(Mesitylene)molybdenum tricarbonyl, Reactions
Tricarbonyl(mesitylene)molybdenum can act as a catalyst for the polymerisation of phenylacetylene. The Molybdenum complex is activated with an oxidant such as chloranil. The result of the charge transfer facilitates ring slippage and the mesitylene group changes from η6 to η2 this allows the phenylacetylene monomer units to bind to the metal centre. Recently, it has been reported that tricarbonyl(mesitylene)molybdenum can act as a catalyst for the epoxidation of alkenes.


(Methionine synthase) reductase
[ Methionine synthase] reductase, or Methionine synthase reductase, encoded by the gene MTRR, is an enzyme that is responsible for the reduction of methionine synthase inside human body. This enzyme is crucial for maintaining the one carbon metabolism, specifically the folate cycle. The enzyme employs one coenzyme, flavoprotein.


(Methionine synthase) reductase, Mechanism
The 3 products of this enzyme are methionine synthase-methylcob(I)alamin, S-adenosylhomocysteine, and NADP+, whereas its 4 substrates are methionine synthase-cob(II)alamin, NADPH, H+, and S-adenosyl-L-methionine.


(Methionine synthase) reductase, Mechanism
Physiologically speaking, one crucial enzyme participated in the folate cycle is methionine synthase, which incorporated a coenzyme, cobalamin, also known as Vitamin B12. The coenzyme utilizes its cofactor, cobalt to catalyze the transferring function, in which the cobalt will switch between having 1 or 3 valence electrons, dubbed cob(I)alamin, and cob(III)alamin.


(Methionine synthase) reductase, Mechanism
Over time, the cob(I)alamin cofactor of methionine synthase becomes oxidized to cob(II)alamin, rendering the enzyme inactive. Therefore, regeneration of the enzyme is necessary. Regeneration requires reductive methylation via a reaction catalyzed by (methionine synthase) reductase in which S-adenosylmethionine is utilized as a methyl donor, reducing cob(II)alamin to cob(I)alamin.


(Methionine synthase) reductase, Systematic naming
This enzyme belongs to the family of oxidoreductases, to be specific those oxidizing metal ion with NAD+ or NADP+ as acceptor. The systematic name of this enzyme class is [methionine synthase]-methylcob(I)alamin,S-adenosylhomocysteine:NADP+ oxidoreductase. Other names in common use include methionine synthase cob(II)alamin reductase (methylating), methionine synthase reductase, [methionine synthase]-cobalamin methyltransferase (cob(II)alamin, and reducing).


(Methyl-Co(III) methanol-specific corrinoid protein):coenzyme M methyltransferase
(Methyl-Co(III) methanol-specific corrinoid protein):coenzyme M methyltransferase (EC , methyltransferase 2, mtaA (gene)) is an enzyme with systematic name methylated methanol-specific corrinoid protein:coenzyme M methyltransferase. This enzyme catalyses the following chemical reaction


(Methyl-Co(III) methanol-specific corrinoid protein):coenzyme M methyltransferase
Free methylcob(I)alamin can substitute for the corrinoid protein in vitro.


(Methyl-Co(III) methylamine-specific corrinoid protein):coenzyme M methyltransferase
(Methyl-Co(III) methylamine-specific corrinoid protein):coenzyme M methyltransferase (EC , methyltransferase 2, MT2, MT2-A, mtbA (gene)) is an enzyme with systematic name methylated monomethylamine-specific corrinoid protein:coenzyme M methyltransferase. This enzyme catalyses the following chemical reaction


(Methyl-Co(III) tetramethylammonium-specific corrinoid protein):coenzyme M methyltransferase
(Methyl-Co(III) tetramethylammonium-specific corrinoid protein):coenzyme M methyltransferase (EC , methyltransferase 2, mtqA (gene)) is an enzyme with systematic name methylated tetramethylammonium-specific corrinoid protein:coenzyme M methyltransferase. This enzyme catalyses the following chemical reaction


(Methyl-Co(III) tetramethylammonium-specific corrinoid protein):coenzyme M methyltransferase
This enzyme catalyses the transfer of a methyl group from a corrinoid protein.


(Miss)understood
(Miss)understood (stylized in all lowercase) is the seventh studio album by Japanese singer-songwriter Ayumi Hamasaki, released January 1, 2006 by Avex Trax. Hamasaki acted as the album's sole lyricist, as she had on all of her preceding albums. (Miss)understood marked new musical directions for Hamasaki: she explored new influences such as funk and used gospel choruses in some of the songs, foreign to her previous works. This was the result of her having heard compositions by Geo from Sweetbox and asking him for his works; subsequently, Hamasaki rewrote the lyrics to fit (Miss)understood. Lyrically, the album was a departure from her previous work, My Story, which had been primarily autobiographical.


(Miss)understood
Where My Story had contained "musings about her past", Hamasaki wanted the lyricism on (Miss)understood to send a strong message to all women—to be a kind of "girls' talk" to give "moral support", while at the same time reminding women that there were times when they would feel weak and low. These themes, along with the album's funk influences, are epitomized on songs such as "Bold & Delicious" and "Ladies Night".


(Miss)understood
"Step You/Is This Love?" was released as the lead single from (Miss)understood on April 20, 2005. It was a commercial success, reaching number one in Japan and receiving a Platinum certification, selling 345,340 copies in its chart run. It was the nineteenth best-selling song in Japan in 2005, and Hamasaki's best-selling single that year. Second single "Fairyland" was released August 3, and debuted at number one in Japan. It sold 170,000 copies in its first week, the most of any single from (Miss)understood. It went on to sell 316,663 copies, receiving a platinum certification. The third single, "Heaven", experienced similar success: it reached number one, and was certified Platinum, selling around 325,000 copies. "Bold & Delicious/Pride" was not as successful. Despite reaching number one, it became her poorest-selling single at the time since 1998's "Depend on You", selling only 133,000 copies.


(Miss)understood
(Miss)understood was commercially successful, opening at number one in Japan (her eighth consecutive record to do so) with first-week sales of 653,830 copies. It went on to sell over 877,000 copies in Japan in its 31-week chart run, receiving a Million certification and becoming the 8th best-selling album of 2006. It is, to date, her last Million-certified album. According to Avex, It is also her first album to fail to hit over a million sales in Japan according to Oricon. By 2007 (Miss)understood sold 1,030,000 copies in Japan.


(Miss)understood, Production, Background and themes
In 2005, after hearing demo tracks from band Sweetbox's then-upcoming album Addicted, Hamasaki "fell in love" with the songs and consequently asked Sweetbox's composer GEO if she could use some of the songs for her album. GEO agreed and gave Hamasaki permission to use "Bold & Delicious", "Pride", "Ladies Night", "In the Corner", "Every Step", and "Beautiful Girl". Hamasaki then set to work rewriting the lyrics and rearranging parts of songs.


(Miss)understood, Production, Background and themes
While My Story, Hamasaki's preceding album, contained mostly "autobiographical" lyrics and "musings about [her] past", (Miss)understood was a "strong message to send to all women": it was a kind of "girl's talk" to give "moral support" while at the same time reminding women that there would be times when they would "feel weak and low". "Bold & Delicious" "scolded indecisive men", "Pride" expressed Hamasaki's appreciation of "women who do not give up easily", and "Ladies Night" was about female camaraderie. Other themes appeared as well: "Is This Love?" and "Heaven" were about love, and "Fairyland" was about "childhood memories".


(Miss)understood, Production, Composition
(Miss)understood is more musically diverse than My Story; Hamasaki incorporated a variety of musical styles including rock, dance-pop and funk. The album opens with "Bold & Delicious", a funk-infused dance track that utilises a gospel choir in the harmony. The song makes use of funk guitars. "Pride" is a ballad song that "sounded like it could be from a musical"; the arrangement of both songs were influenced by Hamasaki's trip to New York City to record the songs and film their respective music videos.


(Miss)understood, Production, Composition
An organ Hamasaki heard while visiting a church inspired her to include the gospel choir in "Bold", while the musical The Phantom of the Opera influenced her arrangement of "Pride". "Criminal", "Step You", "Alterna", and the titular "(Miss)understood" are all rock songs with prominent electric guitars, while "Heaven" is an "ethereal" piano-driven ballad. As with "Bold & Delicious" and "Pride", other songs composed by GEO were rearranged; violins were added to the bridge of "Rainy Day", and a choir was added to the chorus of "Beautiful Day".


(Miss)understood, Extras
The initial pressings of the album included two photobooks—one for the CD version (entitled "Off My Day"), and another for the CD+DVD version (entitled "On My Way"). The DVD version included all PV's that were made for her 2005 releases (excluding "My Name's Women")—"Step You", "Is This Love? ", "Fairyland", "Alterna", "Heaven", "Bold & Delicious" and "Pride", as well as an alternative PV for "Bold & Delicious" (called the "Side Story"). Two new PVs were also included—"Ladies Night" and "Rainy Day" made their debut on the disc. Behind-the-scenes clips for "Step You", "Is This Love? ", "Fairyland", "Alterna", "Heaven" and "Pride" are featured as well. The song "Rainy Day" was used as the ending theme for the game "Onimusha: Dawn of Dreams".


(Miss)understood, Extras, Music videos
The PV for "Step You" was directed by Tetsuo Inoue and the video featured Ayumi wearing different styles of outfits (signifying different parts of her image and personality). A man walks up to a music box-like contraption and as he activates the levers (shown as I, II, III, and IV) different miniature versions of Ayumi appear. As he activates the last lever, the contraption begins to short-circuit, and the four Ayumis turn into one.


(Miss)understood, Extras, Music videos
The PV for "Is This Love?" was directed by Masashi Muto, the music video features Ayumi singing emotionally in a hotel suite. As she passes by, objects begin to explode (i.e. a bowl of fruit, a fish tank, walls, etc.). The video ends as Ayumi looks at the hotel, in one piece with no sort chaos that happened earlier.


(Miss)understood, Extras, Music videos
The PV of "Fairyland" was shot in Hawaii and is one of the most expensive music videos in the world, as well as being Japan's most expensive music video in terms of production costs. The PV cost 240 million Yen (2 million in U.S. dollars). The video was directed by Wataru Takeishi and it depicts Hamasaki with her companions (dance team) on a lush tropical island, with some scenes showing a timber house with a deck. Eventually, a fallen oil lamp causes the entire structure to burn. Images from earlier sequences showing the group having fun are interspersed through the burning of the house. The video ends with the camera moving away from Hamasaki singing solemnly as she watches the house burn.


(Miss)understood, Extras, Music videos
The PV of "Alterna" depicts Ayumi as an up-coming star who is chased by clowns. The video also depicts her as a singing machine; this aspect of the music video (as well as the lyrics of "alterna") may be Hamasaki's response to either tabloid articles or to her record label's oppressive treatment of her at the time.


(Miss)understood, Extras, Music videos
The PV for "Heaven" features Ayumi singing alone in a subway. As she does, ghosts frequently pass by her. Near the end of the video, the spirits leave Ayumi and board on a train (implying their departure to heaven). The video is done entirely in one shot and in black and white.


(Miss)understood, Extras, Music videos
The music videos of "Bold & Delicious" and "Pride" were both filmed in New York and were both directed by Luis Hernandez.


(Miss)understood, Extras, Music videos
In the video for "Bold & Delicious", Hamasaki is featured with long wavy black hair, and wears a faux fur jacket with a light pink dress. She is seen standing on the back of a moving truck driving through areas of New York City, evoking the iconic 1993 Björk music video for her single "Big Time Sensuality". Some shots feature "behind the scenes" material, showing footage of the truck driving around the city and film crew members.


(Miss)understood, Extras, Music videos
The video for "Pride" features several long takes of Hamasaki in a black dress being prepared by assistants and make-up artists, and then walking through an on-location set prepared under a New York City bridge and in the rain.


(Miss)understood, Extras, Music videos
The music video for "Ladies Night" features Ayumi wearing a pink and blue mini dress, and her legendary long blue leg muffs as she walks down a hotel hallway, trying to go into some of the rooms, and occasionally singing into a payphone. Scenes of different things happening in the rooms can be seen. In one room, a maid is mounted on a man and is whipping him.


