune 3:7 mean-motion resonance keeps it more than 11 AU from Neptune over a 14000-year period.


(95625) 2002 GX32, Resonance
It has been observed 21 times over 4 oppositions and has an orbit quality code of 3.


(9928) 1981 WE9
(9928) 1981 WE9, provisional designation 1981 WE9, is a stony Florian asteroid from the inner regions of the asteroid belt, approximately 3 kilometers in diameter. It was discovered on 16 November 1981, by astronomers at Perth Observatory in Bickley, Australia.


(9928) 1981 WE9, Orbit and classification
The stony S-type asteroid is a member of the Flora family, one of the largest groups of asteroids in the main-belt. It orbits the Sun at a distance of 1.8–2.6 AU once every 3 years and 4 months (1,206 days).


(9928) 1981 WE9, Orbit and classification
Its orbit has an eccentricity of 0.18 and an inclination of 3° with respect to the ecliptic. A first precovery was taken at Palomar in 1951, extending the body's observation arc by 30 years prior to its official discovery observation at Bickley.


(9928) 1981 WE9, Physical characteristics
In December 2014, astronomer Maurice Clark obtained a rotational lightcurve from photometric observations at Preston Gott Observatory. Lightcurve analysis gave an ambiguous rotation period of 18.3980 hours with a brightness variation of 0.41 magnitude, suggesting a non-spheroidal shape (U=2+). The alternative period solution is 9.14 hours with an amplitude of 0.32 magnitude. The results supersede a previously obtained period of 5.547 hours (U=2).


(9928) 1981 WE9, Physical characteristics, Diameter and albedo
According to the survey carried out by NASA's Wide-field Infrared Survey Explorer with its subsequent NEOWISE mission, the asteroid measures between 2.44 and 3.00 kilometers in diameter, and its surface has an albedo between 0.283 and 0.428. The Collaborative Asteroid Lightcurve Link assumes an intermediate albedo of 0.24 – derived from 8 Flora, the largest member and namesake of this asteroid family – and calculates a diameter of 3.11 kilometers with an absolute magnitude of 14.7.


(9928) 1981 WE9, Numbering and naming
This minor planet was numbered by the Minor Planet Center on 2 February 1999. As of 2018, it has not been named.


(9942) 1989 TM1
(9942) 1989 TM1, provisional designation 1989 TM1, is a background asteroid from the central region of the asteroid belt, approximately 4.5 kilometers (2.8 miles) in diameter. It was discovered on 8 October 1989, by Japanese astronomers Nobuhiro Kawasato and Tsutomu Hioki at the Okutama Observatory (877) in Japan. The asteroid has a tentative rotation period of 3.1 hours.


(9942) 1989 TM1, Orbit and classification
The assumed stony S-type is a non-family asteroid from the main belt's background population. It orbits the Sun in the central main-belt at a distance of 2.2–3.0 AU once every 4 years and 2 months (1,527 days; semi-major axis of 2.6 AU). Its orbit has an eccentricity of 0.17 and an inclination of 10° with respect to the ecliptic.


(9942) 1989 TM1, Orbit and classification
Its first observation was a precovery taken at the Palomar Observatory on 30 September 1989, extending the asteroid's observation arc by just 9 days prior to its official discovery observation.


(9942) 1989 TM1, Numbering and naming
This minor planet was numbered by the Minor Planet Center on 2 February 1999. As of 2018, it has not been named.


(9942) 1989 TM1, Physical characteristics, Diameter and albedo
The asteroid was predicted to cross the focal plane array of the Infrared Astronomical Satellite (IRAS). However, it was missed on each of its seven planned observation and was never detected. According to the "missed predictions file" of the supplemental IRAS minor planet survey (SIMPS), the body was expected to have a diameter of 13.5 kilometers and an absolute magnitude of 13.20.


(9942) 1989 TM1, Physical characteristics, Diameter and albedo
Based on an absolute magnitude of 13.99, and an assumed standard albedo for stony asteroids of 0.20, the Collaborative Asteroid Lightcurve Link calculated a much smaller diameter of 4.7 kilometers, which agrees with a diameter of 4.1 kilometers, found by NASA's Wide-field Infrared Survey Explorer with its subsequent NEOWISE mission.


(9942) 1989 TM1, Physical characteristics, Rotation period
In October 2010, a rotational lightcurve for this asteroid was obtained from photometric observations at the Palomar Transient Factory in California. It rendered a tentative rotation period of 3.0706±0.0004 hours with a brightness variation of 0.08 in magnitude (U=1).


(9948) 1990 QB2
(9948) 1990 QB2, provisional designation 1990 QB2, is a stony Nysian asteroid from the inner region of the asteroid belt, approximately 3.4 kilometers (2.1 miles) in diameter. It was discovered on 22 August 1990, by American astronomer Henry Holt at the Palomar Observatory in California. The likely elongated S-type asteroid has a rotation period of 3.53 hours. This asteroid has not been named.


(9948) 1990 QB2, Orbit and classification
1990 QB2 is member of the Nysa family (405), located in the Nysa–Polana complex. It is named after 44 Nysa and one of the largest families in the main belt.


(9948) 1990 QB2, Orbit and classification
The asteroid orbits the Sun in the inner asteroid belt at a distance of 1.9–2.9 AU once every 3 years and 8 months (1,344 days; semi-major axis of 2.38 AU). Its orbit has an eccentricity of 0.22 and an inclination of 2° with respect to the ecliptic. The asteroid was first observed as 1979 SJ6 at Crimea–Nauchnij in September 1979. The body's observation arc begins at Palomar with its official discovery observation in 1990.


(9948) 1990 QB2, Physical characteristics
1990 QB2 has been characterized as a common, stony S-type asteroid by Pan-STARRS' survey and in the SDSS-based taxonomy.


(9948) 1990 QB2, Physical characteristics, Rotation period
In November 2005, a first rotational lightcurve of 1990 QB2 was obtained from photometric observations by Australian amateur astronomer David Higgins. Lightcurve analysis gave a well-defined rotation period of 3.5257 hours with a high brightness variation of 0.77 magnitude (U=3). In January 2014, observations in the R-band at the Palomar Transient Factory in California gave two concurring periods of 3.523 and 3.53 hours with an amplitude of 0.60 magnitude (U=2/2). A high brightness amplitude typically indicates that the body has a non-spherical shape


(9948) 1990 QB2, Physical characteristics, Diameter and albedo
According to the survey carried out by the NEOWISE mission of NASA's Wide-field Infrared Survey Explorer, 1990 QB2 measures 3.345 kilometers in diameter and its surface has an albedo of 0.250. The Collaborative Asteroid Lightcurve Link adopts Petr Pravec's revised WISE-result, that is, an albedo of 0.2232 and a diameter of 3.351 kilometers based on an absolute magnitude of 14.62.


(9948) 1990 QB2, Naming
This minor planet was numbered on 2 February 1999 (M.P.C. 33659). As of 2018, it has not been named.


(99907) 1989 VA
(99907) 1989 VA is a very eccentric, stony asteroid and near-Earth object, approximately 1 kilometer in diameter. It was discovered on 2 November 1989, by American astronomer couple Carolyn and Eugene Shoemaker and Canadian astronomer David Levy at the Palomar Observatory on Mount Palomar, California.


(99907) 1989 VA, Orbit and classification
It is a member of the Aten asteroid, a subgroup of near-Earth objects that are located in the zone of influence of Venus. It has frequent, relatively close encounters with the Earth, as its minimum orbit intersection distance (MOID) is 0.16 AU or about 23 million kilometers. It was the eighth Aten asteroid discovered. Since then the number of Atens has grown to about one thousand known bodies.


(99907) 1989 VA, Orbit and classification
This asteroid orbits the Sun with a short orbital period at a distance of 0.3–1.2 AU once every 227 days. The body rotates every two and a half hours around its axis and has a notably high albedo of about 0.40. Its orbit is tilted by 29 degrees to the plane of the ecliptic. With an exceptionally high eccentricity of 0.59, it was the most eccentric Aten asteroid known at the time of discovery, more eccentric than previously discovered Aten, 3753 Cruithne. Since then, more eccentric Atens – such as (162004) 1991 VE, with an eccentricity of 0.665 – have been discovered. Due to this elongated orbit, the Aten asteroid and near-Earth asteroid also classifies as Earth-crosser, Venus-crosser and Mercury-grazer.


(99907) 1989 VA, Orbit and classification
1989 VA was the first asteroid discovered with such a small semi-major axis (0.728 AU, about the same as Venus), breaking 2100 Ra-Shalom's distance record (0.832 AU), which had held for over a decade. It remained the asteroid with the smallest known semi-major axis for five years until the discovery of 1994 GL (0.683 AU), which was the first asteroid discovered closer to the Sun than Venus.


(99907) 1989 VA, Orbit and classification
Being so close to Venus, it is also the first asteroid discovered within Venus' zone of influence. This means that it is close enough to Venus for the planet to capture 1989 VA into a co-orbital relationship. Though it is not a Venus co-orbital at the moment, it may become one in the future and may have been one in the past. Currently, the only known Venus co-orbitals are 2001 CK32, 2002 VE68 and 2012 XE133 (as of 18 March 2013). Of the seven known objects in Venus' zone of influence, 1989 VA is the largest at about 1,400 metres. All of these objects, like 1989 VA, have eccentric orbits that cross Mercury's and Earth's orbits as well.