(Miss)understood, Extras, Music videos
In another room, a woman dressed in a white 18th century dress and white powdered wig is seen walking around her room, which is all white and has a large collection of butterflies. In the third room, a strange woman in a bulky black dress with a long braided black wig and face painted all in black (later revealed to be Ayumi herself) is seen dominating and whipping mannequins. The hotel room scenes have been compared by many to the 1995 indie film Four Rooms.


(Miss)understood, Extras, Music videos
In between the hotel room scenes there are other scenes of Ayumi dressed in a dictator's outfit and addressing an army of bald and pale women in an outdoor arena that resembles the Colosseum. The women all appear to have the same face and march along to Ayumi's singing during the song's middle eight.


(Miss)understood, Extras, Music videos
The music video of "Rainy Day" features Ayumi with short-black hair singing in a house looking in and out of the window. The scene then cuts to her sitting at a bus stop, wearing a white-powered wig. A dog appears out of an alleyway. The dog and Ayumi stare at each other. During the mid-eight, rain has started to fall and the dog is no longer in the scene. Images of people passing the bus stop with umbrellas are shown. An Hansom cab then arrives and picks up Ayumi. She sees the lone dog again and looks back with a regretful face. The house scenes featuring shows Ayumi collapsing onto the floor and crying.


(Miss)understood, Sales
In 2007, Avex reported that (Miss)understood sold 1,030,000 copies in Japan. (Miss)understood was certified million by RIAJ in sales and was recognized for having more than a million copies shipped to store. On the Oricon Charts, (Miss)understood failed to break a million-selling only a little under 900,000 in 2006, but by 2007 it was able to sell 1,030,000 copies. The total sales number of the album's singles comes to a total of 1,285,000. The album sales and the single sales combined come to a grand sales revenue of 2,315,000 CDs sold.


(More) So Much More
(More) So Much More is a live EP released by Brett Dennen following the release of his second studio album So Much More. It includes several prominent songs from the previous album as well as a cover version of a Bob Marley song.


(More) So Much More, Track listing
All tracks are written by Brett Dennen, except where noted.


(Much) Wenlock (UK Parliament constituency)
Much Wenlock, often called simply Wenlock, was a constituency of the House of Commons of the Parliament of England until 1707, then of the Parliament of Great Britain from 1707 to 1800, and finally of the Parliament of the United Kingdom from 1801 to 1885, when it was abolished. It was named after the town of that name in Shropshire.


(Much) Wenlock (UK Parliament constituency)
The seat was founded in 1468 as a borough constituency and was represented throughout its history by two burgesses.


(Much) Wenlock (UK Parliament constituency), Boundaries
Much Wenlock's constituency boundaries ran from Leighton to just west of Dawley, to Ironbridge, and finally to just east of Madeley along the northern border; travelling eastwards, the boundaries ran from just east of Madeley to the bend in the River Severn, following the river thereafter. The far southern border, commencing in the east, travelled along the southern part of the Severn across to Easthope; the western border, running northwards, going from Easthope through to Benthall, and onwards back to Leighton.


(Much) Wenlock (UK Parliament constituency), Election results, Elections in the 1830s
Weld-Forester was appointed Groom of the Bedchamber to William IV, requiring a by-election.


(Much) Wenlock (UK Parliament constituency), Election results, Elections in the 1840s
Gaskell was appointed a Lord Commissioner of the Treasury, requiring a by-election.


(Much) Wenlock (UK Parliament constituency), Election results, Elections in the 1850s
Weld-Forester was appointed Comptroller of the Household, requiring a by-election.


(Much) Wenlock (UK Parliament constituency), Election results, Elections in the 1850s
Gaskell was appointed Comptroller of the Household, requiring a by-election.


(Much) Wenlock (UK Parliament constituency), Election results, Elections in the 1870s
Forester succeeded to the peerage, becoming Lord Forester and causing a by-election.


(My Baby Don't Love Me) No More
(My Baby Don't Love Me) No More" is a popular song.


(My Baby Don't Love Me) No More
The music was written by Leo J. De John, the lyrics by his sisters Julie De John and Dux De John. The song was published in 1954.


(My Baby Don't Love Me) No More
The best-selling version was recorded by The De John Sisters  (both credited as lyricists) in 1954; a recording was also made by The McGuire Sisters the same year. Both hit the Billboard magazine charts.


(My Baby Don't Love Me) No More
The recording by The De John Sisters was released by Epic Records as catalog number 9085. It first reached the Billboard magazine Best Seller chart on December 22, 1954, and lasted 10 weeks on the chart, peaking at #8. It reached #6 on the Billboard Top 100 charts.


(My Baby Don't Love Me) No More
The recording by The McGuire Sisters was released by Coral Records as catalog number 61323. It first reached the Billboard magazine Best Seller chart on January 19, 1955, and lasted 6 weeks on the chart, peaking at #23. The flip side of this recording was the bigger (#1) hit "Sincerely." In the UK, No More peaked at #20, and was covered by Billie Anthony.


(My Friends Are Gonna Be) Strangers
"(My Friends Are Gonna Be) Strangers" is a song written by Liz Anderson. Best remembered as American country music artist Merle Haggard's first national Top 10 record, it was also a Top 10 song concurrently for Roy Drusky. The song is also known as All My Friends Are Gonna Be Strangers, (From Now On) All My Friends Are Gonna Be Strangers, and simply Strangers. Haggard went on to name his band The Strangers after the record's success. The song was subsequently recorded by scores of additional country stars as an album track including George Jones, Ernest Tubb, Porter Wagoner, Ferlin Husky, as well as Liz Anderson herself and Anderson's daughter Lynn Anderson.


(My Friends Are Gonna Be) Strangers, Background and writing
Liz Anderson wrote the song circa 1964 and had sent it to Nashville producers. Her friend Bonnie Owens encouraged her to meet with Haggard (Owens' beau at the time) and pitch some of her songs to the newcomer. Anderson was reluctant to do so, having already had songs recorded by national artists and not particularly interested in a regional performer and having never heard Haggard, not certain he had talent but agreed to meet with him out of her loyalty to Owens.


(My Friends Are Gonna Be) Strangers, Background and writing
Haggard likewise had never heard of Anderson and was not particularly pleased that Bonnie insisted they go to the Anderson home to listen to some songs however Merle and Liz hit it off and both proved to be in awe of the others' talents, with Haggard eventually recording several songs by Anderson he heard that night. He was particularly taken with "(My Friends Are Gonna Be) Strangers" and rushed into the studio to record it and planned it for a single release.


(My Friends Are Gonna Be) Strangers, Background and writing
After the track had been cut and the single printed, all involved learned Roy Drusky had also just recorded it and was releasing it as a single. Although both Drusky and Haggard versions eventually made it into the Billboard Hot Country Singles top ten, the competing records undoubtedly kept either version for being a top five and perhaps number one record.


(My Friends Are Gonna Be) Strangers, Content
The song's narrator is embittered by a deceitful lover, not only vowing to be through with love but trusting in anyone at all.


(My My) Baby's Gonna Cry
"(My My) Baby's Gonna Cry" is a song recorded by pop music duo Eurythmics. It was written by group members Annie Lennox and David A. Stewart and produced by Stewart. The song appears on the duo's album We Too Are One.


(My My) Baby's Gonna Cry
"(My My) Baby's Gonna Cry" marked two firsts for Eurythmics: this was the only single from the band which was released in the United States but not the UK and this is also the only single released by the duo to feature co-lead vocals by Lennox and Stewart. Issued as the third American single from We Too Are One, the single failed to chart on the Billboard Hot 100. It did, however, chart in Canada, peaking at #58.


(My My) Baby's Gonna Cry
Lyrically Lennox sings the part of a woman asking her partner why he was "untrue" and whether he feels sorry for cheating, while he (Stewart) responds that the relationship makes him "feel sad", and he is "never coming back". The song could be interpreted as the foreshadowing of Eurythmics near decade-long hiatus, as the duo's professional relationship was strained at the time of We Too Are One's release.


(Myelin basic protein)-arginine N-methyltransferase
In enzymology, a [myelin basic protein]-arginine N-methyltransferase (EC ) is an enzyme that catalyzes the chemical reaction


(Myelin basic protein)-arginine N-methyltransferase
Thus, the two substrates of this enzyme are S-adenosyl methionine and myelin basic protein-arginine, whereas its two products are S-adenosylhomocysteine and myelin basic protein-Nomega-methyl-arginine.


(Myelin basic protein)-arginine N-methyltransferase
This enzyme belongs to the family of transferases, specifically those transferring one-carbon group methyltransferases. The systematic name of this enzyme class is S-adenosyl-L-methionine:[myelin-basic-protein]-arginine Nomega-methyltransferase. Other names in common use include myelin basic protein methylase I, protein methylase I, S-adenosyl-L-methionine:[myelin-basic-protein]-arginine, and omega-N-methyltransferase.


(N-acetylneuraminyl)-galactosylglucosylceramide N-acetylgalactosaminyltransferase
(N-acetylneuraminyl)-galactosylglucosylceramide N-acetylgalactosaminyltransferase (EC , uridine diphosphoacetylgalactosamine-ganglioside GM3 acetylgalactosaminyltransferase, ganglioside GM2 synthase, ganglioside GM3 acetylgalactosaminyltransferase, GM2 synthase, UDP acetylgalactosamine-(N-acetylneuraminyl)-D-galactosyl-D-glucosylceramide acetylgalactosaminyltransferase, UDP-N-acetyl-D-galactosamine:1-O-[O-(N-acetyl-alpha-neuraminyl)-(2->3)-O-beta-D-galactopyranosyl-(1->4)-beta-D-glucopyranosyl]-ceramide 1,4-beta-N-acetyl-D-galactosaminyltransferase acetylgalactosaminyltransferase, UDP-N-acetylgalactosamine GM3 N-acetylgalactosaminyltransferase, uridine diphosphoacetylgalactosamine-acetylneuraminylgalactosylglucosylceramide acetylgalactosaminyltransferase, uridine diphosphoacetylgalactosamine-hematoside acetylgalactosaminyltransferase, GM2/GD2-synthase, beta-1,4N-aetylgalactosaminyltransferase, asialo-GM2 synthase, GalNAc-T, UDP-N-acetyl-D-galactosamine:(N-acetylneuraminyl)-D-galactosyl-D-glucosylceramide N-acetyl-D-galactosaminyltransferase) is an enzyme with systematic name UDP-N-acetyl-D-galactosamine:1-O-(O-(N-acetyl-alpha-neuraminyl)-(2->3)-O-beta-D-galactopyranosyl-(1->4)-beta-D-glucopyranosyl)-ceramide 4-beta-N-acetyl-D-galactosaminyltransferase. This enzyme catalyses the following chemical reaction


(N-acetylneuraminyl)-galactosylglucosylceramide N-acetylgalactosaminyltransferase
This enzyme catalyses the formation of the gangliosides (i.e. sialic-acid-containing glycosphingolipids) GM2, GD2 and SM2 from GM3, GD3 and SM3, respectively.


(Ne) Polnoye sobraniye sochineniy
(Ne) Polnoye sobraniye sochineniy (Russian: (Не) Полное собрание сочинений, means '(In)complete collected works') is a greatest hits album by the Russian ska punk band Leningrad.


(Ne) Polnoye sobraniye sochineniy, Track listing
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(No Pussyfooting)
(No Pussyfooting) is the debut studio album by the British duo Fripp & Eno, released in 1973. (No Pussyfooting) was the first of three major collaborations between the musicians, growing out of Brian Eno's early tape delay looping experiments and Robert Fripp's "Frippertronics" electric guitar technique.


(No Pussyfooting)
(No Pussyfooting) was recorded in three days over the course of a year. Its release was close to that of Eno's own debut solo album Here Come the Warm Jets (1974), and it constitutes one of his early experiments in ambient music.


(No Pussyfooting), Production
Brian Eno invited Robert Fripp to his London home studio in September 1972. Eno was experimenting with a tape system developed by Terry Riley and Pauline Oliveros where two reel-to-reel tape recorders were set up side-by side. Sounds recorded on the first deck would be played back by the second deck, and then routed back into the first deck to create a long looping tape delay. Fripp played guitar over Eno's loops, while Eno selectively looped or recorded Fripp's guitar without looping it. The result is a dense, multi-layered piece of ambient music. This technique later came to be known as "Frippertronics"


(No Pussyfooting), Production
(No Pussyfooting)'s first track, which fills one side, is a 21-minute piece titled "The Heavenly Music Corporation". Fripp originally wanted the track titled "The Transcendental Music Corporation", which Eno didn't allow as he feared it would make people "think they were serious". It was recorded in two takes, first creating the background looping track, then adding an extended non-looped guitar solo over the backing track. This track features Fripp's electric guitar as the sole sound source.


(No Pussyfooting), Production
The second track "Swastika Girls", which fills the other side, was recorded almost a year after "The Heavenly Music Corporation" in August 1973 at Command Studios at 201 Piccadilly in London, where Fripp's King Crimson had recorded their acclaimed Larks' Tongues in Aspic album earlier that year. The track employed the same technique as "The Heavenly Music Corporation" except Fripp played to a background electronic loop created by Eno on VCS3. Fripp and Eno took the tapes of "Swastika Girls" to British record producer George Martin's AIR Studios at Oxford Circus to continue mixing and assembling the track there.


(No Pussyfooting), Production
The track's title refers to an image of nude women performing a Nazi salute that was ripped from a discarded pornographic film magazine found by Eno at AIR Studios. Eno stuck the image on the recording console while recording the track with Fripp and it became the title of the track.


(No Pussyfooting), Release and reception
Released in November 1973, (No Pussyfooting) failed to chart in either the US or UK. Island Records  actively opposed it. The album was released in the same year as Eno's more rock-based solo album Here Come the Warm Jets. Eno was attempting to launch a solo career, having left Roxy Music, and his management bemoaned the confusion caused by two albums with such different styles. Robert Fripp's bandmates in King Crimson also disliked the album. The mainstream rock press paid the album little attention compared to Fripp's work with King Crimson and Eno's solo album.


(No Pussyfooting), Release and reception
In the UK, the album was released at a large discount compared to normal prices and was regarded as something of a novelty. In 1975, Robert Christgau, critic for The Village Voice, gave the album a B+ rating, calling it "the most enjoyable pop electronics since Terry Riley's A Rainbow in Curved Air" and that it was "...more visionary and more romantic than James Taylor could dream of being."


(No Pussyfooting), Release and reception
The album was rereleased on vinyl in 1982, and on CD in 1987 by E.G. Records. Modern reception has been mostly positive. Ted Mills of AllMusic gave the album four and a half stars out of five, praising "Heavenly Music Corporation" and noting "the beauty" of their tape deck setup, yet giving a negative view of "Swastika Girls", suggesting the loop system was abused with "too many disconnected sounds sharing the space, some discordant, some melodic... the resulting work lacks form and structure".


(No Pussyfooting), Release and reception
Eric Tamm, the author of the Eno biography Brian Eno: His Music and the Vertical Color of Sound (1995) reacted similarly to Mills, stating that "The Heavenly Music Corporation" "anticipated Eno's own ambient style." About "Swastika Girls" Tamm said, "if it is less successful than the earlier piece, it is because of the much greater overall saturation of the acoustical space. There seems to be a perceptual rule that possibilities for appreciation of timbral subtleties decrease in proportion to the rate of actual notes being played. ' Swastika Girls' shows that Eno and Fripp had not yet understood the full weight of this principle".


(No Pussyfooting), Release and reception
More recent reviews of Fripp & Eno's album The Equatorial Stars (2004) cite (No Pussyfooting) in a positive light. Peter Marsh for the BBC's experimental music review referred to the album as "now one of those albums that's spoken about in hushed, reverential tones as a proto-ambient classic". Dominique Leone of the music webzine Pitchfork noted that "to [Fripp's] and Eno's credit, it didn't really sound like anything that had come before it".


(No Pussyfooting), Release and reception
"I was told later," recalled Fripp, "that, as a consequence of the album, Eno's management decided he was ready to go solo. They thought he had a far more glittering commercial career available to him than working with the progressive rock, left-field guitarist Robert Fripp, which now seems absurd. However, here are the ironies: David Bowie was a fan, I believe, of (No Pussyfooting); and I was told that Iggy Pop, who David was working with at the time, could sing all the main guitar themes."


(No Pussyfooting), Release and reception
A double CD 24 bit remastered edition, by Simon Heyworth and Robert Fripp was released in 2008, the bonus disc featuring reversed versions of both tracks and a half-speed version of "The Heavenly Music Corporaton".


(No Pussyfooting), Track listing
All tracks are written by Brian Eno and Robert Fripp.


(No Pussyfooting), Track listing, Remastered edition (2008)
The double CD remastered edition adds variations to the track list:


(No Pussyfooting), Track listing, Remastered edition (2008)
24 bit remaster by Simon Heyworth and Robert Fripp. This edition also divides "Heavenly" into five CD tracks and "Swastika Girls" into two. The inclusion of the reversed versions is based on the incident where Fripp and Eno sent John Peel a copy of the album on open reel tape instead of standard vinyl, and had it "tails out" on what was meant to be the take-up reel, meaning that the tape had to be rewound to the beginning before playing it.


(No Pussyfooting), Track listing, Remastered edition (2008)
On the December 18, 1973 broadcast of his Radio 1 show Top Gear, John played the entire album - backwards, showing that the "tails out" notice was disregarded. Eno had been listening to Peel's show and phoned the BBC demanding to speak with him, but the receptionist took exception to his tone and hung up on him, and the playback continued unabated. After the second track, Peel said on the air, "I'd like to see what they made of that on Come Dancing... Opinion in here is divided...I think it's great, I really do, magnificent, in fact, in the Tangerine [Dream] tradition, I suppose, in a sense. Very very good, and well worth having the LP, incidentally."


(No Pussyfooting), Legacy
The album artwork influenced the music video set for The 1975's 2018 single, "Give Yourself a Try", and The Strokes's 2003 single "The End Has No End". Electronic music composer Kim Cascone uses the moniker Heavenly Music Corporation in tribute to Fripp & Eno.


(Norbornadiene)molybdenum tetracarbonyl
(Norbornadiene)molybdenum tetracarbonyl is the organomolybdenum compound with the formula (C7H9)Mo(CO)4. Structurally, the compound consists of the norbornadiene bonded to a Mo(CO)4 fragment. The compound is a yellow, volatile solid. It is prepared by thermal or photochemical substitution of molybdenum hexacarbonyl. The compound was originally examined as a potential antiknock agent.


(Norbornadiene)molybdenum tetracarbonyl
(Norbornadiene)molybdenum tetracarbonyl is a precursor to other derivatives of the type L2Mo(CO)4. This conversion exploits the lability of the diene ligand:


(Not Just) Knee Deep
"(Not Just) Knee Deep" is a funk song, with a running time of 15 minutes, 21 seconds, on Side 1 of Funkadelic's 1979 album Uncle Jam Wants You.


(Not Just) Knee Deep, Song information
An edited version of the song, appearing as Side A on the single release, reached number one on the Billboard Black Singles chart. The song was written by George Clinton (credited on some releases as "George Clinton, Jr."); the recording was arranged by Walter "Junie" Morrison and produced by Clinton under the alias "Dr. Funkenstein".


(Not Just) Knee Deep, Song information
The Funkadelic version is sung by Clinton and several other group members, including Philippé Wynne, who was a former lead singer of the rhythm and blues group, The Spinners, which he left two years earlier.


(Not Just) Knee Deep, Song information
The song is widely regarded as a funk classic, peaking at No. 77 on the Billboard Hot 100 and topping the US R&B charts in 1979. The lyrics tell of a "girl" who "was a freak of the week" and the man who was dancing with her. He was unimpressed by the Jerk, the Monkey, the Chicken, and the Moose, but was turned on by the Freak.


(Not Just) Knee Deep, Sampled in other music
The song has been heavily sampled by many artists. Hip hop group De La Soul sampled the intro to the song in their hit "Me Myself and I", which reached #34 on the Billboard Pop Charts and #1 on the R&B Charts.


(Not Just) Knee Deep, Sampled in other music
Also LL Cool J ("Nitro"), Everlast ("Never Missin A Beat"), Tone Lōc ("Funky Cold Medina"), MC Hammer & Deion Sanders ("Straight to My Feet"), The rap group Mass 187 ("Swang Your Hips)", G-Funk Intro & his unreleased track "Do U Remember". Tha Dogg Pound used the sample in their unreleased track "Can't C Us". Geto Boys sampled the intro for "Homie Don't Play That". The Black Eyed Peas also used the beat behind it to remix their hit single "Shut Up". X Clan sampled the song in "Funkin' Lesson". It was also interpolated in the song "Get Away" by Bobby Brown. In 2014, it was sampled in Jessie J's "Seal Me with a Kiss".


(Not Just) Knee Deep, Sampled in other music
EPMD sampled it in their song "Gold Digger", and Digital Underground used it in two of their songs, "Kiss You Back" and "Bran Nu Swetta".


(Not Just) Knee Deep, Sampled in other music
Rapper 2Pac sampled the song for his "Intro/Bomb First (My Second Reply)" and his Dr. Dre produced track "Can't C Me".


(Not Just) Knee Deep, Sampled in other music
In 1997, Vanessa Williams sampled "Knee Deep" for her song "Happiness".


(Not Just) Knee Deep, Sampled in other music
Dr. Dre's song, "Fuck wit Dre Day (And Everybody's Celebratin')", is based on "Knee Deep".


(Not Just) Knee Deep, Sampled in other music
South Korean girl band Mamamoo song "Um Oh Ah Yeh" from their third mini-album Pink Funky was influenced from it.


(Not) The Love of My Life
"(Not) The Love of My Life" is a song by Malaysian singer-songwriter Yuna, released as the fourth single from her fourth international album (her seventh overall), Rouge. The song was co-written by Yuna, Alexandra Govere and Robin Hannibal and released on August 22, 2019 by Verve Forecast Records.


(Not) The Love of My Life, Music video
""(Not) The Love Of My Life" tells a story of a bride in the midst of getting ready for her wedding but is second guessing her decision to settle down. I went back to Malaysia and wanted to collaborate again with my friend and traditional Indian choreographer Harshini Sukumaran whom I’ve worked with in the "Forevermore" music video.


(Not) The Love of My Life, Music video
The official video for "(Not) The Love of My Life" was premiered on Yuna's official YouTube and Vevo account on 22 August 2019. The video features Bollywood-theme with Yuna herself served as a director. In the video, Yuna wears Indian costumes and traditional folk jewelry from head to toe. The video also marks Yuna’s second collaboration with Indian traditional choreographer, Harshini Sukumaran after "Forevermore".


(Not) The Love of My Life, Critical reception
In a retrospective review of Rouge, Skylar de Paul from The Daily Californian said: "(Not) The Love of My Life" continues following Yuna’s emotional growth. Each lyric is enunciated like spoken word, showing she wants to make her message clear: The person she’s singing to is not really "the one"". Adriane Pontecorvo from PopMatters described the song "has gorgeous color to its melody, in no small part due to Yuna's dulcet scorn".


(Nothing But) Flowers
"(Nothing But) Flowers" is a song by rock band Talking Heads. It appears on the band's final album Naked, released in 1988. It was released as the album's second single. In addition to the band, the song features Kirsty MacColl on backup vocals and Johnny Marr, formerly of The Smiths, on lead guitar. It peaked at number 79 in the UK Singles Chart. Kevin Smith used the song as the opening of Clerks 2.


(Nothing But) Flowers, Music video
The song's music video featured innovative uses of typography by graphic designer Tibor Kalman. The band performs in the video with an expanded lineup featuring Johnny Marr, Kirsty MacColl, Brice Wassy, Yves N'Djock and Abdou M'Boup, all of whom performed on the studio recording of the song. The music video was directed by Sandy McLeod and David Byrne.


(Nothing But) Flowers, 2010 TED Conference
David Byrne performed a briefer version of the song at the 2010 TED conference accompanied by Thomas Dolby on keyboard and the string quartet ETHEL.


(Nothing Serious) Just Buggin'
"(Nothing Serious) Just Buggin'" is the debut single by American hip hop/R&B group Whistle, from their 1986 eponymous debut album. It was first released as a single in 1985, and was a top ten hit and the group's only major success in the UK, where it peaked at No. 7 on the UK Singles Chart in early 1986. On the U.S. Billboard R&B and dance charts, it reached numbers 17 and 18, respectively.