(99907) 1989 VA, Orbit and classification
The combination of a small semi-major axis and high eccentricity made 1989 VA the first Aten asteroid discovered to get closer to the Sun (0.295 AU) than Mercury ever does. 2340 Hathor (the second Aten discovered, in 1976) had the smallest perihelion (0.464 AU) earlier, which was about the same distance as Mercury's aphelion (0.467 AU). It was not until (66063) 1998 RO1 (0.277 AU) was discovered that an Aten asteroid with a lower perihelion was found.


(99907) 1989 VA, Orbit and classification
1989 VA's eccentric orbit takes it out past the Earth, where it has encounters of about 0.15 to 0.20 AU about every 3 to 5 years around October–November. It was discovered during its 1989 encounter and was about 0.17 AU away at the time. Further observations were made in October 2002 and during the most recent close encounter in November 2007.


(99907) 1989 VA, Physical characteristics
In the SMASS taxonomy, 1989 VA is characterized as a Sq-subtype that fall into the broader class of stony S-type asteroids.


(99907) 1989 VA, Numbering and naming
This minor planet was numbered by the Minor Planet Center on 22 June 2005. As of 2018, it has not been named.


(9992) 1997 TG19
(9992) 1997 TG19 is a stony asteroid and eccentric Mars-crosser, approximately 4 kilometers in diameter. It was discovered on 8 October 1997, by Japanese astronomers Tetsuo Kagawa and Takeshi Urata at Gekko Observatory near Shizuoka, Japan.


(9992) 1997 TG19, Orbit and classification
The stony S-type asteroid orbits the Sun at a distance of 1.5–2.8 AU once every 3 years and 2 months (1,169 days). Its orbit has an eccentricity of 0.29 and an inclination of 3° with respect to the ecliptic. The first used observation was made at the Cerro El Roble Station in 1974, extending the asteroid's observation arc by 23 prior to its discovery.


(9992) 1997 TG19, Physical characteristics, Lightcurves
Between 2006 and 2013, three rotational lightcurves for this asteroid were obtained from photometric observations made at the  Hunters Hill Observatory, Australia, the Ondřejov Observatory, Czech Republic, and the U.S. Palomar Transient Factory, California. They gave a well-defined, concurring rotation period of 5.7402±0.0005 hours (best result) with a brightness amplitude of 0.42, 0.40 and 0.27 in magnitude, respectively (U=3/3/2).


(9992) 1997 TG19, Physical characteristics, Diameter and albedo
According to the survey carried out by the Japanese Akari satellite, the asteroid's surface has an albedo of 0.13 and a diameter of 4.75 kilometers. The Collaborative Asteroid Lightcurve Link assumes a standard albedo for stony asteroids of 0.20 and calculates a diameter of 3.1 kilometers, as the higher the body's albedo (reflectivity), the shorter its diameter, at a constant absolute magnitude (brightness).


(9992) 1997 TG19, Numbering and naming
This minor planet was numbered by the Minor Planet Center on 2 February 1999. As of 2018, it has not been named.


(A Ballad of) A Peaceful Man
(A Ballad of) A Peaceful Man is Gravy Train's second — and probably their most praised — album, released in late 1971. Unlike their heavier debut, this album sports some lovely string arrangements, provided by Nick Harrison.


(A Ballad of) A Peaceful Man
A unique feature of the album is that it splits the heavy tracks from the lighter tracks: all the ballads are on side 1, while all the rockers are on side 2.


(A Little Touch Of) Baroque in Winter
(A Little Touch of) Baroque in Winter is a 1995 Christmas EP by Takako Minekawa.


(A) Senile Animal
(A) Senile Animal is the 15th album (not including split albums) by American rock band Melvins, released on October 10, 2006 on Ipecac Recordings. After bassist Kevin Rutmanis' departure the two remaining members of the Melvins joined forces with Big Business, a duo consisting of Jared Warren on bass and Coady Willis on drums.


(A) Senile Animal, Background
On the line-up change, frontman Buzz Osborne spoke to Kerrang! in 2008, stating:


(A) Senile Animal, Background
When it became obvious we wouldn't be working with Kevin again, me and Dale were very discouraged fellows – I was bummed out for 18 months! We didn't know what we were going to do, but we knew we were going to do something. We'd played with Big Business and Jared [Warren]'s name had been batted around when we were thinking of bass players but I thought instead of just getting him, why don't we just get both those guys?


(A) Senile Animal, Background
We thought about two drummers a long time ago and messed around a little bit but [getting Coady Willis, Big Business' drummer] was the best decision we could have made. I'm not afraid of making changes and everything's worked out perfectly for everybody including Kevin. This record is one of my favourites and I think we're just scratching the surface of what we can do with these guys.


(A) Senile Animal, Background
A music video for "The Talking Horse" was made and shown in 2007.


(A) Senile Animal, Background
The song "A History of Bad Men" appears in the film I Know Who Killed Me and in the TV show True Detective.


(A) Senile Animal, Musical style
(A) Senile Animal features Melvins' signature sludge and stoner metal sound. AllMusic critic Greg Prato noted: "Although they started out primarily as a punk band that slowed down the riffs, the Melvins have also always mixed in prog rock-like bits, such as the tricky rhythms of 'Blood Witch' and the King Crimson/Tool-ish 'The Hawk.' The album also contains some of the group's most straightforward compositions in some time, including the metallic/new wave-ish ditty 'A History of Drunks.'"


(A) Senile Animal, Critical reception
AllMusic's Greg Prato wrote: "The transfusion of new blood has made one of rock's gnarliest beats even -- gnarlier!". Drowned in Sound's Grant Purdum stated: "In lieu of live albums and collaborations aplenty, A Senile Animal couldn't have snarled to life at a better time."


(A) Senile Animal, Vinyl edition
The vinyl edition was released as a 4-LP box set from Hydra Head Records. Each LP featured music on one side and an etching on the other. This was limited to 300 copies in a variety of colors and designs.


(Ah, the Apple Trees) When the World Was Young
"(Ah, the Apple Trees) When the World Was Young" is a popular song composed by Philippe-Gérard, with lyrics by Angèle Vannier. The English lyrics were written by Johnny Mercer. The original French title was "Le Chevalier de Paris". Apart from a reference to apples, the English lyrics only have minor commonalities with the original French words.


(Ah, the Apple Trees) When the World Was Young
English lyrics were originally written by Carl Sigman, but these were rejected by the music publisher, Mickey Goldsen. Sigman suggested Mercer, and Mercer wrote the English lyrics (three verses and three choruses) in three days.


(Ah, the Apple Trees) When the World Was Young
The song is from the perspective of an aging Parisian "boulevardier"/"coquette", as they review their life.


(Ain't Nobody Loves You) Like I Do
"(Ain't Nobody Loves You) Like I Do" is a 1987 single by American singer La Toya Jackson. The song is taken from her fifth album, La Toya. It is one of only four songs by Jackson to have an accompanying music video. The song features a bridge sung by Mike Stock. The single was released in 1987 throughout Europe, excluding the United Kingdom. Despite being produced by the European trio Stock Aitken Waterman, who were big hit-producers at the time, the single failed to chart. The B-side of the single, "(Tell Me) She Means Nothing To You At All", was released as its own single in France. The 12" singles include a longer version of the song.


(Ain't Nobody Loves You) Like I Do, Background
However, the single did fairly well on the German DJ charts. It debuted at No. 17 and stayed on the charts for several months. She also performed the song on the German television show Die Verflixte Sieben (with Rudi Carrell). The music video for the single was given little airplay and was never released on video or DVD. It didn't surface on the internet until March 2007. The Miami News described the number as "so unlike anything Stock Aitken and Waterman have produced that it seems a mistake to see their names on the credits. ' Like I Do' is funky, gritty and doesn't repeat every other verse 25 times."


(Ain't Nobody Loves You) Like I Do, Music video
A music video was filmed and released to promote the single. The clip is similar to Jackson's 1983 music video "Heart Don't Lie" in its colourful, cartoon-like cinematography and dance routines. The video can be found on YouTube and on various Jackson fan Web sites.


(Almost) Straight Outta Compton
"(Almost) Straight Outta Compton" is a headline from a 2016 article published by the MailOnline, the website of the British tabloid newspaper the Daily Mail. The headline has been criticised and described as being an example of racist press commentary towards the American former  actress Meghan, Duchess of Sussex (née Markle), prior to marrying the British Prince Harry.


(Almost) Straight Outta Compton, Origin
The November 2016 MailOnline article is about the inferred family background of American actress Meghan Markle (born 1981) and her upbringing in the Los Angeles district of Crenshaw with her mother, Doria Ragland. It was published after Markle began dating Prince Harry. The full headline is "Harry's girl is (almost) straight outta Compton: Gang-scarred home of her mother revealed – so will he be dropping by for tea?". It was also published on 2 November 2016 in a byline given to Ruth Styles "in Los Angeles for Dailymail.com".


(Almost) Straight Outta Compton, Origin
Crenshaw is portrayed in the article as having a high crime rate with the first paragraph stating that "Plagued by crime and riddled with street gangs, the troubled Los Angeles neighborhood that Doria Ragland, 60, calls home couldn't be more different to London's leafy Kensington. But social worker Ragland might now find herself welcoming a royal guest to downtrodden Crenshaw after Prince Harry was revealed to be dating her daughter – Suits actress Meghan Markle".