(Now You See Me) Now You Don't
"(Now You See Me) Now You Don't" is a song written by Tony Lane, Jess Brown and David Lee, and recorded by American country music artist Lee Ann Womack. It was released in August 1999 as the third single from her CD Some Things I Know. The song peaked at number 12 on the Billboard Hot Country Singles & Tracks.


(Now You See Me) Now You Don't, Critical reception
Editors at Billboard gave the song a positive review and wrote, "Clocking in under three minutes, it's a short, saucy little number with a lively melody, excellent guitar work, and a clever lyric about a woman on her way out of a sour relationship. Womack's voice is a combination of childlike vulnerability and spurned-woman desperation as she perfectly conveys the emotion in the lyric. This has all the elements necessary to become a summertime hit--and possibly Womack's long-awaited chart-topper."


(Now and Then There's) A Fool Such as I
"(Now and Then There's) A Fool Such as I" is a popular song written by Bill Trader and was published in 1952. Recorded as a single by Hank Snow it peaked at number four on the US country charts  early in 1953.


(Now and Then There's) A Fool Such as I
Since the original Snow version, "Fool Such as I"—as the song is sometimes known—has been recorded and released as singles several times, by artists as diverse as Jo Stafford, Elvis Presley, Bob Dylan, and Baillie & the Boys.


(Now and Then There's) A Fool Such as I, Other versions, Tommy Edwards
The Tommy Edwards version reached number 13 on the Cash Box survey. Listed a co-best-seller with the Jo Stafford version, it lasted 11 weeks in their chart.


(Now and Then There's) A Fool Such as I, Other versions, Jo Stafford
The recording by Jo Stafford was released by Columbia Records as catalog number 39930. It reached the Billboard Best Seller chart on February 28, 1953, at number twenty, its only week on the chart.


(Now and Then There's) A Fool Such as I, Other versions, Elvis Presley
A recording by Elvis Presley was a platinum record. Initially released as B-side to "I Need Your Love Tonight", it reached number one in the UK as an A-side single. Presley's recording reached number two in the United States.


(Now and Then There's) A Fool Such as I, Other versions, Elvis Presley
The song was recorded on June 10, 1958 at RCA's Studio B, Nashville, while Presley was on leave from the Army. The recording featured guitar by Hank Garland, Chet Atkins and Presley, bass by Bob Moore, drums by D. J. Fontana and Buddy Harman and piano by Floyd Cramer and backing vocal by the Jordanaires, with the bass voice provided by Ray Walker. It reached number sixteen on the R&B charts.


(Now and Then There's) A Fool Such as I, Other versions, Petula Clark
Petula Clark's French language version titled "Prends mon Cœur", was more successful in France (number 9, 1960) than Presley's version.


(Now and Then There's) A Fool Such as I, Other versions, Bob Dylan
In 1967, Bob Dylan recorded the song during the Basement Tape sessions. For many years never officially released, the recording had been widely bootlegged, and was finally released November 4, 2014, on The Bootleg Series Vol. 11: The Basement Tapes Complete. Dylan recorded the song again in April 1969; that version was released in 1973 by Columbia on the Dylan album. On the 1973 Dylan album and several associated Columbia 1973 singles, the song is wrongly credited to "B. Abner" and "LeFevre Sing Pub Co (BMI)". This is a different song with the same title, written by Buford Abner of the Swanee River Boys. This mistake has not been corrected, and on www.bobdylan.com the song is still credited to "B. Abner".


(Now and Then There's) A Fool Such as I, Other versions, Rodney Crowell
Rodney Crowell covered the song in 1979. The release was not a success, peaking at No. 90 in the Billboard country charts. It was his second charting single after "Elvira" in the previous year which barely scraped the bottom of the charts as well. Both songs were included in his debut album Ain't Living Long Like This.


(Now and Then There's) A Fool Such as I, Other versions, Baillie & the Boys
In 1990, Baillie & the Boys released the song from the band's album The Lights of Home. This version, released under the title "Fool Such as I", peaked at No. 5 on the Billboard Hot Country Singles chart. It was the trio's last Top 10 hit on the country charts.


(Now and Then There's) A Fool Such as I, Other versions, Slim Whitman
Whitman also recorded his own country version on the Imperial Records label in 1959.


(Oh Baby Mine) I Get So Lonely
"Oh Baby Mine (I Get So Lonely)" is a popular song. It was written by Pat Ballard and was published in 1953.


(Oh Baby Mine) I Get So Lonely, Original recording
The biggest hit version was done by The Four Knights on Capitol Records in 1953.


(Old Dogs, Children and) Watermelon Wine
"(Old Dogs, Children And) Watermelon Wine" is a song written and recorded by American country music artist Tom T. Hall. It was released in November 1972 as the second and final single from the album, The Storyteller. The song was Hall's third number one on the U.S. country singles chart and earned him his second nomination for the Grammy Award for Best Country Song. "(Old Dogs, Children And) Watermelon Wine" spent one week at the top and a total of thirteen weeks on the chart. On June 1, 2014, Rolling Stone magazine ranked "(Old Dogs, Children and) Watermelon Wine" #93 in their list of the 100 greatest country songs.


(Old Dogs, Children and) Watermelon Wine, Content
The song is a true account of Hall's experience at the 1972 Democratic National Convention, where he had a conversation with an old porter (janitor) at a Miami Beach hotel. The porter appraises his own life by concluding that the only worthwhile things are the three listed in the song's title.


(Old Dogs, Children and) Watermelon Wine, Covers
The song has been covered by artists such as Frankie Laine, George Burns, John Prine and Mac Wiseman, and Ferlin Husky. Alf Robertson recorded the song in 1977 in Swedish as Hundar och ungar och hembryggt äppelvin (Swedish for Dogs and children and home brewed apple wine), with new lyrics by  himself. and with the song he also scored a Svensktoppen hit for 10 weeks between 2 November 1980--18 January 1981 which included topping the chart.


(One Glance Is) Holy
"(One Glance Is) Holy" is a single by English musician Mike Oldfield, released in 1989. It is from the album Earth Moving. Lead vocals are by Adrian Belew of the progressive rock band King Crimson. The single was only released in Germany, and contained four mixes of the song including an instrumental version.


(Open Up the Door) Let the Good Times In
"(Open Up the Door) Let the Good Times In" is a song that was released by Dean Martin in 1966. The song spent 6 weeks on the Billboard Hot 100 chart, peaking at No. 55, while reaching No. 7 on Billboard's Easy Listening chart, and No. 51 on Canada's RPM 100.


(Opportunity Knocks But Once) Snatch and Grab It
"(Opportunity Knocks But Once) Snatch and Grab It" is a 1947 novelty song composed by Sharon A. Pease. The song was performed by Julia Lee and Her Boy Friends. The single was number one on the US Billboard R&B chart for twelve weeks and spent seven months on the chart.


(Otto)
(Otto) is a 2015 Dutch animated short film directed by Job Roggeveen, Joris Oprins and Marieke Blaauw, from the Dutch animation studio Job, Joris & Marieke. The film had its international premiere at the Toronto International Film Festival. (Otto) was chosen to be the official Dutch entry for the Academy Award Best Animated Short Film 2016. Job, Joris & Marieke's previous film A Single Life was nominated Academy Award for Best Animated Short Film at the 87th Academy Awards.


(Otto), Plot
A woman who can't have children steals the imaginary friend of a little girl and keeps this a secret from her husband. While the woman enjoys life with her imaginary child the gap between her and her husband grows bigger. When the little girl comes to claim back her imaginary friend, it's the power of imagination that brings everyone together.


(Our Love) Don't Throw It All Away
"(Our Love) Don't Throw It All Away" is a song penned by Barry Gibb and Blue Weaver and recorded by the Bee Gees in 1977 on the Saturday Night Fever sessions but was not released until Bee Gees Greatest (1979). It was released in September 1978 as the third single by Andy Gibb on his version from his second studio album Shadow Dancing.


(Our Love) Don't Throw It All Away, Andy Gibb's version
"(Our Love) Don't Throw It All Away" was released as the third single from Andy Gibb's Shadow Dancing album, but only in the United States, in September 1978. The song was also his fifth single to reach the US Top 10; the single reached #9 on the Billboard Hot 100 chart and #2 on the Adult Contemporary chart.


(Our Love) Don't Throw It All Away, Andy Gibb's version
When Andy Gibb was going to record it, Barry reworked on the song adding the middle eight that was not on the original Bee Gees' version, as Blue Weaver recalls, "When Andy actually went to record it, Barry listened to it [the original version] again and thought, 'Oh, it's not finished', so Barry wrote the whole of the middle-eight.


(Our Love) Don't Throw It All Away, Andy Gibb's version
Allmusic's Amy Hanson described this version of "(Our Love) Don't Throw It All Away" as a "tender ballad" that suited Andy's voice. It appears on Andy's three greatest-hits albums.


(Our Love) Don't Throw It All Away, Bee Gees' version
The Bee Gees version of the song, the first one created, was recorded in 1977 during the sessions for Saturday Night Fever but was not released until the compilation Bee Gees Greatest 1979. Barry and Maurice Gibb are the only members of the Bee Gees to appear on the recording.


(Our Love) Don't Throw It All Away, Bee Gees' version
Barry wrote the lyrics while Weaver composed the melody. Weaver said of this song, "That was me playing around again; It wasn't done for [Saturday Night Fever], it was just something that we did". The stereo mix of an early state of the song exists but was unreleased until now. Samantha Sang, who was visiting France where this version was recorded, asked Barry for a song; not long afterwards, Barry sent Sang "Don't Throw it All Away", but Sang never recorded or released it, choosing instead the new song "Emotion".


(Our Love) Don't Throw It All Away, Bee Gees' version
During the Bee Gees' One Night Only tour, they performed the song with Andy's vocal mixed in during the second stanza, chorus, bridge and the coda of the song years after Andy died.


(Pentamethylclopentadienyl)titanium trichloride
(Pentamethyclopentadienyl)titanium trichloride is an organotitanium compound with the formula Cp*TiCl3 (Cp* = C5(CH3)5). It is an orange solid. The compound adopts a piano stool geometry. An early synthesis involve the combination of lithium pentamethylcyclopentadienide and titanium tetrachloride. The compound is an intermediate in the synthesis of decamethyltitanocene dichloride.


(Pentamethylcyclopentadienyl)aluminium(I)
(Pentamethylcyclopentadienyl)aluminium(I) is an organometallic compound with the formula Al(C5Me5) ("Me" is a methyl group; CH3). The compound is often abbreviated to AlCp* or Cp*Al, where Cp* is the pentamethylcyclopentadienide anion (C5Me5−). Discovered in 1991 by Dhmeier et al., AlCp* serves as the first ever documented example of a room temperature stable monovalent aluminium compound. In its isolated form, Cp*Al exists as the tetramer [Cp*Al]4, and is a yellow crystal that decomposes at temperatures above 100 °C but also sublimes at temperatures above 140 °C.


(Pentamethylcyclopentadienyl)aluminium(I), Synthesis
The earliest documented synthesis and characterization of Cp*Al was by Dohmeier et al. in 1991, where four equivalents of AlCl in toluene/diethyl ether is reacted with two equivalents of 2[Mg(Cp*)2] to give [Cp*Al]4 as yellow crystals:


(Pentamethylcyclopentadienyl)aluminium(I), Synthesis
Despite the above synthetic scheme successfully producing tetrameters of [Cp*Al]4 at reasonable yields (44%), its use of AlCl proved problematic, as AlCl synthesis requires harsh conditions and its reactive nature makes storage a challenge. As such, more facile ways of synthesising the [Cp*Al]4 tetramer were discovered, and required the reduction of Cp*AlX2 (X = Cl, Br, I) by a metal (K when X = Cl) or a metal alloy (Na/K alloys when X = Br, I):


(Pentamethylcyclopentadienyl)aluminium(I), Synthesis
More exotic ways of synthesizing [Cp*Al]4 include the controlled disproportionation of an Al(II) dialane into constituent Al(I) and Al(III) products. For example, reacting dialane [ Cp*AlBr]2 with a Lewis base such as pyridine the Lewis base stabilized [Cp*AlBr2] and [Cp*Al]4.


(Pentamethylcyclopentadienyl)aluminium(I), Synthesis
Monomeric Cp*Al has also been isolated in a solid Ar matrix by heating [Cp*Al]4 in toluene to 133 °C and spraying the resultant vapours with Ar onto a copper block kept at 12 K.


(Pentamethylcyclopentadienyl)aluminium(I), Structure and Bonding
X-ray crystallographic data determined Cp*Al to exist exclusively as a tetramer in its solid state. This tetramer, [Cp*Al]4, consists of an Al4 tetrahedron, and the Cp* rings are ŋ5-coordinated to the aluminium(I) cation such that the planes of the C5Me5- rings are approximately parallel to the opposite base of the Al4 tetrahedron. The perpendicular distance between Al and the Cp* ring was determined through crystallography to range from 199.7 to 203.2 pm, with a mean value of 201.5 pm.


(Pentamethylcyclopentadienyl)aluminium(I), Structure and Bonding
The Al-Al bond in [Cp*Al]4 is 276.9 pm, which is slightly shorter than that of metallic aluminium, which has an Al-Al bond length of 286 pm. Additionally, the Al-Al bond in [Cp*Al]4 is significantly shorter than other oligomeric and polymeric Group III M(I)-ŋ5-Cp* compounds such as octahedral [InCp*]6 (394, 336 pm), dimeric [InCp*]2 (363.1 pm), and polymeric [TlCp*] (641 pm), indicating a significantly larger interaction between aluminium atoms in [Cp*Al]4 than monovalent Cp* compounds of In(I) and Tl(I). Additional characterization that has been performed include Raman spectroscopy, which detected a Raman active breathing vibration (A1, 377 cm-1) of the Al4 tetrahedron in [Cp*Al]4.


(Pentamethylcyclopentadienyl)aluminium(I), Structure and Bonding
Natural bond orbital (NBO) analysis of [Cp*Al] and [Cp*Al]4 using B3LYP/6-31G(d,p) calculated the average charge transfer per Cp* fragment to an Al atom to be 0.657 and 0.641 respectively. This is slightly higher than the charge transfers calculated on [CpAl] and [Cp*Al]4 (0.630 and 0.591 respectively). NBO calculation of the HOMO-LUMO gap in [Cp*Al] also revealed a significant decreasing in the tetrameric [Cp*Al]4 complex compared to the monomeric [Cp*Al] (4.36 compared to 5.49), which is consistent with density functional theory calculations of analogous systems including superatom complexes of gold, aluminium and gallium. Atoms in molecules (AIM) calculations calculate the Al-Al bonding to be metallic. Stabilization of [Cp*Al]4 relative to [CpAl]4 is thought to arise from addition of H-H interactions on the methyl groups attached to the Cp* ligand as opposed to the increased Al-Al bonding interactions.


(Pentamethylcyclopentadienyl)aluminium(I), Structure and Bonding
Despite its typically tetrameric form, the monomer Cp*Al has been isolated and studied in the gas-phase using gas-phase electron diffraction. In its gaseous monomeric form, the perpendicular distance between the Al to the Cp* ring was calculated to be 206.3(8) pm, which is slightly longer than tetrameric [Cp*Al]4.


(Pentamethylcyclopentadienyl)aluminium(I), Reactivity
When isolated in a solid H2 doped Ar matrix, monomeric Cp*Al has shown to form the hydride species H2Cp*Al upon exposure to H2 and photolysis with a Hg lamp:


(Pentamethylcyclopentadienyl)aluminium(I), Reactivity
At temperatures above 100 °C, [Cp*Al]4 decomposes to form pentamethylcyclopentandiene (Cp*H), metallic aluminium (Al(0)) and other non-volatile Al(III) compounds. The overall stability of [Cp*Al]4 is unique as there is a thermodynamic affinity for tetrameric aluminium(I) compounds ([RAl]4) to disproportionate into elemental aluminium and R3Al. As such, a number of different novel oligomeric structures can be synthesised when using tetrameric [Cp*Al]4 as a precursor. For example, treatment of [Cp*Al]4 with excess selenium and tellurium in mild conditions gives the unique heterocubane structures [Cp*AlSe]4 and [Cp*AlTe]4 respectively. These heterocubane structures are extremely air and moisture sensitive, leading to its decomposition and evolution of H2Se and H2Te respectively. Analogously, reaction of [Cp*Al]4 with lighter chalcogens such as O2, N2O and sulfur yield [Cp*AlX]4 (X = O, S).


(Pentamethylcyclopentadienyl)aluminium(I), Reactivity
[Cp*Al]4 was also the used as a precursor to synthesize the first ever stable dimeric iminoalane containing an Al2N2 heterocycle through the treatment of [Cp*Al]4 with Me3SiN3 in a 1:4 molar ratio. The resultant iminoalanes was characterized to contain an ideally planar Al2N2 core ring with three coordinate aluminium and nitrogen atoms. Other dimeric iminoalanes including [Cp*AlNSi(i-Pr)3]2, [Cp*AlNSiPh3]2 and [Cp*AlNSi(t-Bu)3]2 have since been synthesized using [Cp*Al]4 as a precursor through oxidative addition of an organic azide.


(Pentamethylcyclopentadienyl)aluminium(I), Reactivity, Function as a ligand
[ Cp*Al] is able to act as an atypical exotic ligand in donor-acceptor type bonds. For example, mixing [ Cp*Al]4 with the Lewis acidic B(C6F6)3 forms the Al-B donor-acceptor type bond, and results in the synthesis of the adduct [Cp*Al-B(C6F6)3]. Analogous main-group complexes that have been synthesised and characterised include dialane complexes [Cp*Al-Al(C6F5)3] and [Cp*Al-Al(t-Bu)3], and group 13-group 13 complexes [Cp*Al-Ga(t-Bu)3].


(Pentamethylcyclopentadienyl)aluminium(I), Reactivity, Function as a ligand
[ Cp*Al] is also able to act as a potent ligand to transition metals. For example, treatment of [Cp*Al] with [(dcpe)Pt(H)(CH2t-Bu)] (dcpe = bis(dicyclohexylphosphino)ethane) yields [(dcpe)Pt(Cp*Al)2]. Other transition metals which use [Cp*Al] as a ligand include, but are not limited to d10 metal centre complexes such as [Pd(Cp*Al)4] and [Ni(Cp*Al)4], and lanthanide/actinide metal centre complexes such as (CpSiMe3)3U-AlCp*, (CpSiMe3)3Nd-AlCp* and (CpSiMe3)3Ce-AlCp*.


(Phosphatase 2A protein)-leucine-carboxy methyltransferase
(phosphatase 2A protein)-leucine-carboxy methyltransferase (EC , leucine carboxy methyltransferase-1, LCMT1) is an enzyme with systematic name S-adenosyl-L-methionine:(phosphatase 2A protein)-leucine O-methyltransferase. This enzyme catalyses the following chemical reaction


(Pronounced 'Lĕh-'nérd 'Skin-'nérd)
(Pronounced 'Lĕh-'nérd 'Skin-'nérd) is the debut album by American rock band Lynyrd Skynyrd, released in 1973. Several of the album's songs remain among the band's most well-known: "Gimme Three Steps", "Simple Man", "Tuesday's Gone" and "Free Bird", the latter of which launched the band to national stardom.


(Pronounced 'Lĕh-'nérd 'Skin-'nérd)
The album was certified gold on December 18, 1974, and double platinum on July 21, 1987, by the RIAA. It peaked at 27 on the Billboard 200 in 1975.


(Pronounced 'Lĕh-'nérd 'Skin-'nérd), Overview
Most of the songs on the album had been in the band's live repertoire for some time. The band found a rural rehearsal space near Jacksonville, Florida which they nicknamed "Hell House" due to the long hours spent there jamming in the intense Florida heat, and it was there that they composed and ran through the songs endlessly until they were perfected. Producer Al Kooper marveled at how well prepared the band were once they entered the studio; every note was immutable and absolutely no improvisation was allowed.


(Pronounced 'Lĕh-'nérd 'Skin-'nérd), Overview
Bassist Leon Wilkeson left the band a few months before the album's recording sessions. Ex-Strawberry Alarm Clock guitarist Ed King had been impressed with the band after an earlier incarnation of Lynyrd Skynyrd had opened for Strawberry Alarm Clock in Florida circa 1970. He told vocalist Ronnie Van Zant to keep him in mind if he ever needed a guitarist, and he was invited to replace Wilkeson as bassist. Once the recording sessions were wrapping up, Van Zant decided that King would better serve the band as a guitarist, and he visited Wilkeson and convinced him to rejoin.


(Pronounced 'Lĕh-'nérd 'Skin-'nérd), Overview
Wilkeson returned to the band and King moved to lead guitar, giving the band what would become their trademark "Three Guitar Army" along with Allen Collins and Gary Rossington. Wilkeson was back in the band by the time the band shot the cover photo for the album, and appears on the cover, as well as being acknowledged in the liner notes.


(Pronounced 'Lĕh-'nérd 'Skin-'nérd), Overview
Atlanta Rhythm Section drummer and friend of the band Robert Nix was requested by Van Zant and Al Kooper to play on the track "Tuesday's Gone".


(Pronounced 'Lĕh-'nérd 'Skin-'nérd), Overview
As the band worked up "Simple Man" in rehearsal, producer Kooper expressed his feeling that the song was weak and should not be included on the album. The band felt differently on both counts and could not change Kooper's mind. Ultimately, Van Zant escorted the producer outside to his car and ordered him to remain there until the song was recorded. The band recorded the song on their own with the producer absent from the studio, and it subsequently became one of Lynyrd Skynyrd's best known tracks.


(Pronounced 'Lĕh-'nérd 'Skin-'nérd), Overview
The album was re-released in 2001 as an expanded version with bonus tracks, including the two B-sides to the original singles and three previously unreleased demos from the album sessions. Sales through 2014 were an estimated two million units internationally.


(Pronounced 'Lĕh-'nérd 'Skin-'nérd), Cover art
The cover photograph was taken on Main Street in Jonesboro, Georgia and shows, from left to right, Leon Wilkeson (seated), Billy Powell (seated), Ronnie Van Zant, Gary Rossington (seated), Bob Burns, Allen Collins and Ed King. The photo was the last in a long day of shooting for the album cover, and Rossington vomited on the sidewalk seconds after it was taken. To the right of Ed King in the background is a lightning strike in the sky. It is not fabricated and the band did not know it was there until after they saw the released album cover.


(Pronounced 'Lĕh-'nérd 'Skin-'nérd), Cover art
With Ed King's death on August 22, 2018, Rossington is the last surviving member of Lynyrd Skynyrd pictured in this photo.


(Pronounced 'Lĕh-'nérd 'Skin-'nérd), Reception
(Pronounced 'Lĕh-'nérd 'Skin-'nérd) immediately put the band on the rock-and-roll map. Upon its release, rock journalist Robert Christgau acknowledged the quality of the songs and gave the album an "A" rating while referring to Lynyrd Skynyrd as a "staunchly untranscendent band". Producer Al Kooper, a close friend of Pete Townshend, secured the band a spot opening for The Who on their American tour, and Lynyrd Skynyrd was subsequently exposed to much larger audiences than they had ever seen before.


(Pronounced 'Lĕh-'nérd 'Skin-'nérd), Reception
In 2012, Rolling Stone magazine ranked the album number 403 on its list of the 500 Greatest Albums of All Time, and it was later ranked number 381 in the 2020 edition.


(Pyruvate, phosphate dikinase) kinase
(Pyruvate, phosphate dikinase) kinase (EC , PPDK regulatory protein, pyruvate, phosphate dikinase regulatory protein, bifunctional dikinase regulatory protein) is an enzyme with systematic name ADP:(pyruvate, phosphate dikinase) phosphotransferase. This enzyme catalyses the following chemical reaction


(Pyruvate, phosphate dikinase) kinase
This enzyme is isolated from the plants Zea mays (maize) and arabidopsis.