(Almost) Straight Outta Compton, Origin
The headline references the 1988 song "Straight Outta Compton", the debut record by the American gangsta rap hip hop group N.W.A. The city of Compton in southern Los Angeles County, California, was historically associated with gang violence. Compton is located 14 miles from Crenshaw, the area profiled in the article. A separate article by the British tabloid the Daily Star had a headline querying whether Harry would "marry into gangster royalty? ".


(Almost) Straight Outta Compton, Origin
Markle grew up in the 1980s and 1990s. She became engaged to Prince Harry in 2017. Upon their marriage in 2018, she became the Duchess of Sussex. Their son, Archie Mountbatten-Windsor, was born in 2019. The following year, the couple stepped down as senior members of the royal family, moving to Canada and then to the Duchess's native Southern California.


(Almost) Straight Outta Compton, Origin
In reaction to the March 2021 Oprah with Meghan and Harry television interview with Oprah Winfrey, Finlay Greig wrote in the Edinburgh Evening News that the headline insinuates that Meghan comes from a "life of crime", despite being brought up in a middle class area, which had suffered significant damage from both the 1992 Los Angeles riots and the 1994 Northridge earthquake, but was able to rebound in the late 2000s with the help of redevelopment and gentrification. The 2016 "(Almost) Straight Outta Compton" article also captioned a picture: "Prince Harry's new girl, Meghan Markle, grew up in this house in Crenshaw, Los Angeles, a troubled area that had 47 crimes in the past week – including murder."


(Almost) Straight Outta Compton, Reaction
The tone of this and other articles prompted Prince Harry's Communications Secretary to issue a statement that deplored the "racist" and "sexist" commentary and coverage received by Meghan. The statement described Meghan as having been "...subject to a wave of abuse and harassment. Some of this has been very public — the smear on the front page of a national newspaper; the racial undertones of comment pieces; and the outright sexism and racism of social media trolls and web article comments". The statement described Harry as worried about Meghan's safety and concluded that he had asked for the statement "to be issued in the hopes that those in the press who have been driving this story can pause and reflect before any further damage is done".


(Almost) Straight Outta Compton, Reaction
The Los Angeles Times clarified that the area "described by the British press as Crenshaw" was in reality the "more upscale" area of Baldwin Hills. Writing for BBC News in September 2017, Regan Morris wrote that "When one newspaper dubbed Markle '(Almost) Straight Outta Compton' last year, there was an outcry" and that "If you read the British tabloid press you would think the actress grew up in LA's notorious gang culture and was lucky to escape a life of crime".


(Almost) Straight Outta Compton, Reaction
In a January 2020 opinion piece for The New York Times, published in the wake of 'Megxit', the writer and broadcaster Afua Hirsch wrote that "From the very first headline about her being '(almost) straight outta Compton' and having 'exotic' DNA, the racist treatment of Meghan has been impossible to ignore".


(Almost) Straight Outta Compton, Reaction
The headline was highlighted in the reaction to Meghan and Harry's interview with Oprah Winfrey in March 2021. Hanna Ziady wrote for CNN that "The first round of headlines back in 2016 played on harmful stereotypes and helped set the tone for how parts of the UK media, and especially its tabloid newspapers, would treat this newcomer to the royal family who stood out in one very obvious way: her race".


(Almost) Straight Outta Compton, Reaction
Activist and lawyer Shola Mos-Shogbamimu wrote for The Guardian that she "[could not] believe that we are still having this debate about whether the way that Meghan has been treated is racist. It is misogynoir, pure and simple. Look at the media coverage of her. The Daily Mail said that she was "(almost) straight outta Compton".... That tells you what kind of society we live in". The headline was raised in an interview by Victoria Derbyshire with Ian Murray, the head of the Society of Editors. Derbyshire asked Murray if the headline was bigoted or racist, Murray replied that it was "disputed" as to whether the headline was offensive and said that it was "not acceptable" to describe sections of the British press as "bigoted". Murray described the article as a "rags to riches" story.


(Almost) Straight Outta Compton, Reaction
Murray has since stepped down from the Society of Editors, after releasing a statement headlined "UK media not bigoted: SoE responds to Sussexes' claims of racism" denying racism and bigotry in the UK press. The statement received an immediate backlash in the form of an open letter signed by over 250 "journalists of colour from the Guardian, Metro, the New York Times, the BBC and others", calling the initial statement "laughable" proof of "an institution and an industry in denial".


(Always Be My) Sunshine
"(Always Be My) Sunshine" is a hip hop song by American rapper Jay-Z with guest vocals from fellow femcee Foxy Brown and R&B singer-songwriter Babyface who performs the song's chorus. It serves as the first single from his second album In My Lifetime, Vol. 1 (1997). The track features production by Daven "Prestige" Vanderpool. Vanderpool samples MC Lyte's "Cha Cha Cha", Alexander O'Neal's "Sunshine", Kraftwerk's "The Man-Machine" and The Fearless Four's "Rockin' It" for the track's beat. In addition, George Fonenette plays keyboards on this song.


(Always Be My) Sunshine
The song's lyrics helped indicate Jay-Z's change from his Mafioso rap style to a more commercial "shiny suit" style. Steve Juon of RapReviews.com supports the song claiming that it is a less gangsta version of The Notorious B.I.G. 's "Me & My Bitch", a well-received track. Jay-Z cites this song as "what killed the album."


(Always Be My) Sunshine, Music video
The music video was directed by Hype Williams. Jay-Z is featured in the video rapping in a room resembling a Rubik's Cube & having a carnival theme to it with Foxy Brown rapping alongside of him. Jay-Z & co-founder of Roc-A-Fella, Damon Dash later regretted doing the video citing that the video wasn't their style.


(And Now the Waltz) C'est La Vie
"(And Now the Waltz) C'est La Vie" is a song by the British rock band Slade, released in 1982 as the lead single from the band's eleventh studio album The Amazing Kamikaze Syndrome. It was also included on its 1984 American counterpart Keep Your Hands Off My Power Supply. The song was written by lead vocalist Noddy Holder and bassist Jim Lea, and produced by Lea. It reached No. 50 in the UK, remaining in the charts for seven weeks.


(And Now the Waltz) C'est La Vie, Background
Slade started recording their second studio album for RCA in 1982, and in November that year, the album's first single, "(And Now the Waltz) C'est La Vie", was released. Attempting to appeal to the Christmas market, it reached No. 50 in the UK, but fared better in Poland, reaching No. 2 there in January 1983, while also reaching No. 29 on Radio Luxembourg's chart. As the song was not the big UK hit that both the band and RCA hoped for, the new album The Amazing Kamikaze Syndrome would not be released until December 1983.


(And Now the Waltz) C'est La Vie, Background
At the beginning of the year, RCA told the band that the album lacked potential chart hits and in the effort to amend that, the label hired producer John Punter to work on two new tracks "My Oh My" and "Run Runaway", both of which would go on to become big hits in 1983-84.


(And Now the Waltz) C'est La Vie, Background
"(And Now the Waltz) C'est La Vie" was described by Holder as a "sentimental love song". In a 1983 interview with Sounds, Lea said of the song: "We thought it was a ballad but when Dave Lee Travis played it, he said "That's Slade and now for a ballad" and put Lionel Ritchie on and then we realised ours wasn't a ballad at all. It came over like four idiots trying to tear their way out of the speakers." Holder also told Sounds in 1983: "It looked as if it was going to be quite a big hit but unfortunately it didn't get much above #50 in the charts."


(And Now the Waltz) C'est La Vie, Background
In 2005, Holder appeared on his regular TV-reviewing slot on the BBC Radio 2 show The Radcliffe and Maconie Show. Asked to choose a track from the band's new compilation album The Very Best of Slade, Holder chose "(And Now the Waltz) C'est La Vie". He felt the track, although not one of Slade's best-known singles, showed off his voice really well.


(And Now the Waltz) C'est La Vie, Release
"(And Now the Waltz) C'est La Vie" was released on 7" vinyl by RCA Records in the UK, Ireland, Australia, Germany and the Netherlands. The B-side, "Merry Xmas Everybody (Live & Kickin')", was exclusive to the single and would later appear on the band's 1985 studio/compilation album Crackers: The Christmas Party Album. On the single, it was credited to "Slade & The Assorted Nutters Choir".


(And Now the Waltz) C'est La Vie, Promotion
No music video was filmed to promote the single. In the UK, the band performed the song on the ITV children's music show Razzmatazz. In December, Slade embarked on a UK tour, which promoted the single and the newly-released Slade on Stage album.


(And Now the Waltz) C'est La Vie, Critical reception
Upon release, Malcolm Dome of Kerrang! described the song as an "excellent taster" of the band's new studio album. In a review of The Amazing Kamikaze Syndrome, Kerrang! said the song "tends to disappear into the clouds of its own long-winded ambition." Sounds said: "The "Sailing"-style scarves in the air of "My Oh My" is surpassed by the even more anthemic "C'est La Vie"". In a retrospective review, Joe Geesin of the Get Ready to Rock! felt the song was a strange choice for a single.