(Pyruvate, phosphate dikinase)-phosphate phosphotransferase
(Pyruvate, phosphate dikinase)-phosphate phosphotransferase (EC , PPDK regulatory protein, pyruvate, phosphate dikinase regulatory protein, bifunctional dikinase regulatory protein, PDRP1 (gene)) is an enzyme with systematic name (pyruvate, phosphate dikinase) phosphate:phosphate phosphotransferase. This enzyme catalyses the following chemical reaction


(Pyruvate, phosphate dikinase)-phosphate phosphotransferase
The enzyme from the plants maize and arabidopsis is bifunctional and also catalyses the phosphorylation of pyruvate (EC 2.7.11.32).


(Pyruvate, water dikinase) kinase
(Pyruvate, water dikinase) kinase (EC , PSRP, PEPS kinase) is an enzyme with systematic name ADP:(pyruvate, water dikinase) phosphotransferase. This enzyme catalyses the following chemical reaction


(Pyruvate, water dikinase)-phosphate phosphotransferase
(Pyruvate, water dikinase)-phosphate phosphotransferase (EC , PSRP) is an enzyme with systematic name (pyruvate, water dikinase) phosphate:phosphate phosphotransferase. This enzyme catalyses the following chemical reaction


(Q,r) model
The (Q,r) model is a class of models in inventory theory. A general (Q,r) model can be extended from both the EOQ model and the base stock model


(Q,r) model, Overview, Costs
The number of orders per year can be computed as F(Q,r)=DQ{\displaystyle F(Q,r)={\frac {D}{Q}}}, the annual fixed order cost is F(Q,r)A. The fill rate is given by:


(Q,r) model, Overview, Costs
The annual stockout cost is proportional to D[1 - S(Q,r)], with the fill rate beying:


(Q,r) model, Overview, Costs, Backorder cost approach
The total cost is given by the sum of setup costs, purchase order cost, backorders cost and inventory carrying cost:


(Q,r) model, Overview, Costs, Backorder cost approach
The optimal reorder quantity and optimal reorder point are given by:


(Q,r) model, Overview, Costs, Stockout cost approach
The total cost is given by the sum of setup costs, purchase order cost, stockout cost and inventory carrying cost:


(Q,r) model, Overview, Costs, Stockout cost approach
What changes with this approach is the computation of the optimal reorder point:


(Q,r) model, Overview, Lead-Time Variability
σ=Var(X)=ℓσD2+d2σL2= θ+d2σL2{\displaystyle \sigma ={\sqrt {Var(X)}}={\sqrt {\ell \sigma _ {D}^{2}+d^{2}\sigma _{L}^{2}}}={\sqrt {\theta +d^{2}\sigma _{L}^{2}}}}


(R)-2-Methyl-CBS-oxazaborolidine
(R)-2-Methyl-CBS-oxazaborolidine is an organoboron catalyst that is used in organic synthesis. This catalyst, developed by Itsuno and Elias James Corey, is generated by heating (R)-(+)-2-(diphenylhydroxymethyl) pyrrolidine along with trimethylboroxine or methylboronic acid. It is an excellent tool for the synthesis of alcohols in high enantiomeric ratio. Generally, 2-10 mol% of this catalyst is used along with borane-tetrahydrofuran (THF), borane-dimethylsulfide, borane-N,N-diethylaniline, or diborane as the borane source. Enantioselective reduction using chiral oxazaborolidine catalysts has been used in the synthesis of commercial drugs such as ezetimibe and aprepitant.


(R)-2-haloacid dehalogenase
In enzymology, a (R)-2-haloacid dehalogenase (EC ), DL-2-haloacid halidohydrolase (inversion of configuration), DL-DEXi, (R,S)-2-haloacid dehalogenase (configuration-inverting)) is an enzyme that catalyzes the chemical reaction


(R)-2-haloacid dehalogenase
Thus, the two substrates of this enzyme are (R)-2-haloacid and H2O, whereas its two products are (S)-2-hydroxyacid and halide.


(R)-2-haloacid dehalogenase
This enzyme belongs to the family of hydrolases, specifically those acting on halide bonds in carbon-halide compounds. The systematic name of this enzyme class is (R)-2-haloacid halidohydrolase. Other names in common use include 2-haloalkanoic acid dehalogenase[ambiguous], 2-haloalkanoid acid halidohydrolase[ambiguous], D-2-haloacid dehalogenase, and D-DEX.


(R)-2-hydroxy-fatty-acid dehydrogenase
In enzymology, a (R)-2-hydroxy-fatty-acid dehydrogenase (EC ) is an enzyme that catalyzes the chemical reaction


(R)-2-hydroxy-fatty-acid dehydrogenase
Thus, the two substrates of this enzyme are (R)-2-hydroxystearate and NAD+, whereas its 3 products are 2-oxostearate, NADH, and H+. This reaction is important in fatty acid metabolism.


(R)-2-hydroxy-fatty-acid dehydrogenase
This enzyme belongs to the family of oxidoreductases, specifically those acting on the CH-OH group of donor with NAD+ or NADP+ as acceptor. The systematic name of this enzyme class is (R)-2-hydroxystearate:NAD+ oxidoreductase. Other names in common use include D-2-hydroxy fatty acid dehydrogenase, and 2-hydroxy fatty acid oxidase.


(R)-2-hydroxyacid dehydrogenase
In enzymology, a (R)-2-hydroxyacid dehydrogenase (EC ) is an enzyme that catalyzes the chemical reaction


(R)-2-hydroxyacid dehydrogenase
The 3 substrates of this enzyme are (2R)-3-sulfolactic acid, NAD+, and NADP+, whereas its 4 products are 3-sulfopyruvic acid, NADH, NADPH, and H+. This enzyme is important in the metabolism of archaea, particularly their biosynthesis of coenzymes such as coenzyme M, tetrahydromethanopterin and methanofuran.


(R)-2-hydroxyacid dehydrogenase
This enzyme belongs to the family of oxidoreductases, specifically those acting on the CH-OH group of donor with NAD+ or NADP+ as acceptor. The systematic name of this enzyme class is (R)-2-hydroxyacid:NAD(P)+ oxidoreductase. Other names in common use include (R)-sulfolactate:NAD(P)+ oxidoreductase, L-sulfolactate dehydrogenase, ComC, and (R)-sulfolactate dehydrogenase.


(R)-2-hydroxyacid dehydrogenase, Structural studies
As of late 2007, only one structure has been solved for this class of enzymes, with the PDB accession code .


(R)-2-methylmalate dehydratase
In enzymology, a (R)-2-methylmalate dehydratase (EC ) is an enzyme that catalyzes the chemical reaction


(R)-2-methylmalate dehydratase
Hence, this enzyme has one substrate, (R)-2-methylmalate, and two products, 2-methylmaleate and H2O.


(R)-2-methylmalate dehydratase
This enzyme belongs to the family of lyases, specifically the hydro-lyases, which cleave carbon-oxygen bonds. The systematic name of this enzyme class is (R)-2-methylmalate hydro-lyase (2-methylmaleate-forming). Other names in common use include citraconate hydratase, citraconase, citramalate hydro-lyase, (−)-citramalate hydro-lyase, and (R)-2-methylmalate hydro-lyase. This enzyme participates in valine, leucine and isoleucine biosynthesis and c5-branched dibasic acid metabolism. It employs one cofactor, iron.


(R)-3-Nitrobiphenyline
(R)-3-Nitrobiphenyline is a drug which acts as an α2-adrenergic agonist, selective for the α2C subtype, as well as being a weak antagonist at the α2A and α2B subtypes.


(R)-3-amino-2-methylpropionate—pyruvate transaminase
In enzymology, a (R)-3-amino-2-methylpropionate—pyruvate transaminase (EC ) is an enzyme that catalyzes the chemical reaction


(R)-3-amino-2-methylpropionate—pyruvate transaminase
Thus, the two substrates of this enzyme are (R)-3-amino-2-methylpropanoate and pyruvate, whereas its two products are 2-methyl-3-oxopropanoate and L-alanine.


(R)-3-amino-2-methylpropionate—pyruvate transaminase
This enzyme belongs to the family of transferases, specifically the transaminases, which transfer nitrogenous groups. The systematic name of this enzyme class is (R)-3-amino-2-methylpropanoate:pyruvate aminotransferase. Other names in common use include D-3-aminoisobutyrate-pyruvate transaminase, beta-aminoisobutyrate-pyruvate aminotransferase, D-3-aminoisobutyrate-pyruvate aminotransferase, D-3-aminoisobutyrate-pyruvate transaminase, (R)-3-amino-2-methylpropionate transaminase, and D-beta-aminoisobutyrate:pyruvate aminotransferase. But some additional information is that this enzyme catalyzed it transamination with L isomer, but D isomer in natural form, inactive as substrate. Also other names of enzymes similar to this contains, L-3-aminoisobutyrate transaminase, beta-aminobutyric transaminase, L-3-aminoisobutyric aminotransferase, and beta-aminoisobutyrate-alpha-ketoglutarate transaminase.


(R)-3-hydroxyacid-ester dehydrogenase
In enzymology, a (R)-3-hydroxyacid-ester dehydrogenase (EC ) is an enzyme that catalyzes the chemical reaction


(R)-3-hydroxyacid-ester dehydrogenase
Thus, the two substrates of this enzyme are ethyl (R)-3-hydroxyhexanoate and NADP+, whereas its 3 products are ethyl 3-oxohexanoate, NADPH, and H+.


(R)-3-hydroxyacid-ester dehydrogenase
This enzyme belongs to the family of oxidoreductases, specifically those acting on the CH-OH group of donor with NAD+ or NADP+ as acceptor. The systematic name of this enzyme class is ethyl-(R)-3-hydroxyhexanoate:NADP+ 3-oxidoreductase. This enzyme is also called 3-oxo ester (R)-reductase.


(R)-4-hydroxyphenyllactate dehydrogenase
In enzymology, a (R)-4-hydroxyphenyllactate dehydrogenase (EC ) is an enzyme that catalyzes the chemical reaction


(R)-4-hydroxyphenyllactate dehydrogenase
The 3 substrates of this enzyme are (R)-3-(4-hydroxyphenyl)lactate, NAD+, and NADP+, whereas its 4 products are 3-(4-hydroxyphenyl)pyruvate, NADH, NADPH, and H+.


(R)-4-hydroxyphenyllactate dehydrogenase
This enzyme belongs to the family of oxidoreductases, specifically those acting on the CH-OH group of donor with NAD+ or NADP+ as acceptor. The systematic name of this enzyme class is (R)-3-(4-hydroxyphenyl)lactate:NAD(P)+ 2-oxidoreductase. Other names in common use include (R)-aromatic lactate dehydrogenase, and D-hydrogenase, D-aryllactate. This enzyme participates in tyrosine and phenylalanine catabolism.


(R)-6-hydroxynicotine oxidase
In enzymology, a (R)-6-hydroxynicotine oxidase (EC ) is an enzyme that catalyzes the chemical reaction


(R)-6-hydroxynicotine oxidase
The 3 substrates of this enzyme are (R)-6-hydroxynicotine, H2O, and O2, whereas its two products are 1-(6-hydroxypyridin-3-yl)-4-(methylamino)butan-1-one and H2O2.


(R)-6-hydroxynicotine oxidase
This enzyme belongs to the family of oxidoreductases, specifically those acting on the CH-NH group of donors with oxygen as acceptor. The systematic name of this enzyme class is (R)-6-hydroxynicotine:oxygen oxidoreductase. Other names in common use include D-6-hydroxynicotine oxidase, and 6-hydroxy-D-nicotine oxidase. It employs one cofactor, FAD.


(R)-6-hydroxynicotine oxidase, Structural studies
As of late 2007, 3 structures have been solved for this class of enzymes, with PDB accession codes , , and .


(R)-amidase
(R)-amidase (EC , R-stereospecific amidase, R-amidase) is an enzyme with systematic name (R)-piperazine-2-carboxamide amidohydrolase. This enzyme catalyses the following chemical reaction


(R)-amidase
This enzyme also hydrolyses (R)-piperidine-3-carboxamide to (R)-piperidine-3-carboxylic acid and NH3.


(R)-aminopropanol dehydrogenase
In enzymology, a (R)-aminopropanol dehydrogenase (EC ) is an enzyme that catalyzes the chemical reaction


(R)-aminopropanol dehydrogenase
Thus, the two substrates of this enzyme are (R)-1-aminopropan-2-ol and NAD+, whereas its 3 products are aminoacetone, NADH, and H+.


(R)-aminopropanol dehydrogenase
This enzyme belongs to the family of oxidoreductases, specifically those acting on the CH-OH group of donor with NAD+ or NADP+ as acceptor. The systematic name of this enzyme class is (R)-1-aminopropan-2-ol:NAD+ oxidoreductase. Other names in common use include L-aminopropanol dehydrogenase, 1-aminopropan-2-ol-NAD+ dehydrogenase, L(+)-1-aminopropan-2-ol:NAD+ oxidoreductase, 1-aminopropan-2-ol-dehydrogenase, DL-1-aminopropan-2-ol: NAD+ dehydrogenase, and L(+)-1-aminopropan-2-ol-NAD+/NADP+ oxidoreductase. This enzyme participates in glycine, serine and threonine metabolism. It requires potassium as a cofactor.


(R)-benzylsuccinyl-CoA dehydrogenase
(R)-benzylsuccinyl-CoA dehydrogenase (EC , BbsG, (R)-benzylsuccinyl-CoA:(acceptor) oxidoreductase) is an enzyme with systematic name (R)-benzylsuccinyl-CoA:electron transfer flavoprotein oxidoreductase. This enzyme catalyses the following chemical reaction


(R)-citramalate synthase
(R)-citramalate synthase (EC , CimA) is an enzyme. This enzyme catalyses the following chemical reaction


(R)-citramalate synthase
This enzyme participates in a novel pyruvate pathway for isoleucine biosynthesis.


(R)-dehydropantoate dehydrogenase
In enzymology, a (R)-dehydropantoate dehydrogenase (EC ) is an enzyme that catalyzes the chemical reaction


(R)-dehydropantoate dehydrogenase
The 3 substrates of this enzyme are (R)-4-dehydropantoate, NAD+, and H2O, whereas its 3 products are (R)-3,3-dimethylmalate, NADH, and H+.


(R)-dehydropantoate dehydrogenase
This enzyme belongs to the family of oxidoreductases, specifically those acting on the aldehyde or oxo group of donor with NAD+ or NADP+ as acceptor. The systematic name of this enzyme class is (R)-4-dehydropantoate:NAD+ 4-oxidoreductase. Other names in common use include D-aldopantoate dehydrogenase, D-2-hydroxy-3,3-dimethyl-3-formylpropionate:diphosphopyridine, and nucleotide (DPN+) oxidoreductase. This enzyme participates in pantothenate and coa biosynthesis.


(R)-limonene 6-monooxygenase
In enzymology, a (R)-limonene 6-monooxygenase (EC ) is an enzyme that catalyzes the chemical reaction


(R)-limonene 6-monooxygenase
The 4 substrates of this enzyme are (+)-(R)-limonene, NADPH, H+, and O2, whereas its 3 products are (+)-trans-carveol, NADP+, and H2O.


(R)-limonene 6-monooxygenase
This enzyme belongs to the family of oxidoreductases, specifically those acting on paired donors, with O2 as oxidant and incorporation or reduction of oxygen. The oxygen incorporated need not be derived from O2 with NADH or NADPH as one donor, and incorporation of one atom o oxygen into the other donor. The systematic name of this enzyme class is (R)-limonene,NADPH:oxygen oxidoreductase (6-hydroxylating). Other names in common use include (+)-limonene-6-hydroxylase, and (+)-limonene 6-monooxygenase. This enzyme participates in monoterpenoid biosynthesis and limonene and pinene degradation.


(R)-limonene synthase
In enzymology, a (R)-limonene synthase (EC ) is an enzyme that catalyzes the reversible chemical reaction


(R)-limonene synthase
Hence, this enzyme has one substrate, geranyl diphosphate, and two products, (+)-(4R)-limonene and diphosphate.


(R)-limonene synthase
This enzyme belongs to the family of lyases, specifically those carbon-oxygen lyases acting on phosphates. The systematic name of this enzyme class is geranyl-diphosphate diphosphate-lyase [cyclizing, (+)-(4R)-limonene-forming]. Other names in common use include (+)-limonene synthase, and geranyldiphosphate diphosphate lyase [(+)-(R)-limonene-forming]. This enzyme participates in monoterpenoid biosynthesis and is localized to Leucoplasts of oil gland secretory cells.


(R)-limonene synthase, Further reading
This EC 4.2 enzyme-related article is a stub. You can help Wikipedia by .


(R)-p-Isothiocyanatobenzoylecgonine methyl ester
(R)-p-Isothiocyanatobenzoylecgonine methyl ester (p-ISOCOC) is a cocaine analogue and irreversible (covalent) binding inhibitor of the cocaine receptor, as well as irreversible blocker of dopamine uptake by DAT (the latter being unlike its C3 homologue m-Isococ). p-Isococ also blocks the high-affinity cocaine site in preference to the low-affinity site.


(R)-pantolactone dehydrogenase (flavin)
In enzymology, a (R)-pantolactone dehydrogenase (flavin) (EC ) is an enzyme that catalyzes the chemical reaction


(R)-pantolactone dehydrogenase (flavin)
Thus, the two substrates of this enzyme are (R)-pantolactone and acceptor, whereas its two products are 2-dehydropantolactone and reduced acceptor.


(R)-pantolactone dehydrogenase (flavin)
This enzyme belongs to the family of oxidoreductases, specifically those acting on the CH-OH group of donor with other acceptors. The systematic name of this enzyme class is (R)-pantolactone:acceptor oxidoreductase (flavin-containing). Other names in common use include 2-dehydropantolactone reductase (flavin), 2-dehydropantoyl-lactone reductase (flavin), and (R)-pantoyllactone dehydrogenase (flavin).


(R)evolution: The Remixes
(R)Evolution: The Remixes is a remix album from German trance producer and DJ Paul van Dyk released on 22 February 2013. The album consists of 18 selected remixes of songs from the original Evolution album in 2012.


(R,R)-Tetrahydrochrysene
(R,R)-Tetrahydrochrysene ((R,R)-THC) is a drug used to study the estrogen receptors (ERs) in scientific research. It is an ERβ antagonist and an ERα agonist with 10-fold higher affinity for ERβ relative to ERα. (R,R)-THC is a silent antagonist of ERβ, and, uniquely relative to other known ERβ antagonists, a passive antagonist of the receptor.


(R,R)-Tetrahydrochrysene
(S,S)-Tetrahydrochrysene ((S,S)-THC) also binds to the ERs, but in contrast to (R,R)-THC, (S,S)-THC is an agonist of both ERα and ERβ and has 20-fold lower affinity for ERβ relative to (R,R)-THC.


(R,R)-butanediol dehydrogenase
In enzymology, a (R,R)-butanediol dehydrogenase (EC ) is an enzyme that catalyzes the chemical reaction


(R,R)-butanediol dehydrogenase
Thus, the two substrates of this enzyme are (R,R)-butane-2,3-diol and NAD+, whereas its 3 products are (R)-acetoin, NADH, and H+.


(R,R)-butanediol dehydrogenase
This enzyme belongs to the family of oxidoreductases, specifically those acting on the CH-OH group of donor with NAD+ or NADP+ as acceptor. The systematic name of this enzyme class is (R,R)-butane-2,3-diol:NAD+ oxidoreductase. Other names in common use include butyleneglycol dehydrogenase, D-butanediol dehydrogenase, D-(−)-butanediol dehydrogenase, butylene glycol dehydrogenase, diacetyl (acetoin) reductase, D-aminopropanol dehydrogenase, D-aminopropanol dehydrogenase, 1-amino-2-propanol dehydrogenase, 2,3-butanediol dehydrogenase, D-1-amino-2-propanol dehydrogenase, (R)-diacetyl reductase, (R)-2,3-butanediol dehydrogenase, D-1-amino-2-propanol:NAD+ oxidoreductase, 1-amino-2-propanol oxidoreductase, and aminopropanol oxidoreductase. This enzyme participates in butanoic acid metabolism.


(RED)Wire
(RED)Wire is an online magazine and music service created by Bono (of the Irish rock band U2) and Bobby Shriver. It is a part of the broader Product RED organization, which serves to work with corporations who are contracted to give a percentage of their profits for particular products to the Global Fund to fight HIV/AIDS in Africa. (RED)Wire was created on World AIDS Day on December 1, 2006. Each issue contains an exclusive song from a major artist and a "spotlight" song from an up-and-coming artist, as well as other non-music media, such as video clips, poems, and so on.


(RED)Wire
A full subscription costs the user $5 per month, half of which goes to the Global Fund and the other half going to the artists and producers involved, thus creating a sustainable business. Users can sign up to receive two free issues of the magazine. The magazine is currently only available for users in the United States and the United Kingdom. Currently (RED)Wire does not offer previous issues for purchase, but negotiations with the labels to be able to offer them are ongoing.


(RED)Wire
Issues of the magazine are retrieved and displayed by a custom Adobe Air application.


(RNA-polymerase)-subunit kinase
In enzymology, a [RNA-polymerase]-subunit kinase (EC ) is an enzyme that catalyzes the chemical reaction


(RNA-polymerase)-subunit kinase
Thus, the two substrates of this enzyme are ATP and DNA-directed RNA polymerase, whereas its two products are ADP and [[phospho-[DNA-directed RNA polymerase]]].


(RNA-polymerase)-subunit kinase
This enzyme belongs to the family of transferases, specifically those transferring a phosphate group to the sidechain oxygen atom of serine or threonine residues in proteins (protein-serine/threonine kinases). The systematic name of this enzyme class is ATP:[DNA-directed RNA polymerase] phosphotransferase. Other names in common use include CTD kinase, and STK9.


(RS)-1-benzyl-1,2,3,4-tetrahydroisoquinoline N-methyltransferase
In enzymology, a (RS)-1-benzyl-1,2,3,4-tetrahydroisoquinoline N-methyltransferase is an enzyme that catalyzes the chemical reaction:


(RS)-1-benzyl-1,2,3,4-tetrahydroisoquinoline N-methyltransferase, Nomenclature
This enzyme belongs to the family of transferases, specifically those transferring one-carbon group methyltransferases. The systematic name of this enzyme class is S-adenosyl-L-methionine:(RS)-1-benzyl-1,2,3,4-tetrahydroisoquinoline N-methyltransferase. This enzyme is also called norreticuline N-methyltransferase.


(RS)-MCPG
(RS)-MCPG is a phenylglycine derivative and a non-selective antagonist of group I and II metabotropic glutamate receptors (mGluRs). It has been used in long-term potentiation (LTP) as well as long-term depression (LTD) research and proved that certain LTP and LTD pathways depend on mGluRs. Its full chemical name is (RS)-α-methyl-4-carboxyphenylglycine. It appears as a white solid and its molecular weight is 209.2 Da. Its molecular formula is C10H11NO4.


(RS)-norcoclaurine 6-O-methyltransferase
In enzymology, a (RS)-norcoclaurine 6-O-methyltransferase (EC ) is an enzyme that catalyzes the chemical reaction


(RS)-norcoclaurine 6-O-methyltransferase
Thus, the two substrates of this enzyme are S-adenosyl methionine and (R,S)-norcoclaurine, whereas its two products are S-adenosylhomocysteine and (R,S)-coclaurine.


(RS)-norcoclaurine 6-O-methyltransferase
This enzyme belongs to the family of transferases, specifically those transferring one-carbon group methyltransferases. The systematic name of this enzyme class is S-adenosyl-L-methionine:(RS)-norcoclaurine 6-O-methyltransferase. This enzyme participates in alkaloid biosynthesis i.


(Rap) Superstar
"(Rap) Superstar" is a single by American hip hop group Cypress Hill. The song was released as the lead single from the group's fifth album, Skull & Bones. It was originally released as a double A-side with its rock counterpart on February 29, 2000 in the UK. An individual release was available starting sometime in April.


(Rap) Superstar, Music video
The music video for the song begins with a young man walking down the street, kicking a can. Walking up to a puddle, the man finds a ticket with "Rap Superstar" written on it. A fun house suddenly pops up and the man hands the ticket to Sen Dog, then enters. In one of the rooms, the man sees a group of women who dress him up in a suit. In another room, the man listens to a speech being given by B-Real, dressed as Fidel Castro. In another room, TV screens show rappers Eminem and Noreaga giving testimonies about the rap business. At the video's climax, the man goes to a performance by the band before being chased by the crowd. As the man exits the fun house, an explosion occurs and the man smiles.