(And The) Pictures in the Sky
"(And The) Pictures in the Sky" is a song by the British band, Medicine Head. It was written by band member, John Fiddler.


(And The) Pictures in the Sky
The first hit single for Medicine Head, it was released in 1971 and entered the UK Singles Chart in June, reaching number 22 in July.


(Are You) The One That I've Been Waiting For
"(Are You) The One That I've Been Waiting For?" is the second single from the album The Boatman's Call by Nick Cave and the Bad Seeds. The single, released on May 19, 1997, was pressed on 7" and 12" vinyl, as well as a standard CD single, though the song failed to chart anywhere except the U.K., where it only made it to #67. A promotional music video for the song was also recorded.


(Are You) The One That I've Been Waiting For, Background and history
The song, like many on The Boatman's Call, seems to reflect on Nick Cave's personal relationships and spiritual yearnings at the time of writing. This song in particular is widely speculated to either be a love song or directed at either the mother of Cave's son Luke, Viviane Carneiro, or PJ Harvey, with whom Cave had a brief relationship prior to the album's recording and release.


(Are You) The One That I've Been Waiting For, Background and history
A line from the song that states, "there's a man who spoke wonders / I've never met him / he said, 'he who seeks finds and who knocks will be let in'", which is an indirect quotation of Matthew 7:8 from The Bible.


(Are You) The One That I've Been Waiting For, Music video
Before the single's release, a promotional music video for the song was recorded. The video features the band performing the song in a small church hall.


(Are You) The One That I've Been Waiting For, Cover versions
A version in Swedish, (Är du) den som jag har väntat på? appears on album Vid Grinden by Georga.


(At Your Best) You Are Love
"(At Your Best) You Are Love" is a song by The Isley Brothers, originally a radio hit in 1976. It was originally dedicated to their mother.


(At Your Best) You Are Love, Aaliyah version
Eighteen years later, the song was covered by American singer Aaliyah for her debut studio album Age Ain't Nothing but a Number. Released as the album's second single, it peaked at number six on the US Billboard Hot 100 and number two on the R&B singles chart, it also peaked at number 27 on the UK Singles Chart. The song was certified gold single by RIAA on October 25, 1994.


(At Your Best) You Are Love, Aaliyah version
In 2010 Canadian rapper Drake sampled Aaliyah's version of the song in his song "Unforgettable" in his debut album Thank Me Later; four years later singer Tamar Braxton sampled this song for her single "Let Me Know" featuring Future. In 2017, Sevyn Streeter used an interpolation of the song for her hit, "Before I Do", the lead single from her album Girl Disrupted.


(At Your Best) You Are Love, Aaliyah version, Critical reception
Damien Scott from Complex felt that the song was a nice departure from the hip hop and new jack swing inspired songs that comprised a large portion of Aaliyah's debut album. He also mentioned that it "showed a young women [sic] on the cusp of adulthood". Music writer James Masterton wrote in his weekly UK chart commentary, "Her second hit is in essence a beauty, a sparse but haunting rendition of an old Isley Brothers track, first written and recorded before she was even born." Alan Jones from Music Week rated it three out of five, adding that "this pretty Isley Brothers ballad is played on traditional instruments, and is sung by the striking young R Kelly protege in intimate and breathily pure style."


(At Your Best) You Are Love, Aaliyah version, Remix
The song became a hit based on remix versions Aaliyah cut with R. Kelly featured on the song chanting "this is for the steppers" and earlier saying, "1-2, check up, baby, lemme know what's up" before Aaliyah began singing.


(At Your Best) You Are Love, Aaliyah version, Music video
The accompanying music video for "(At Your Best) You Are Love" was directed by Millicent Shelton. It was shot back to back with R. Kelly's "Summer Bunnies" and were both released in fall 1994. The video is for the remix not the original and R. Kelly, who produced the songs, is in the video. It was published on YouTube in October 2009. As of September 2021, the video has amassed over 13 million views.


(At Your Best) You Are Love, Other versions
In the Philippines, it was covered by two artists: MYMP on their album Versions and Nina from her love songs live album Nina Live!. In 2010, Drake made a song with Young Jeezy called "Unforgettable" using the same beat. Swedish artist El Perro Del Mar covered the song in 2009 as a special Record Store Day release as well. Tamar Braxton sampled the song in her single with Future, "Let Me Know".


(At Your Best) You Are Love, Other versions
In 2015, Frank Ocean released a cover on his Tumblr account as a tribute to Aaliyah, one day after what would have been her 36th birthday. A slightly different version was also included on his visual album Endless.


(At Your Best) You Are Love, Other versions
In 2021, English singer Sinéad Harnett covered the song with a new music video to tribute to Aaliyah's version of the song.


(A→B) Life
[ A→B] Life is the debut album by American rock band mewithoutYou. It was released on Tooth & Nail Records on June 18, 2002. The songs "Bullet to Binary" and "Gentlemen" were featured on a split album with Norma Jean.


(A→B) Life, Track listing
"The Cure for Pain" contains an acoustic rendition of "I Never Said That I Was Brave" as a hidden track. The vocal in this song is performed by guitarist Michael Weiss.


(B, N) pair
In mathematics, a (B, N) pair is a structure on groups of Lie type that allows one to give uniform proofs of many results, instead of giving a large number of case-by-case proofs. Roughly speaking, it shows that all such groups are similar to the general linear group over a field. They were introduced by the mathematician Jacques Tits, and are also sometimes known as Tits systems.


(B, N) pair, Definition
A (B, N) pair is a pair of subgroups B and N of a group G such that the following axioms hold:


(B, N) pair, Definition
The idea of this definition is that B is an analogue of the upper triangular matrices of the general linear group GLn(K), H is an analogue of the diagonal matrices, and N is an analogue of the normalizer of H.


(B, N) pair, Definition
The subgroup B is sometimes called the Borel subgroup, H is sometimes called the Cartan subgroup, and W is called the Weyl group. The pair (W,S) is a Coxeter system.


(B, N) pair, Properties of groups with a BN pair
The map taking w to BwB is an isomorphism from the set of elements of W to the set of double cosets of B; this is the Bruhat decomposition G = BWB.


(B, N) pair, Properties of groups with a BN pair
If T is a subset of S then let W(T) be the subgroup of W generated by T: we define and G(T) = BW(T)B to be the standard parabolic subgroup for T.  The subgroups of G containing conjugates of B are the parabolic subgroups; conjugates of B are called Borel subgroups (or minimal parabolic subgroups). These are precisely the standard parabolic subgroups.


(B, N) pair, Applications
BN-pairs can be used to prove that many groups of Lie type are simple modulo their centers. More precisely, if G has a BN-pair such that B is a solvable group, the intersection of all conjugates of B is trivial, and the set of generators of W cannot be decomposed into two non-empty commuting sets, then G is simple whenever it is a perfect group. In practice all of these conditions except for G being perfect are easy to check. Checking that G is perfect needs some slightly messy calculations (and in fact there are a few small groups of Lie type which are not perfect). But showing that a group is perfect is usually far easier than showing it is simple.


(Baby I've Got You) On My Mind
"(Baby I've Got You) On My Mind" (also known simply as "On My Mind") is the first single from the fifth studio album by Powderfinger. It was released as a single on 16 June 2003 and reached No. 9 on the Australian Singles Chart, the band's third-highest-charting single to date. In January 2018, as part of Triple M's "Ozzest 100", the 'most Australian' songs of all time, "(Baby I've Got You) On My Mind" was ranked No. 97.


(Baby I've Got You) On My Mind, Background
After two albums of Powderfinger releasing singles that were either acoustic anthems (such as "My Happiness") or ballads ("The Metre" or "The Day You Come"), Powderfinger decided to release a heavy rock song as their new album, Vulture Street's lead single.


(Baby I've Got You) On My Mind, Background
In accordance with this, the band's publicity was geared towards a more rock oriented slant, with magazine covers and articles indicating that they were "returning to rock," alluding to the rock albums Parables for Wooden Ears and the highly successful Double Allergic, however some criticism was that the band's "rock" sound was different from previous releases, indicating that they were trying to be more like AC/DC than previously. Although the single for the song was released under the title of "On My Mind," the album cover has the song's title printed as "(Baby I've Got You) On My Mind." It is alleged that Bernard Fanning implicitly wrote the lyrics as a tribute to former radio and television personality John Burgess.


(Baby I've Got You) On My Mind, Background
The album's artwork is of a painted ship entitled "On My Mind". The design style of the cover and case is in the same style as the other singles from Vulture Street, however all are very different from the album itself, except for the use of highly contrasting colours.


(Baby I've Got You) On My Mind, Music video
The music video for "On My Mind" was directed by Scott Walton. The video, like the group's previous single "Like a Dog", was filmed in black and white.


(Baby I've Got You) On My Mind, Cover versions
In 2005, on the third season of Australian Idol, the song was performed by contestant Tarni Stephans on the Top 12 Australiana theme night. Stephans was eliminated the next night on the verdict show, however she recorded a cover of this song on that season's cast album.


(Baby I've Got You) On My Mind, Cover versions
In 2007, "(Baby I've Got You) On My Mind" was performed again on the fifth season of Australian Idol by Natalie Gauci who eventually won the series. Gauci recorded a cover of the song for her Winner's Journey album.


(Baby Tell Me) Can You Dance
"(Baby Tell Me) Can You Dance" is the lead single by Shanice from her debut album, Discovery.


(Baby Tell Me) Can You Dance, Music video
The music video takes place in a city at night. The video features Shanice and many other dancers showing off their dance moves.


(Baby) You Don't Have to Tell Me
"(Baby) You Don't Have to Tell Me" (often written "You Don't Have to Tell Me") is a song by New York songwriter Pete Antell (formerly of the American pop group The Chants) and first recorded by singer Bobby Coleman. The obscure song was later recorded and released by the American pop group the Walker Brothers as their sixth single in 1966. The accompaniment was directed by Reg Guest.


(Baby) You Don't Have to Tell Me
"(Baby) You Don't Have to Tell Me" was a modest hit for the Walker Brothers, spending eight weeks on the UK Singles Chart and peaking at number 13. In comparison to their previous three singles, each of which made the top three, the single was a disappointment and marked the beginning of the group's popular decline. Despite the single's underperformance, Portrait, the group's second album, was released at the same time was much more popular, reaching number three on the UK Albums Chart.


(Baby) You Don't Have to Tell Me
In most territories the single was backed with "My Love Is Growing", a song co-written by Scott Walker's former musical partner John Stewart. In the US the single was backed by a Scott Walker-John Franz original, "Young Man Cried".


(Back to the) Heartbreak Kid
"(Back to The) Heartbreak Kid" is a song written by Van Stephenson and Tim DuBois, and recorded by American country music group Restless Heart. It was released in October 1985 as the third single from the album Restless Heart. The song reached number 7 on the Billboard Hot Country Singles & Tracks chart.


(Back to the) Heartbreak Kid, Music video
A video for the song, depicting the band performing, was shot at Vasquez Rocks.


(Back to the) Heartbreak Kid, Other versions
The song previously appeared on Kathy Mattea's 1984 self-titled album, and was the B-side to her 1984 single "You've Got a Soft Place to Fall".


(Barbara) Hazel Guggenheim King-Farlow McKinley
(Barbara) Hazel Guggenheim King-Farlow McKinley (1903–1995) was an American painter, art collector, and art benefactor.


(Barbara) Hazel Guggenheim King-Farlow McKinley, Personal life
McKinley, was born Barbara Hazel Guggenheim, on April 30, 1903 in New York City to Benjamin and Fleurette (Seligman) Guggenheim. The marriage united two wealthy German-Jewish families, although their wealth did not protect them from anti-Semitism  Born into the well-known Guggenheim family she grew up in New York, alongside her sisters Benita Guggenheim and Marguerite "Peggy" Guggenheim who would become the influential gallery proprietor, art collector, museum founder, and midwife to the Abstract Expressionism art movement. Her father Benjamin gave up much of his financial interest in the family's mining business to start his own business in Paris.


(Barbara) Hazel Guggenheim King-Farlow McKinley, Personal life
With his business failing and amid much womanizing, in 1912 he set out to return to the United States in time for Hazel's ninth birthday, unfortunately, on the ill-fated Titanic. HIs body was never recovered. He died at the age of 46 years old. Hazel inherited $450,000, a far cry from the millions she might have inherited if her father had not left the Guggenheim businesses. She later inherited additional money upon the deaths of her mother and older sister, Benita, who died in childbirth. The loss of her father haunted her the rest of her life and in 1969 she recorded "In Memoriam, Titanic Lifeboat Blues."


(Barbara) Hazel Guggenheim King-Farlow McKinley, Personal life
In 1921, aged 18, after studying at Washington Square College, New York University and as one of the season's debutantes, McKinley married banker Sigmund Marshall Kempner. Divorcing Kempner a year later, she then moved to Paris where she married journalist Milton S. Waldman in 1923 with whom she had two sons, Terence and Benjamin. Tragically, during a later visit back to New York in 1928 both her young sons, Terrence aged four and half years and Benjamin aged 14 months, fell to their deaths in a 13-story fall from the rooftop of the Surrey apartment block.


(Barbara) Hazel Guggenheim King-Farlow McKinley, Personal life
There is much speculation about the details of this tragic incident, however, this event was largely kept hidden from public by the influential Guggenheim family. McKinley was visiting her cousin who lived in the penthouse apartment. The fall was believed to be accidental, although McKinley "was unable to tell a coherent story of what happened." Discrepancies in witness accounts caused the police investigation to be re-opened. The second police investigation came to the same conclusion, that the deaths were accidental. However, within their social circle it was widely believed that she pushed the boys off the roof due to her deteriorating  marriage. Two years after the death of their sons, Hazel and Milton divorced. The mystery surrounding her sons' deaths left her permanently stigmatized.


(Barbara) Hazel Guggenheim King-Farlow McKinley, Personal life
In 1931 Hazel married the Englishman Denys King-Farlow. They settled in Sussex, UK, and had two children, John King-Farlow, PhD, who became a noted philosopher and poet and Barbara Benita King-Farlow Jacobs Shukman, who became an artist in her own right. After their divorce the children lived with McKinley in the United States before a custody fight was won by their father, Denys King-Farlow, who moved them back to England. While the marriage to King-Farlow did not last, Hazel continued to use his last name when signing her paintings.


(Barbara) Hazel Guggenheim King-Farlow McKinley, Personal life
Hazel next married Charles (Chuck) Everett McKinley, Jr, an artist and USAAF pilot, on August 13, 1940, with whom she painted alongside. Chuck McKinley died in 1942 in a plane crash in a farmer's field in Missouri due to stormy weather while moving planes for military training purposes. As an artist, Hazel used the last name McKinley on all of her subsequent work until the end of her life. Hazel went on to marry at least three more times. On October 1, 1943, McKinley married Army Corporal Larry Leonard in Denver, a former actor and athletic instructor.


(Barbara) Hazel Guggenheim King-Farlow McKinley, Personal life
The wedding was announced in newspapers across the country and much was made of the fact that the bride was 40 and the groom 28 years old and that the bride was marrying down in rank, with previous husbands being a major and a lieutenant. Her next marriage was recorded by a Certificate of Marriage in the Commonwealth of Virginia where the then Hazel G. McKinley, age 49, married F. Keith Cole, age 28, listed as a T.V. projectionist on July 7, 1952. In later newspaper accounts she was listed as Mrs. Hazel Hayes, but further details of this marriage are unknown.


(Barbara) Hazel Guggenheim King-Farlow McKinley, Personal life
McKinley moved back to Europe for approximately 10 years, then returned to the United States in 1969 and lived in New Orleans until her death in 1995. Upon her death, her only living son, John King-Farlow, wrote a poem in his mother's honor, entitled "Eulogy For My Mother (Hazel Guggenheim McKinley, Artist)."


(Barbara) Hazel Guggenheim King-Farlow McKinley, Personal life
Hazel was less well-known than her more famous, and infamous, older sister Peggy Guggenheim, a self-described "art addict," gallery owner, museum founder, early supporter of Jackson Pollock, and midwife to the Abstract Expressionist art movement in New York City. The sisters had a lot in common. They endured an unhappy childhood with an often absent, womanizing, but beloved father, who died an early and tragic death. Their mother was anxious, over-bearing, and had a habit of repeating phrases twice. They were often left in the care of strict nannies and nurses and were educated only to be wives and mothers.


(Barbara) Hazel Guggenheim King-Farlow McKinley, Personal life
Both escaped the insular, repressive, and intermarrying German-Jewish aristocracy (detailed in the book, "Our Crowd)  in New York City to live bohemian, art-centered lives, often abroad in Europe. Both underwent rhinoplasty, although Peggy unsuccessfully. Both were criticized as often absent and poor mothers  Both had quiet breathy voices with a vague British accent, apparently taught at the finishing school, the Jacobi School, they both attended in New York City. Both demonstrated sexual agency with robust sexual appetites. One of Peggy's biographer's noted that the two sisters had an informal, tongue-in-cheek bet of which one could have sex with a thousand men first.


(Barbara) Hazel Guggenheim King-Farlow McKinley, Personal life
Despite their similarities, the sisters had an often contentious and competitive relationship. Peggy reported her first memory as being Hazel's birth and the jealousy it aroused. Peggy considered herself the ugly duckling of the family and was envious of her more attractive sisters. Peggy was reportedly embarrassed by Hazel, steering her friends away from her. For her part, Hazel felt superior to Peggy, as Peggy was a mere collector of art in comparison to Hazel's being a maker of art.


(Barbara) Hazel Guggenheim King-Farlow McKinley, Personal life
Hazel died on June 15, 1995 and her two remaining children scattered her ashes on the Mississippi River. A short obituary was published in numerous newspapers across the country that noted she was a member of the illustrious New York Guggenheim family, that she was determined to make a name for herself as an artist, that her art works were shown in museums in the United States and Europe, and were in the collections of such celebrities as Greer Garson, Benny Goodman, and Jason Robards, and that she had died of cancer at the age of 92.


(Barbara) Hazel Guggenheim King-Farlow McKinley, Painting and Collecting career
Hazel McKinley began painting as a teenager and was a prolific artist throughout her life. When she fled New York for Paris at age 19 she studied at the Sorbonne and became part of 1920's bohemian Paris, where she was able to be taught by key modernist artists of the time. Her primary mediums were ink, water color, tempera, and crayon.