(Reach Up for The) Sunrise
"(Reach Up for The) Sunrise" is a song recorded by English pop rock band Duran Duran. It was released as the lead single from their eleventh studio album, Astronaut (2004) and their 31st single overall. It was the first single since "A View to a Kill" in 1985 to feature all five of the original members of the band. The song was sent to US radio on 30 August 2004 and was issued physically over the following few months.


(Reach Up for The) Sunrise
Upon its release, "Sunrise" debuted and peaked at number five on the UK Singles Chart, giving the band their 14th top-10 hit in their native country. It was highly successful in Italy, where it reached number two, as well as in Denmark and Spain, peaking at number six in both countries. In the United States, the single topped the Billboard Dance Club Songs chart, Duran Duran's third and last song to do so.


(Reach Up for The) Sunrise, Chart performance
"Sunrise" peaked at number five on the UK Singles Chart in October 2004 and reached number one on the US Billboard Hot Dance Music/Club Play chart on 4 December 2004. The Jason Nevins newly produced version is the main version of the song. It marked the band's first top ten since "Ordinary World" in the UK, even though its chart stay was only four weeks. Elsewhere, the song reached number six in Denmark and Spain and number two in Italy, where it became the soundtrack of a telephone advertising campaign.


(Reach Up for The) Sunrise, Music video
The video was directed by Michael and Mark Polish (aka the Polish Brothers), and featured each band member on their own journey across various landscapes, only to be joined together on a stage before an intense sunrise for the chorus.


(Reach Up for The) Sunrise, Music video
Each band member's storyline was filmed in a different film or digital format, creating a very different look for each set of scenes. Several versions of the video were made available on the Internet, with each version focusing on the storyline of one band member.


(Reach Up for The) Sunrise, Music video
The band plays the Jason Nevins version live in concert. Jason has co-production credit, to which he is credited in the liner notes on the album.


(Reach Up for The) Sunrise, Covers, samples, & media references
At the end of an episode of Las Vegas, the band appeared, performing the song in the Montecito as was normal during the Second Season.


(Reach Up for The) Sunrise, Covers, samples, & media references
As of 2005, the Jason Nevins newly produced version of the song is used in the beginning sequence of the television programme Sunrise on Seven Network in Australia. It was also used in Telecom Italia Mobile commercials with Adriana Lima. The Jason Nevins version appeared on an episode of Queer Eye for the Straight Guy as well as the television soundtrack, released on Capitol Records.


(Reach Up for The) Sunrise, Covers, samples, & media references
Also, the Jason Nevins Club Mix is featured in the 2007 arcade game Dance Dance Revolution SuperNOVA 2.


(Red) Christmas EP
(Red) Christmas EP, stylised as (RED) Christmas EP, is the first extended play (EP) by American rock band The Killers. It was released digitally on November 29, 2011, by Island Records. The EP features the band's yearly Christmas singles from 2006 to 2011. Proceeds from the sales from the (Red) Christmas EP have been donated to the Product Red campaign, headed by Bobby Shriver and U2 lead singer Bono.


(Red) Christmas EP, Background
The Killers have become recognized for their work with the Product Red campaign, headed by Bono and Bobby Shriver. Every year between 2006 and 2016, the band released a Christmas song in support of the campaign. Every single came out around December 1 (coinciding with World AIDS Day). As of the EP, they had released six Christmas-themed songs and music videos: "A Great Big Sled" (2006), "Don't Shoot Me Santa" (2007), "Joseph, Better You Than Me" (2008), "¡Happy Birthday Guadalupe!" (2009), "Boots" (2010), and "The Cowboys' Christmas Ball" (2011).


(Red) Christmas EP, Background
On November 30, 2011, the band released the (Red) Christmas EP on iTunes which features the first six songs. All proceeds from the songs have been donated to Product Red campaign and the fight against AIDS in Africa. The EP also features guest appearances from Elton John, Neil Tennant (Pet Shop Boys), Toni Halliday (Curve), Wild Light, and Mariachi El Bronx.


(Red) Christmas EP, Singles
The Killers' 2011 Christmas single, "The Cowboys' Christmas Ball", was released as the lead single from the EP.


(Red) Christmas EP, Commercial performance
The album debuted on the US Billboard 200 at number 85. It also opened on the Billboard Digital Albums chart at number 10, Rock Albums at number 11, and Alternative Albums at number nine.


(Remember Me) I'm the One Who Loves You
"(Remember Me) I'm The One Who Loves You" is a song written and originally sung by Stuart Hamblen, which he released in 1950. The song was a hit for Ernest Tubb the same year, and Dean Martin in 1965. Johnny Cash also covered it on his 1957 debut album Johnny Cash with His Hot and Blue Guitar!


(Remember Me) I'm the One Who Loves You, Stuart Hamblen version
Hamblen's version reached No. 2 on Billboard's chart of "Country & Western Records Most Played by Folk Disk Jockeys", No. 3 on Billboard's chart of "Best-Selling Retail Folk (Country & Western) Records", and No. 4 on Billboard's chart of "Most Played Juke Box Folk (Country & Western) Records."


(Remember Me) I'm the One Who Loves You, Stuart Hamblen version
Hamblen's version was also ranked No. 8 on Billboard's ranking of 1950's "Top Country & Western Records According to Retail Sales" and No. 24 on Billboard's ranking of 1950's "Top Country & Western Records According to Juke Box Plays."


(Remember Me) I'm the One Who Loves You, Ernest Tubb version
Ernest Tubb released a version of the song in 1950, which reached No. 5 on Billboard's chart of "Most Played Juke Box Folk (Country & Western) Records" and No. 7 on Billboard's chart of "Best-Selling Retail Folk (Country & Western) Records."


(Remember Me) I'm the One Who Loves You, Dean Martin version
In 1965, the song was released by Dean Martin. The song spent 7 weeks on the Billboard Hot 100 chart, peaking at No. 32, while reaching No. 7 on Billboard's Easy Listening chart, and No. 14 on Canada's R.P.M. Play Sheet.


(Remember Me) I'm the One Who Loves You (album)
(Remember Me) I'm the One Who Loves You is a 1965 studio album by Dean Martin, produced by Jimmy Bowen and arranged by Ernie Freeman. The album was Martin's fifth album to appear in the Top 40, and peaked at number 12 on the Billboard Top LPs chart. The album's release in September 1965 corresponded with the debut of Martin's long-running TV series The Dean Martin Show.


(Remember Me) I'm the One Who Loves You (album)
The album was reissued on CD by Hip-O Records in 2009.


(Remember Me) I'm the One Who Loves You (album), Reception
William Ruhlmann on AllMusic gave the album three stars out of five, commenting on the "Formula" developed by Bowen for Martin's sound, of "piano triplets, a 4/4 beat, swooping strings, a female chorus." Ruhlman added that "... The country market never bit at these records, but Martin had a clutch of material that sounded fresh to pop fans. And, the liner notes notwithstanding, Bowen and Freeman knew that the time had come to vary the formula."


(Ribulose-bisphosphate carboxylase)-lysine N-methyltransferase
In enzymology, a [ribulose-bisphosphate carboxylase]-lysine N-methyltransferase (EC ) is an enzyme that catalyzes the chemical reaction


(Ribulose-bisphosphate carboxylase)-lysine N-methyltransferase
Thus, the two substrates of this enzyme are S-adenosyl methionine and ribulose-1,5-bisphosphate carboxylase-lysine, whereas its two products are S-adenosylhomocysteine and ribulose-1,5-bisphosphate carboxylase-N6-methyl-L-lysine.


(Ribulose-bisphosphate carboxylase)-lysine N-methyltransferase, Transferase Family
This enzyme belongs to the family of transferases, specifically those transferring one-carbon group methyltransferases.


(Ribulose-bisphosphate carboxylase)-lysine N-methyltransferase, Transferase Family
The systematic name of this enzyme class is S-adenosyl-L-methionine:[3-phospho-D-glycerate-carboxy-lyase (dimerizing)]-lysine N6-methyltransferase.


(Ribulose-bisphosphate carboxylase)-lysine N-methyltransferase, Transferase Family
Other names in common use include rubisco methyltransferase, ribulose-bisphosphate-carboxylase/oxygenase N-methyltransferase, ribulose-1,5-bisphosphate carboxylase/oxygenase large subunit, epsilonN-methyltransferase, S-adenosyl-L-methionine:[3-phospho-D-glycerate-carboxy-lyase, and (dimerizing)]-lysine 6-N-methyltransferase.


(Ribulose-bisphosphate carboxylase)-lysine N-methyltransferase, Structural studies
As of late 2007, 7 structures have been solved for this class of enzymes, with PDB accession codes , , , , , , and .


(Rock) Superstar
"(Rock) Superstar" is the second single from Cypress Hill's fifth studio album Skull & Bones. It was originally released as a double A-side with its standard rap counterpart on February 29, 2000 in the UK. An individual release was available starting sometime in April.


(Rock) Superstar, Music video
The song's music video is very similar to the previous single, "(Rap) Superstar", with the man picking up a ticket that says "Rock Superstar" on it. After giving the ticket to Sen Dog, the man enters into a fun house. A group of women dress up the man in a suit, before he wanders off. After seeing a testimony on a TV screen from Everlast, he encounters many record executives. At the video's climax, the man is chased out after going to a performance by Cypress Hill. As the man exits the fun house, it blows up behind him.


(Rock) Superstar, Music video
Coal Chamber bassist Nadja Peulen appears in a cameo as the bass player of the band performing at the song's climax.


(Rock) Superstar, Use in other media
The song is featured in the 2001 film Training Day. It was also in the film Little Nicky.


(Rock) Superstar, Use in other media
The song is featured in the 2000 video game MTV Sports: Skateboarding featuring Andy Macdonald, released on PC and various consoles.


(Rock) Superstar, Use in other media
The instrumental is used as an intro at the beginning of each hour on the nationally syndicated radio and television sports talk show The Dan Patrick Show, and is also used in a small game called Alien Battlecraft Arena.


(Rock) Superstar, Use in other media
The song is featured twice in the American Dad! episode "The Boring Identity". The first is when Steve becomes a paperboy and is introduced to their best worker, Roger. The second time is during a montage of the two "hustling" to earn extra money.


(Romance) in the Digital Age
(Romance) in the Digital Age is a 2017 feature-length film written and directed by Jason Michael Brescia.


(Romance) in the Digital Age, Plot
The film is music focused, which according to Deadline, "a former emo musician who invites his ex-bandmates to his Christmas-themed wedding." While there a video of the fictional band Autumn in August performing the song P.S. Whatever, which in turn becomes a viral hit.


(Romance) in the Digital Age, Cast
Like Brescia's previous film Bridge and Tunnel, (Romance) In The Digital Age features an ensemble cast.


(Romance) in the Digital Age, Cast
The film also features cameo appearances by Frank Iero of My Chemical Romance, Andrew W.K., John Nolan of Taking Back Sunday, Mary Kate Wiles, Annet Mahendru, Hornswoggle, and Tay Zonday.


(Romance) in the Digital Age, Production
Shooting for the film began on February 27, 2016 in Long Beach, New York and wrapped on March 17 of the same year. The film was shot entirely in Long Beach and Amityville, New York, a Long Island suburb. Pickups for certain segments took place throughout 2016, with the final segment featuring Annet Mahendru wrapping up in February, 2017.


(Romance) in the Digital Age, Release
On June 7, 2017 it was announced by Deadline that the film had been acquired by Comedy Dynamics for global distribution. In August 2017 the film premiered at the Long Beach International Film Festival where it received the Joan Jett Music Award for "Best Music". On November 3, 2017 the film had a screening in New York City featuring a concert afterwards featuring John Nolan and LOLO performing songs from the film's soundtrack. The following night in Amityville, Nolan and LOLO performed full sets at the soundtrack release show


(Romance) in the Digital Age, Release
On November 7, 2017 (Romance) In The Digital Age was released worldwide on video on demand. That night the film also screened in Los Angeles at the Regal Cinema at L.A. Live.


(Rough and Unreleased) Homemade Recordings
(Rough and Unreleased) Homemade Recordings is the first extended play by Penny Hill. It was released on 10 November 2010.