(Barbara) Hazel Guggenheim King-Farlow McKinley, Painting and Collecting career
Whilst living in the south of England with Denys King-Farlow in the 1930s Hazel was influenced by a group of avante-garde artists, and had her first solo exhibition in London in April 1937 at the Coolings Gallery. She received instruction from artists Rowland Suddaby, Raymond Coxon, and Edna Ginesi, becoming associated with the London Group and the Euston Road School. She painted primarily in watercolor. Her work included still-life, portraits, townscapes and landscapes. Although her first work was done in a "slightly plain palette," her later work in the 1930s brightened, sometimes falling within the realm of fauvism. "Under the influence of the Surrealists, Hazel's paintings after the 1930's became freer, though her work was far more whimsical and humorous than many artists more closely associated with the movement"


(Barbara) Hazel Guggenheim King-Farlow McKinley, Painting and Collecting career
In 1939 Hazel fled Europe due to the impending war and returned to the US, living mostly in California. She took brief art lessons from her sister Peggy's one-time husband Max Ernst and much later attended several long summer schools taught by muralist and renowned teacher Xavier Gonzalez.


(Barbara) Hazel Guggenheim King-Farlow McKinley, Painting and Collecting career
In her life in the United States and abroad, Hazel met many prominent artists of the Paris, London, and New York art scenes. She told this story about Jackson Pollock, one of her sister's Peggy's art proteges, "Peggy once left Pollack with me at the Chelsea Hotel, saying she could not take him to lunch with her. Pollock was so drunk, he vomited all over the carpet. . . Years later, the manager asked if I didn't have a Pollock to sell. I told him to cut himself a piece of the carpet."


(Barbara) Hazel Guggenheim King-Farlow McKinley, Painting and Collecting career
She continued to paint and ran a small gallery of her own in the late 1950s and early 1960s in West Cornwall, Connecticut. A newspaper advertisement for the gallery read:  Hazel McKinley Gallery, Gifts, Antiques, Modern Ceramics, Paintings. Covered Bridge Shopping Center, West Cornwall, Conn. Open Daily Except Sunday. One show at her gallery featured the works of British and Irish painters including Rowland Suddaby, Frank Beteson, Tom Nisbett, and Patrick Swift. Hazel had two of her own works also shown in the same exhibit, a watercolor painted at Positano, Italy and one painted at the Tuileries, Paris. Another featured work was a surrealistic water color portrait of Hazel by London artist Mervyn Peake.


(Barbara) Hazel Guggenheim King-Farlow McKinley, Painting and Collecting career
Hazel exhibited her work both in Europe and the United States throughout her long career, mostly at smaller and less prestigious venues. An incomplete listing of her exhibits and museum acquisitions of her work include:  Berkshire Museum, the Galerie Raymond Duncan in Paris, Stendahl Galleries, the Jake Zeitlin Gallery, the Montgomery Museum of Fine Art, the Artists' Own Gallery in London, the Manchester City Art Gallery, and Santa Fe Art Museum. As the case with many artists, and with the added burden of being such an unconventional woman and a Guggenheim heiress, her work was both admired and dismissed by critics.


(Barbara) Hazel Guggenheim King-Farlow McKinley, Painting and Collecting career
McKinley's work was only once included in a show by her sister Peggy Guggenheim, most likely due to the difficult relationship between them. In 1943 Hazel was selected to exhibit one of her paintings in Peggy's infamous show '31 Women' in her New York gallery Art of This Century. The exhibition was radical at the time for being one of the first all-woman exhibitions, as well as showing only abstract or Surrealist works. In 1998 after her death, one of her paintings was exhibited in Peggy Guggenheim's Venice home/museum the Palazzo Venier dei Leioni.


(Barbara) Hazel Guggenheim King-Farlow McKinley, Painting and Collecting career
Returning to Europe in the 1960's to live for a decade, Hazel was mentioned in a Walter Winchell column as she gathered American theater people to help Italian flood survivors and also donated paintings for the effort while living in Rome. In her later life she settled in New Orleans where she continued painting, exhibiting, and even studying art into her eighties at Newcomb College, New Orleans. Towards the end of her life while confined to bed, her last works were colored pen drawings and sketches.


(Barbara) Hazel Guggenheim King-Farlow McKinley, Painting and Collecting career
Like her sister Peggy, Hazel collected major contemporary artworks and she very generously donated these works to public institutions. For example, she donated over 15 works to Wakefield Art Gallery, UK, in the 1930s, and in 1938 Hazel presented the painting Cossacks (Cosaques) by Wassily Kandinsky to the Tate galleries, which would become an important work within the Tate collection. She also donated to the Tate works by artists Edna Ginesi and Raymond Coxon. She donated many paintings, some her own, to museums across the UK,  including the municipal collections of several English cities including Wakefield, Manchester, and Leeds.


(Believed You Were) Lucky
"(Believed You Were) Lucky" is a song by American band 'Til Tuesday, which was released in 1988 as the lead single from their third and final studio album Everything's Different Now. The song was written by Aimee Mann (music, lyrics) and Jules Shear (music), and produced by Rhett Davies. "(Believed You Were) Lucky" peaked at No. 95 on the US Billboard Hot 100.


(Believed You Were) Lucky, Background
"(Believed You Were) Lucky" was one of a number of songs on Everything's Different Now which was inspired by Mann and Shear's failed relationship. Mann told Steve Morse of The Boston Globe in 1988, "It was a really amazing relationship. I thought it was very healthy to stay together, but Jules just couldn't make up his mind."


(Believed You Were) Lucky, Music video
The song's music video was directed by Peter Wallach and produced by Michael Faerman and Wallach. In a 2018 interview with Stereogum, Mann criticized the video for being "super dumb". She added, "It was supposed to look like the Twilight Zone opening. I think that was the concept."


(Believed You Were) Lucky, Critical reception
On its release, Billboard described the song as a "spirited pop number" which is "delivered with conviction" and "shouldn't be overlooked". Cash Box listed the single as one of their "feature picks" during October 1988. They felt the song "fits into the quasi-sixties bag" and noted the "tight vocal harmonies".


(Believed You Were) Lucky, Critical reception
During February 1989, Music & Media selected the song as their "Single of the Week" and wrote, "This is well produced, atmospheric folk/rock complete with attractive, intriguing melodies supported by a semi-acoustic sound." They also noted Mann's "fanciful vocals" as being "one of the most attractive things about this band".


(Believed You Were) Lucky, Critical reception
In a retrospective review of Everything's Different Now, Alex Henderson of AllMusic picked the song as one of the album's "introspective and personal gems" which shows Mann "coming from the heart".


(Benzene)chromium tricarbonyl
(Benzene)chromium tricarbonyl is an organometallic compound with the formula Cr(C6H6)(CO)3. This yellow crystalline  solid compound is soluble in common nonpolar organic solvents. The molecule adopts a geometry known as “piano stool” because of the planar arrangement of the aryl group and the presence of three CO ligands as "legs" on the chromium-bond axis.


(Benzene)chromium tricarbonyl, Preparation
(Benzene)tricarbonylchromium was first reported in 1957 by Fischer and Öfele, who prepared the compound by the carbonylation of bis(benzene)chromium. They obtained mainly chromium carbonyl (Cr(CO)6) and traces of Cr(C6H6)(CO)3. The synthesis was optimized through the reaction of Cr(CO)6 and Cr(C6H6)2. For commercial purposes, a reaction of Cr(CO)6 and benzene is used:


(Benzene)chromium tricarbonyl, Applications
Complexes of the type (Arene)Cr(CO)3 have been well investigated as reagents in organic synthesis.. The aromatic ring of (benzene)tricarbonylchromium is substantially more electrophilic than benzene itself, allowing it to undergo nucleophilic addition reactions.


(Benzene)chromium tricarbonyl, Applications
It is also more acidic, undergoing lithiation upon treatment with n-butyllithium. The resulting organolithium compound can then be used as a nucleophile in various reactions, for example, with trimethylsilyl chloride:


(Benzene)chromium tricarbonyl, Applications
(Benzene)tricarbonylchromium is a useful catalyst for the hydrogenation of 1,3-dienes. The product alkene results from 1,4-addition of hydrogen. The complex does not hydrogenate isolated double bonds.


(Benzene)ruthenium dichloride dimer
(Benzene)ruthenium dichloride dimer is the organoruthenium compound with the formula [(C6H6)RuCl2]2. This red-coloured, diamagnetic solid is a reagent in organometallic chemistry and homogeneous catalysis.


(Benzene)ruthenium dichloride dimer, Preparation, structure, and reactions
The dimer is prepared by the reaction of cyclohexadienes with hydrated ruthenium trichloride. As verified by X-ray crystallography, each Ru center is coordinated to three chloride ligands and a η6-benzene. The complex can be viewed as an edge-shared bioctahedral structure.


(Benzene)ruthenium dichloride dimer, Preparation, structure, and reactions
(Benzene)ruthenium dichloride dimer reacts with Lewis bases to give monometallic adducts:


(Benzylideneacetone)iron tricarbonyl
(Benzylideneacetone)iron tricarbonyl is the organoiron compound with the formula (C6H5CH=CHC(O)CH3)Fe(CO)3. It is a reagent for transferring the Fe(CO)3 unit. This red-colored compound is commonly abbreviated (bda)Fe(CO)3.


(Benzylideneacetone)iron tricarbonyl, Structure and bonding
(bda)Fe(CO)3 is an example of a comnplex of an η2-ketone. It is a piano stool complex. The compound is characterized by IR bands at 2065, 2005, and 1985 cm−1 (cyclohexane solution), the three bands being indicative of the low symmetry of the complex, which is chiral.


(Benzylideneacetone)iron tricarbonyl, Synthesis, reactions, related reagents
It is prepared by the reaction of Fe2(CO)9 with benzylideneacetone.


(Benzylideneacetone)iron tricarbonyl, Synthesis, reactions, related reagents
(bda)Fe(CO)3 reacts with Lewis bases to give adducts without displacement of the bda.


(Benzylideneacetone)iron tricarbonyl, Synthesis, reactions, related reagents
Another popular source of Fe(CO)3 is Fe2(CO)9. Alternatively, Fe(CO)3(cyclooctene)2 is highly reactive, the trade-off being that it is thermally sensitive. Imine derivatives of cinnamaldehyde, e.g. C6H5CH=CHC(H)=NC6H5, also form conveniently reactive Fe(CO)3 adducts, which have been shown to be superior in some ways to (bda)Fe(CO)3.


(Bis(trifluoroacetoxy)iodo)benzene
(Bis(trifluoroacetoxy)iodo)benzene, C6H5I(OCOCF3)2, is a hypervalent iodine compound used as a reagent in organic chemistry. It can be used to carry out the Hofmann rearrangement under acidic conditions.


(Bis(trifluoroacetoxy)iodo)benzene, Preparation
The syntheses of all aryl hypervalent iodine compounds start from iodobenzene. The compound can be prepared by reaction of iodobenzene with a mixture of trifluoroperacetic acid and trifluoroacetic acid in a method analogous to the synthesis of (diacetoxyiodo)benzene:


(Bis(trifluoroacetoxy)iodo)benzene, Preparation
It can also be prepared by dissolving diacetoxyiodobenzene (a commercially-available compound) with heating in trifluoroacetic acid:


(Bis(trifluoroacetoxy)iodo)benzene, Uses
It also brings around the conversion of a hydrazone to a diazo compound, for example in the diazo-thioketone coupling. It also converts thioacetals to their parent carbonyl compounds.


(Bis(trifluoroacetoxy)iodo)benzene, Uses, Hofmann rearrangement
The Hofmann rearrangement is a decarbonylation reaction whereby an amide is converted to an amine by way of an isocyanate intermediate. It is usually carried out under strongly basic conditions.


(Bis(trifluoroacetoxy)iodo)benzene, Uses, Hofmann rearrangement
The reaction can also be carried out under mildly acidic conditions by way of the same intermediate using a hypervalent iodine compound in aqueous solution. An example published in Organic Syntheses is the conversion of cyclobutanecarboxamide, easily synthesized from cyclobutylcarboxylic acid, to cyclobutylamine. The primary amine is initially present as its trifluoroacetate salt, which can be converted to the hydrochloride salt to facilitate product purification.


(Blooper) Bunny
(Blooper) Bunny is a Merrie Melodies animated short film directed by Greg Ford and Terry Lennon, with music by George Daugherty, produced in 1991 by Warner Bros. Animation. Featuring the voice talents of Jeff Bergman and Gordon Hunt, the short is a parody of some of the specials produced for Bugs Bunny's 50th anniversary the previous year. The short never received its intended theatrical release and was shelved for six years. It was finally given a television premiere on June 13, 1997, after Cartoon Network discovered the film sitting unseen in the vaults. It is featured on the Looney Tunes Golden Collection: Volume 1 as of 2003.


(Blooper) Bunny, Synopsis
The cartoon opens with a short special, celebrating Bugs Bunny's 51st and a Half Anniversary Spectacular. Once that is finished, what happened earlier that day is shown, with a backstage look at the characters (featuring 3D rendering of the scenery). Bugs is shown rehearsing his one line in the special. Elmer Fudd is shown trying to use minoxidil to regrow his hair. Daffy Duck and Yosemite Sam are shown only begrudgingly going along with the act, complaining non-stop until called to their places by the director. They attempt a performance, which results in a series of animated "bloopers".


(Blooper) Bunny, Synopsis, Featured bloopers
Bugs Bunny begins to dance, but the music is slightly out of tune and the record skips. He then dryly looks at the camera and says, "Ehh...What's up, Doc?" in an annoyed and sarcastic voice. The director and producers laugh as Bugs walks off stage. He then peeks back in to say "Monotonous, isn't it? ", which gets the director and producers laughing again and right when the screen fades to black, the record scratches.


(Blooper) Bunny, Synopsis, Featured bloopers
Bugs halts the production midway, explaining he noticed a loose floorboard which could pose a hazard to his "esteemed fellow thespians". He suggests cutting the action back and readjusting the camera.


(Blooper) Bunny, Synopsis, Featured bloopers
The cane is thrown before Bugs is ready to catch it, Bugs later mumbles angrily.


(Blooper) Bunny, Synopsis, Featured bloopers
While waiting for the cane to be thrown, it becomes clear that Daffy Duck has refused to throw it to Bugs. According to Daffy, his contract states that he is not supposed to throw canes to "stupid rabbits" and that Bugs' people spoke to his, resulting in the director agreeing to have someone else throw it in Daffy's place.


(Blooper) Bunny, Synopsis, Featured bloopers
Daffy enters the stage at the exact time that Bugs does, saying that he thought it was a vast improvement as he walks away, only to bump his head on the boom mike.


(Blooper) Bunny, Synopsis, Featured bloopers
Daffy does not appear when he is supposed to. Offstage, Daffy is heard telling Bugs, the director and the producers to wait, followed by the sound of a toilet flushing. As Daffy then rushes onto the stage dancing, the director yells in exasperation, "Cut! CUT! CUT!"


(Blooper) Bunny, Synopsis, Featured bloopers
Elmer Fudd fires a real gun as opposed to a prop, grazing Daffy's head. Bugs scolds him, but Elmer responds that he thought that it would be "a gweat, big birthday surpwise if after 511⁄2 years of twying, [he] finally bwasted [ Bugs]". Daffy starts yelling at Elmer for not using the prop gun and neglects Bugs's insistence on cutting. As he walks away telling Elmer to expect his lawyers to call him, he steps on the loose board Bugs had avoided earlier, and the board strikes him in the face and goes through his beak. When Bugs asks if they can cut now, Daffy grumbles, "You smug son of a—" and is then cut off when Daffy would've about to curse.


(Blooper) Bunny, Synopsis, Featured bloopers
Daffy dances onto the stage with the board still stuck to his face. Bugs uses a hand mirror to reveal this to Daffy. When he pulls it off, he yanks his beak off as well in the process, but continues speaking and where his beak was, a mouth appears, though he fails to notice it.


(Blooper) Bunny, Synopsis, Featured bloopers
Everything plays out correctly until Yosemite Sam emerges from the cake with a scowl on his face and two Cowgirls come up and spruce him up. The director asks him to act a little more enthusiastic and caring for the next take. Yosemite Sam reluctantly agrees and goes back into the cake, mumbling "But I hates rabbits".


(Blooper) Bunny, Synopsis, Featured bloopers
The spectacular performance is done perfectly, except for one thing, as Bugs puts it – there were supposed to be five rockets, but Sam replies "There were five! And I lit 'em, too!". The fifth rocket, attached to Sam's belt, sends him flying about before crashing into the camera. He then yells at Bugs, calling him a "carrot-chomping flop-eared, bobtailed rabbit", along with his usual cursing (which lasts throughout the credits) before being silenced by an unseen glass object. Bugs then suggests that what had just happened can be fixed in the editing before one of the producers asks, "Can we go to lunch now?" The familiar "That's All Folks" runs up the screen at the very end as if written in the film emulsion (like on raw footage).


(Blooper) Bunny, Production
(Blooper) Bunny was produced at a time when newer Looney Tunes shorts were being released to introduce the Warner cartoon characters to a younger, more modern generation — a process that was, thanks to the tepid reception of 2003's Looney Tunes: Back in Action, eventually discontinued for some time from 2004 to 2009. The film was animated using a combination of both new computer technology and traditional cel animation — a first for a Warner Bros. cartoon — with three-dimensional rendering distorting the background in the "backstage" scenes to give the appearance of a handicam being used. The first "backstage" scene in the film, a sequence that goes on for nearly a minute and a half without a cut, is, according to co-director Greg Ford, one of the single longest uninterrupted shots ever attempted in animated cartoons.


(Blooper) Bunny, Production
The short features several direct references to some of the previous output of Warner Bros. animation department. During the first, aforementioned "backstage" scene, the name of Bosko, the first true Looney Tunes star, can be seen on one of the dressing room doors for a few frames (ironically, the Warner Bros. studio did not own the rights to Bosko at the time). Midway through the film, there is also a deliberate homage to the "Hunting Trilogy" made popular by Chuck Jones, of whom Ford reportedly holds great admiration. Additionally, during the end credits, the theme song of One Froggy Evening, another Chuck Jones creation, can be heard.


(Blooper) Bunny, Suppression, rediscovery, and subsequent reputation
(Blooper) Bunny is a self-parody of some of the specials produced for Bugs Bunny's 50th anniversary the previous year, 1990. Intended to be released theatrically in 1991 with the Warner Brothers-released animated film Rover Dangerfield, the short, however, never received its intended theatrical release and was shelved for six years.


(Blooper) Bunny, Suppression, rediscovery, and subsequent reputation
Jonathan Rosenbaum, in a review for Chicago Reader, noted: "Ironically, Invasion of the Bunny Snatchers, another Bugs Bunny cartoon directed at the same time by the same rebellious duo, Greg Ford and Terry Lennon, is even more directly critical of studio greed, yet it got a pass and wound up on the TV special Bugs Bunny's Creature Features, perhaps because it was less formally transgressive."


(Blooper) Bunny, Suppression, rediscovery, and subsequent reputation
(Blooper) Bunny would not receive a television premiere until 1997, after Cartoon Network discovered the film sitting unseen in the vaults. It is featured on disc 1 of the Looney Tunes Golden Collection: Volume 1 DVD, as of 2003, along with an optional audio commentary by co-director Greg Ford.


(Blooper) Bunny, Suppression, rediscovery, and subsequent reputation
Jules Faber, in a review for DVD.net, lauded the cartoon as a "highlight" and elaborated further: "Blooper Bunny: Bugs Bunny's 511⁄2 Anniversary is a clever little blooper reel created in 1991 and utilising some brilliantly conceived early 3D rendering making a very funny behind the scenes mockumentary." Chicago Reader also gave the film a positive mention, saying:


(Blooper) Bunny, Suppression, rediscovery, and subsequent reputation
Much of what's funny about Blooper Bunny is the temperament of the aging cast: Bugs rehearsing his opening line, "Gosh, I'm so unimportant," over and over; Elmer still trying to grow hair with tonic; Daffy insanely jealous about being upstaged and threatening to have "my people" talk to "your people"; and Sam grouchily declaring as he's being forklifted onstage that he couldn't care less how old Bugs is — he still hates rabbits.


(Blooper) Bunny, Suppression, rediscovery, and subsequent reputation
Dawn Taylor, in a review for The DVD Journal, said: "it has some very funny moments, and falls completely flat in others."


(Butadiene)iron tricarbonyl
(Butadiene)iron tricarbonyl is an organoiron compound with the formula (C4H6)Fe(CO)3. It is a well-studied metal complex of butadiene. An orange-colored viscous liquid that freezes just below room temperature, the compound adopts a piano stool structure.


(Butadiene)iron tricarbonyl
The complex was first prepared by heating iron pentacarbonyl with the diene.


(Butadiene)iron tricarbonyl, Related compounds
Iron(0) complexes of conjugated dienes have been extensively studied. In the butadiene series, (η2-C4H6)Fe(CO)4 and (η2:η2-C4H6)(Fe(CO)4)2 have been crystallized. Many related complexes are known for substituted butadienes and related species. The species (η4-isoprene)iron tricarbonyl is chiral.


(C6)-CP 47,497
(C6)-CP 47,497 (CP 47,497 dimethylhexyl homologue) is a synthetic cannabinoid, a CP 47,497 homologue.


(C6H10O5)n
(C6H10O5)n may refer to several polymers sharing the molecular formula:


(C9)-CP 47,497
(C9)-CP 47,497 (CP 47,497 dimethylnonyl homologue) is a synthetic cannabinoid, a CP 47,497 homologue.


(CH-VOX)
(CH-VOX) is the third studio album by British music group Seefeel. The album was released in 1996 on friend Richard D. James's label Rephlex Records.


(CH-VOX), Release
(CH-VOX) was released on vinyl and compact disc on Rephlex Records on 11 November 1996. The album was made up of tracks recorded two years prior to its release.


(CH-VOX), Release
(Ch-Vox) Redux was released on 14 May 2021, containing six previously unreleased tracks.


(CH-VOX), Reception
Keir Langley of AllMusic called (CH-VOX) "an especially lush match of aesthetics — sort of a condensed version of the Aphex Twin landmark record, Selected Ambient Works II." Option called the album "memorable," writing that the band "isn't afraid of harsh textures if needed, but more importantly, they keep a pulse going."


(CH-VOX), Track listing
All tracks are written by Mark Clifford except where otherwise noted.


(Can You) Feel the Passion
"(Can You) Feel the Passion" is a 1991 rave-theme House song recorded, written, and produced by the American/British group Blue Pearl. The single is to date the act's second best known song after Naked In The Rain. Can You Feel The Passion had better success in the United States, hitting No. 1 on both Billboard's Hot Dance Club Play chart and the UK Dance Chart in 1992, while reaching No. 14 on the UK Singles Chart.


(Can You) Feel the Passion, Background
The single is done in a spoken word type manner by lead singer Durga McBroom, while the hook, riffs, and chorus melody written by Durga was augmented by Youth on the keyboards, and samples from Bizarre Inc's "Playing with Knives." Ironically, club DJs have used both "(Can You) Feel the Passion" and "Playing With Knives" in their bootleg mashups due to the former providing the lyrics and the latter's piano-heavy house feel.


(Can't Get My) Head Around You
"(Can't Get My) Head Around You" is a punk rock song by The Offspring. The song features as the sixth track of the band's seventh studio album Splinter (2003) and was released as the second single from the album in 2004. "(Can't Get My) Head Around You" was released to radio on February 24, 2004. The song also appears as the 14th and final track on the band's Greatest Hits (2005).


(Can't Get My) Head Around You, Music video
A music video was released in support of the single. The video clip features the band playing in a dome lit by fluorescent lights and was shot with over 125 cameras, in what the band's website calls 'the ultimate performance video'. The video was directed by Joseph Kahn, with Chris Watts supervising the visual effects and the multicamera system.


(Can't Get My) Head Around You, Music video
This is the first music video from The Offspring to show Atom Willard playing the drums.


(Can't Get My) Head Around You, Music video
The music video appears on the Complete Music Video Collection DVD, released in 2005.


(Can't Live Without Your) Love and Affection
"(Can't Live Without Your) Love and Affection" is a song by American rock band Nelson. It was released in 1990 on DGC Records and backed with "Will You Love Me?". The song was based on a crush on Cindy Crawford. The music video features model and actress Judie Aronson who first appears on the cover of a magazine called "Vague", a parody of Vogue magazine. The song itself is known for its technical drumming involving syncopation and double bass, and virtuoso guitar soloing.


(Can't Live Without Your) Love and Affection
The song topped the Billboard Hot 100 on September 29, 1990, becoming the only single from the band to top the chart. This made the Nelson family, in which Nelson's own Matthew and Gunnar Nelson are the sons of Ricky Nelson, the only family to have three generations of number one singles.


(Can't Live Without Your) Love and Affection
The production on the single and its B-side, "Will You Love Me? ", was done by David Thoener and Marc Tanner. It also appears as the first track on Nelson's album, After the Rain. The song is used in X-Men: Pryde of the X-Men. American boyband Natural covered the song for their 2002 album Keep It Natural.


(Can't You) Trip Like I Do
"(Can't You) Trip Like I Do" is a reworking of "Trip Like I Do", a song featured on The Crystal Method's debut album Vegas. The track was recorded for the 1997 film adaptation of the Spawn comic book series. The song was co-written by Richard Patrick and co-produced by Brian Liesegang, both from Filter who also appeared in the song's video. "(Can't You) Trip Like I Do" is the opening song on the film's soundtrack release, Spawn: The Album and is heard in the end credits. The song was also used for the theatrical trailer of The Matrix and promotional trailers for the Enter the Matrix video game but it does not appear in the film or on the soundtrack.


(Can't You) Trip Like I Do
Inspiration for the song came from a friend of Scott Kirkland who was using ecstasy and leaving voice mail messages telling him "I wish you could trip like I do."


(Can't You) Trip Like I Do, Credits
Tracks 1-3: written, recorded and produced by The Crystal Method and Filter. Mixed by Ben Grosse. Filter appears courtesy of Reprise Records. The Crystal Method appears courtesy of S3.


(Can't You) Trip Like I Do, Credits
Track 1 - Executive Producer and Artist Manager: Richard Bishop for 3 A.M.Track 2 - Remix and additional production by Danny Saber. Track 4 - Written by K. Jordan/S. Kirkland. Produced and mixed by The Crystal Method.


(Can't You) Trip Like I Do, Credits
Track 1 - Taken from /2&3 Special versions adapted from the Immortal/Epic release Spawn: The Album. Track 4 - Taken from the S3 release Vegas.


(Chet Baker Sings) It Could Happen to You
(Chet Baker Sings) It Could Happen to You is an album by jazz trumpeter and vocalist Chet Baker. It follows a formula similar to two other Baker albums, Chet Baker Sings (1954) and Chet Baker Sings and Plays with Bud Shank, Russ Freeman & Strings (recorded in 1955, released in 1964) in which he sings traditional pop standards in a jazzy fashion. Unlike the aforementioned records, on It Could Happen to You, on a few tracks, Baker plays no trumpet whatsoever, opting to scat in place of an instrumental solo.


(Chet Baker Sings) It Could Happen to You
In 2010, it was remastered and reissued on CD by Original Jazz Classics with two previously unissued takes.


(Chet Baker Sings) It Could Happen to You, Reception
The Allmusic review by Lindsay Planer awarded the album 4 stars and states: